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Synthesis, Crystal Structures, Photocatalysis for Rhodamine B Degradation of a Organobismuth (V) Dithiocarbamate Polymer [PhBiS2CN(C2H5)2Cl]n

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Abstract

A organobismuth (V) dithiocarbamate complex, [PhBiS2CN(C2H5)2Cl]n has been synthesized and characterized by IR, element analysis, 1H NMR and X-ray diffraction single crystal analysis. The complex crystallizes in the monoclinic crystal system, space group P2(1)/c. is coordinated by two sulphur atoms, a carbon atom from benzene ring and two chlorine atoms. The complex leads to one-dimensional zigzag chain structure by a bridging chlorine atom to link metal ions and two adjacent chains are bridged by C–H⋯C interactions. Furthermore, the photocatalytic experiments of the complex on degradation of rhodamine B (RhB) manifest that the complex is good candidate for the photocatalytic degradation of RhB.

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Acknowledgments

This research was supported by the National Natural Science Foundation of China to C. F. Bi (No. 21371161).

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Authors and Affiliations

  1. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, 266100, Shandong, People’s Republic of China

    Liansheng Cui, Xiangmin Meng, Yuhua Fan, Xin Li & Caifeng Bi

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  1. Liansheng Cui
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  2. Xiangmin Meng
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  3. Yuhua Fan
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  4. Xin Li
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  5. Caifeng Bi
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Correspondence to Caifeng Bi.

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Cui, L., Meng, X., Fan, Y. et al. Synthesis, Crystal Structures, Photocatalysis for Rhodamine B Degradation of a Organobismuth (V) Dithiocarbamate Polymer [PhBiS2CN(C2H5)2Cl]n . J Inorg Organomet Polym 25, 1490–1494 (2015). https://doi.org/10.1007/s10904-015-0267-5

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