Abstract
The purpose of this study is to investigate the electret properties and charge states of the nanocomposites based on the polyvinylidenefluoride and titanium dioxide nanoparticles. It has been found that, large amount of charges are accumulated in the interface as a result of migration polarization and these charges create rather large internal local field in which the polarization of titanium-dioxide nanoparticles occurs. Calculated, the amount of the charges accumulated in the interfacial layer of nanocomposites, the intensity of the field created by them and the value of charge activation energy of PVDF/TiO2 nanocomposites after polarization from thermally stimulated depolarization (TSD) curves. As well as the thickness of the interphase layer of PVDF/TiO2 nanocomposites was calculated and it has been revealed that, as titanium dioxide content increases in the polymeric matrix, the thickness of the interphase layer increases and reaches at its highest value at 5% volume content of TiO2 nanoparticles, after this it commences to decrease.
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References
M. Khaldi, A. Benyoucef, C. Quijada et al., Synthesis, characterization and conducting properties of nanocomposites of successively intercalated 2-aminophenol with aniline in modified-montmorillonite 24 267 (2014)
I. Radja, H. Djelad, E. Morallon et al., Characterization and electrochemical properties of conducting nanocomposites synthesized from p-anisidine and aniline with titanium carbide by chemical oxidative method 202 25–32 (2015)
F.Z. Dahou, M.A. Khaldi, A. Zehhaf et al., Nanocomposite of 2-aminophenol with aniline using copper-montmorillonite: synthesis, characterization, conductivity, and electrochemical study 35 411–418 (2016)
G. Sesler, Electrets. (Springer, Berlin, 1983), 488
G.A. Luschekin, Polymer Electrets. (Springer, Berlin, 1984), 184
Y.A. Gorokhovatsky, G.A. Bordovskiy, Thermally activated current high impedance spectroscopy of semiconductors and dielectrics (Nauka, Moscow, 1991), p. 248
M.F. Galihanov, D.A. Eremeyev, R. Ya, Deberdeev study coronoelectrets based on polyethylene and silica. Mater. Sci. 9, 24–29 (2003)
M.A. Ramazanov, A.S. Quseynova, Influence of polarization processes on the charge states and dielectric properties of polyethylene-based compositions with low-molecular additions PE + PbCrO4 and PE + Cr J. Optoelectron. Adv. Mater. 7, 9–10 (2013)
M.A. Ramazanov, A.S. Huseynova, F.V. Hajiyeva, Influence of electrothermopolarization on structure and photoluminessent properties of polypropylene and MnO2 based nanocompositions J. Ovonic Res. 11, 35–39 (2015)
M.A. Ramazanov, F.V. Hajiyeva, A.M. Maharramov, Influence of corona discharge on the electret and charge states of nanocomposites based on isotactic polypropylene and zirconium dioxide nanoparticles. J. Ferroelectr. 493(1), 103–109 (2016)
M.A. Ramazanov, F.V. Hajiyeva, A.M. Maharramov, U.A. Hasanova, Effect of corona discharge on the structure and photoluminescence properties of nanocomposites based on polypropylene (PP) and zirconium dioxide (ZrO2) nanoparticles. Ferroelectrics 507, 1–6 (2017)
M.A. Ramazanov, F.V. Hajiyeva, A.M. Maharramov, A.B. Ahmadova, U.A. Hasanova, A.M. Rahimli, H.A. Shirinova, Influence of polarization process on morphology and photoluminescence properties of PP/TiO2 nanocomposites. Acta Phys. Pol. A. 131, 1540–1543 (2017)
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Ramazanov, M.A., Hajiyeva, F.V., Maharramov, A.M. et al. Influence of Polarization Charges on the Photoluminescence Properties of Nanocomposites Based on Polyvinylidene Fluoride and Titanium Dioxide Nanoparticles. J Inorg Organomet Polym 27 (Suppl 1), 239–243 (2017). https://doi.org/10.1007/s10904-017-0675-9
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DOI: https://doi.org/10.1007/s10904-017-0675-9