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Polyol Mediated Solvothermal Synthesis and Characterization of CuIn(1−x)GaxS2 Nanocrystals

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Abstract

Gallium-substituted copper indium sulfide (CuIn(1−x)GaxS2) nanoparticles have been synthesized by a convenient solvothermal method without usage of surfactants or toxic reductants such as hydrazine. Thiourea, sodium hydroxide, CuCl2·2H2O, InCl3 and GaCl3 were used as starting materials and ethylene glycol as solvent and reducing agent. The reactions were performed at 200 °C for 16 h. Effect of sodium hydroxide on the reaction products is analyzed. The powders are mainly characterized by X-ray diffraction, Raman spectroscopy, transmission electron microscopy, BET surface area measurements and UV–Vis absorption spectroscopy. The results show that the gallium is successfully incorporated into the chalcopyrite crystal structure. The homogeneous powders obtained are constituted of nanoparticles with sizes in the range 20–30 nm and exhibit a specific surface area close to 65 m2/g. Further, the possible mechanism for the formation of CuIn(1−x)GaxS2 nanocrystals is explained. The optical band gap energies of the nanoparticles were in the range 1.48–1.75 eV.

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References

  1. Z. Djebbour, A.M. Dubois, A. Darga, D. Mencaraglia, C. Bazin, J.P. Connolly, J.F. Guillemoles, D. Lincot, B. Canava, A. Etcheberry, Thin Solid Films. 515, 6233 (2007)

    Article  CAS  Google Scholar 

  2. J.D. Burnett, T. Xu, M. Sorescu, B.R. Strohmeier, J. Sturgeon, O. Gourdon, K. Baroudi, J.L. Yao, J.A. Aitken, J. Solid State Chem. 197, 279 (2013)

    Article  CAS  Google Scholar 

  3. S. Chen, X.G. Gong, A. Walsh, S.H. Wei, Phys. Rev. B. 79, 165211 (2009)

    Article  Google Scholar 

  4. J. Olejnicek, L.E. Flannery, S.A. Darveau, C.L. Exstrom, S. Kment, N.J. Ianno, R.J. Soukup, J. Alloys Compd. 509, 10020 (2011)

    Article  CAS  Google Scholar 

  5. J. Nelson, The Physics of Solar Cells (Imperial College Press, London, 2003)

    Book  Google Scholar 

  6. C. Tablero, Chem. Phys. Lett. 499, 75 (2010)

    Article  CAS  Google Scholar 

  7. H.M. Pathan, C.D. Lokhande, Appl. Surf. Sci. 239, 11 (2004)

    Article  CAS  Google Scholar 

  8. M. Michalska, A. Aboulaich, G. Medjahdi, R. Mahiou, S. Jurga, R. Schneider, J. Alloys Compd. 645, 184 (2015)

    Article  CAS  Google Scholar 

  9. G. Hanna, A. Jasenek, U. Rau, H.W. Schock, Thin Solid Films 387, 71 (2001)

    Article  CAS  Google Scholar 

  10. S.H. Wei, S.B. Zhang, A. Zunger, Appl. Phys. Lett. 72, 3199 (1998)

    Article  CAS  Google Scholar 

  11. M.A. Green, K. Emery, Y. Hishikawa, W. Warta, E.D. Dunlop, Prog. Photovolt: Res. Appl. 22, 70 (2014)

    Google Scholar 

  12. R. Klenk, J. Klaer, R. Scheer, M.C. Lux, Steiner, I. Luck, N. Meyer, U. Ruhle. Thin Solid Films. 509, 480 (2005)

    Google Scholar 

  13. R. Kaigawa, A. Neisser, R. Klenk, MCh. Lux-Steiner, Thin Solid Films. 415, 266 (2002)

    Article  CAS  Google Scholar 

  14. J.M. Meese, J.C. Manthuruthil, D.R. Locker, J. Am. Phys. Soc. 20, 696 (1975)

    Google Scholar 

  15. A.K. Shuaibov, M.P. Churchman, A.I. Dashchenko, Tech. Phys. Lett. 29, 408 (2003)

    Article  CAS  Google Scholar 

  16. J.J. Scragg, P.J. Dale, L.M. Peter, Thin Solid Films. 517, 2481 (2009)

    Article  CAS  Google Scholar 

  17. L.L. Kazmerski, G.A. Sanborn, J. Appl. Phys. 48, 3178 (1977)

    Article  CAS  Google Scholar 

  18. T. Tanaka, D. Kawasaki, M. Nishio, Q. Guo, H. Ogawa, Phys. Status Solidi C. 3, 2844 (2006)

    Article  CAS  Google Scholar 

  19. M. Benchikhi, R. El Ouatib, S. Guillemet-Fritsch, J.Y. Chane-Ching, J.J. Demai, L. Er-Rakho, B. Durand, Mater. Lett. 136, 431 (2014)

    Article  CAS  Google Scholar 

  20. H.J. Muffler, ChH Fischer, K. Diesner, M.C. Lux-Steiner, Sol. Energy Mater. Sol. Cells. 67, 121 (2001)

    Article  CAS  Google Scholar 

  21. X. Wu, Y. Huang, Q. Bai, Q. Fan, G. Li, X. Fan, C. Zhang, H. Liu, Mater. Sci. Semicond. Process. 37, 250 (2015)

    Article  CAS  Google Scholar 

  22. J.J. Nairn, P.J. Shapiro, B. Twamley, T. Pounds, R. von Wandruszka, T.R. Fletcher, M. Williams, C. Wang, M. Grant, Norton. Nano Lett. 6, 1218 (2006)

    Article  CAS  Google Scholar 

  23. E. Kärber, A. Katerski, I. Oja, Acik, V. Mikli, A. Mere, M. Krunks. Thin Solid Films. 519, 7180 (2011)

    Article  Google Scholar 

  24. S. Lugo, Y. Sánchez, M. Neuschitzer, H. Xie, C. Insignares-Cuello, V. Izquierdo-Roca, Y. Peña, E. Saucedo, Thin Solid Films. 582, 74 (2015)

    Article  CAS  Google Scholar 

  25. M.H.C. Jin, K.K. Banger, J.D. Harris, A.F. Hepp, Mater. Sci. Eng. B 116(395), 2005, 26. X. Liang, J. Zhong, F. Yang, W. Hua, H. Jin, H. Liu, J. Sun, W. Xiang. J. Alloys Compd. 509, 6200 (2011)

    Article  Google Scholar 

  26. X. Liang, J. Zhong, F. Yang, W. Hua, H. Jin, H. Liu, J. Sun, W. Xiang, J. Alloys Compd. 509, 6200 (2011)

    Article  CAS  Google Scholar 

  27. J. Zhong, W. Xiang, Y. Zhao, Q. Cai, Y. Wang, J. Wang, H. Yang, X. Liang, Mater. Res. Bull. 47, 861 (2012)

    Article  CAS  Google Scholar 

  28. D. Lee, S. Park, J.H. Kim, Curr. Appl. Phys. 11, S88 (2011)

    Article  Google Scholar 

  29. S.Y. Lee, B.O. Park, Thin Solid Films. 516, 3862 (2008)

    Article  CAS  Google Scholar 

  30. M.A. Hossain, Z. Tianliang, L.K. Keat, L. Xianglin, R.R. Prabhakar, S.K. Batabyal, S.G. Mhaisalkar, L.H. Wong, J. Mater. Chem. A. 3, 4147 (2015)

    Article  CAS  Google Scholar 

  31. C. Rincón, F.J. Ramírez, J. Appl. Phys. 72, 4321 (1992)

    Article  Google Scholar 

  32. P. Guha, D. Das, A.B. Maity, D. Ganguli, S. Chaudhuri, Sol. Energy Mater. Sol. Cells. 80, 115 (2003)

    Article  CAS  Google Scholar 

  33. X. Chuan-Ming, S. Yun, L. Feng-Yan, Z. Li, X. Yu-Ming, H. Qing, L. Hong-Tu, Chin. Phys. 16, 788 (2007)

    Article  Google Scholar 

  34. M. Ishii, K. Shibata, H. Nozaki, J. Solid State Chem. 105, 504 (1993)

    Article  CAS  Google Scholar 

  35. E. Kärber, K. Otto, A. Katerski, A. Mere, M. Krunks, Mater. Sci. Semicond. Process. 25, 137 (2014)

    Article  Google Scholar 

  36. F. Márquez, V. Fornés, Solid State Commun. 112, 17 (1999)

    Article  Google Scholar 

  37. V. Izquierdo-Roca, X. Fontané, E. Saucedo, J.S. Jaime-Ferrer, J. Álvarez-García, A. Pérez-Rodríguez, V. Bermudez, J.R. Morante, New J. Chem. 35, 453 (2011)

    Article  CAS  Google Scholar 

  38. K.J. Carroll, J.U. Reveles, M.D. Shultz, S.N. Khanna, E.E. Carpenter, J. Phys. Chem. C. 115, 2656 (2011)

    Article  CAS  Google Scholar 

  39. P.B. Malls, P. Ravindranathan, S. Komarneni, E. Breval, R. Roy, J. Mater. Chem. 2, 559 (1992)

    Article  Google Scholar 

  40. N. Zhao-Dong, W. Cheng-Zhen, W. Xue-Ying, H. Hai-Yan, Chin. J. Chem. 26, 1395 (2008)

    Article  Google Scholar 

  41. X. Liang, Q. Cai, W. Xiang, Z. Chen, J. Zhong, Y. Wang, M. Shao, Z. Li, J. Mater. Sci. Technol. 29, 231 (2013)

    Article  CAS  Google Scholar 

  42. N. Tohge, M. Asuka, T. Minami, J. Non-Cryst, Solids 147–148, 652 (1992)

    Google Scholar 

  43. C.J. Doona, D.M. Stanbury, Inorg. Chem. 35, 3210 (1996)

    Article  CAS  Google Scholar 

  44. A.R. Siekkinen, J.M. McLellan, J. Chen, Y. Xia, Chem. Phys. Lett. 432, 491 (2006)

    Article  CAS  Google Scholar 

  45. S.H. Yu, L. Shu, J. Yang, Z.H. Han, Y.T. Qian, Y.H. Zhang, J. Mater. Res. 14, 4157 (1999)

    Article  CAS  Google Scholar 

  46. A. Antony, K.V. Murali, R. Manoj, M.K. Jayaraj, Mater. Chem. Phys. 90, 106 (2005)

    Article  CAS  Google Scholar 

  47. D.L. Wood, J. Tauc, Phys. Rev. B. 5, 3144 (1972)

    Article  Google Scholar 

  48. R. Kaigawa, A. Ohyama, T. Wada, R. Klenk, Thin Solid Films. 515, 6260 (2007)

    Article  CAS  Google Scholar 

  49. Y. Vahidshad, M. Nawaz Tahir, A. Iraji Zad, S. Mohammad Mirkazemi, R. Ghasemzadeh, H. Huesmann, W. Tremel, J. Phys. Chem. C. 118, 24670 (2014)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by two French-Moroccan projects: Volubilis Partenariat Hubert Curien (PHC no: MA 09 205) and Projet de Recherches Convention Internationale du CNRS (CNRS-CNRST no: w 22572).

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Authors and Affiliations

  1. Laboratoire de Physico-Chimie Des Matériaux Inorganiques, Faculté Des Sciences Ain Chock, Université Hassan II Casablanca, Casablanca, Morocco

    Mohamed Benchikhi, Rachida El Ouatib & Lahcen Er-Rakho

  2. Institut Carnot CIRIMAT, CNRS Université de Toulouse, 118 Route de Narbonne, 31062, Toulouse Cedex 9, France

    Mohamed Benchikhi & Bernard Durand

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  1. Mohamed Benchikhi
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  2. Rachida El Ouatib
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Correspondence to Mohamed Benchikhi.

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Benchikhi, M., Ouatib, R.E., Er-Rakho, L. et al. Polyol Mediated Solvothermal Synthesis and Characterization of CuIn(1−x)GaxS2 Nanocrystals. J Inorg Organomet Polym 26, 975–980 (2016). https://doi.org/10.1007/s10904-016-0423-6

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