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Preparation of l-Lactide/3-Glycidyloxypropyltrimethoxysilane Copolymeric Materials with Various Catalysts

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Abstract

Copolymerization reactions of 3-glycidyloxypropyltrimethoxysilane (GPTS) with l-lactide (LLA) at 100 °C for different time intervals are performed by various catalysts such as zirconium perfluoroheptanoate, and commercially available Tin(II) chloride (SnCl2) and sodium trimethylsilanolate (NaOSiMe3). Homo- and copolymers are characterized by FTIR, 1H- and 13C-NMR spectroscopies, electrospray ionization mass spectroscopy, thermal gravimetric analysis, differential scanning calorimetry and gel permeation chromatography. All selected catalysts are effective in ROP of monomers. Especially, SnCl2 is more reactive catalyst in the copolymerization of LLA/GPTS. The structure of final product is found as random copolymers.

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Acknowledgments

This work was supported by the research foundation of Kocaeli University (Project No: 2012/085).

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Authors and Affiliations

  1. Department of Chemistry, Kocaeli University, 41380, Kocaeli, Turkey

    Asgar Kayan & Olcay Mert

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  1. Asgar Kayan
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  2. Olcay Mert
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Correspondence to Olcay Mert.

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Kayan, A., Mert, O. Preparation of l-Lactide/3-Glycidyloxypropyltrimethoxysilane Copolymeric Materials with Various Catalysts. J Inorg Organomet Polym 24, 1055–1062 (2014). https://doi.org/10.1007/s10904-014-0083-3

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  • DOI: https://doi.org/10.1007/s10904-014-0083-3

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