Skip to main content
SpringerLink
Log in

Two Copper Coordination Polymers with Cage-Like 12-MC-4 Metallacrown and Linear Trinuclear Structures

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

Two novel coordination polymers {[Cu4(H2dam-dap)4(ClO4)2]·2ClO4}n (1) and [Cu3(H2dam-dap)2(N3)2(NO3)2]n (2) have been obtained through the copper salts and 3-(3-Amino-propylimino)-butan-2-one oxime (H3dam-dap) ligand, which was synthesized by one-pot reaction in the preparation process of complexes. Single-crystal X-Ray analysis shows that complex 1 displays a cage-like 12-MC-4 metallacrown structural unit with the sides exhibiting Cu–N–O repeat units, and the cage-like structures have been linked into one 1D chain by the bridges of ClO4− anions; 2 possesses trinuclear [Cu3(H2dam-dap)2]4+ unit with three Cu ion locating in a linear arrangement, and the adjacent trinuclear units are linked into a 2D coordination polymer by bridging nitrate anions. Magnetic studies reveal that 1 displays ferromagnetic coupling between metal centres, and 2 exhibits antiferromagnetic interaction and field-induced frequency-dependent behavior.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. J. C. Lutter, C. M. Zaleski, and V. L. Pecoraro (2018). Adv. Inorg. Chem. 71, 177.

    Article  CAS  Google Scholar 

  2. P. Happ, C. Plenk, and E. Rentschler (2015). Coord. Chem. Rev. 289–290, 238.

    Article  CAS  Google Scholar 

  3. G. Mezei, C. M. Zaleski, and V. L. Pecoraro (2007). Chem. Rev. 107, 4933–5003.

    Article  CAS  PubMed  Google Scholar 

  4. M. Ostrowska, I. O. Fritsky, E. Gumienna-Kontecka, and  A. V. Pavlishchuk (2016). Coord. Chem. Rev. 304, 327.

    Google Scholar 

  5. S. N. Wang, L. Q. Kong, H. Yang, Z. T. He, Z. Jiang, D. C. Li, S. Y. Zeng, M. J. Niu, Y. Song, and J. M. Dou (2011). Inorg. Chem. 50, 2705.

    Article  CAS  PubMed  Google Scholar 

  6. H. Yang, Q. X. Yao, Y. W. Li, D. C. Li, and J. M. Dou (2014). Dalton Trans. 43, 16986.

    Article  CAS  PubMed  Google Scholar 

  7. H. Yang, F. Cao, D. C. Li, S. Y. Zeng, Y. Song, and J. M. Dou (2015). Dalton Trans. 44, 6620.

    Article  CAS  PubMed  Google Scholar 

  8. F. Cao, S. N. Wang, D. C. Li, S. Y. Zeng, M. J. Niu, Y. Song, and J. M. Dou (2013). Inorg. Chem. 52, 10747.

    Article  CAS  PubMed  Google Scholar 

  9. H. Yang, F. Cao, D. C. Li, S. Y. Zeng, Y. Song, and J. M. Dou (2015). Chem. Eur. J. 21, 14478.

    Article  CAS  PubMed  Google Scholar 

  10. A. A. Athanasopoulou, J. J. Baldoví, L. M. Carrella, and E. Rentschler (2019). Dalton Trans. 48, 15381.

    Article  CAS  PubMed  Google Scholar 

  11. A. V. Pavlishchuk, S. V. Kolotilov, M. Zeller, L. K. Thompson, and A. W. Addison (2014). Inorg. Chem. 53, 1320.

    Article  CAS  PubMed  Google Scholar 

  12. A. D. Cutland-Van Noord, J. W. Kampf, and V. L. Pecoraro (2002). Angew Chem. Int. Ed. 41, 4667.

    Article  CAS  Google Scholar 

  13. M. Deng, F. Yang, P. Yang, Z. Li, J. Sun, Y. Yang, Z. Chen, L. Weng, Y. Ling, and Y. Zhou (2015). Crysta. Growth Des. 15, 5794.

    Article  CAS  Google Scholar 

  14. W. Q. Lin, J. D. Leng, and M. L. Tong (2012). Chem. Commun. 48, 4477.

    Article  CAS  Google Scholar 

  15. H. B. Xu, B. W. Wang, F. Pan, Z. M. Wang, and S. Gao (2007). Angew. Chem. Int. Ed. 46, 7388.

    Article  CAS  Google Scholar 

  16. J. Jankolovits, C. S. Lim, G. Mezei, J. W. Kampf, and V. L. Pecoraro (2012). Inorg. Chem. 51, 4527.

    Article  CAS  PubMed  Google Scholar 

  17. J. T. Grant, J. Jankolovits, and V. L. Pecoraro (2012). Inorg. Chem. 51, 8034.

    Article  CAS  PubMed  Google Scholar 

  18. M. Tegoni and M. Remelli (2012). Coord. Chem. Rev. 256, 289.

    Article  CAS  Google Scholar 

  19. I. Martinić, S. V. Eliseeva, T. N. Nguyen, V. L. Pecoraro, and S. Petoud (2017). J. Am. Chem. Soc. 139, 8388.

    Article  PubMed  CAS  Google Scholar 

  20. C. Y. Chow, S. V. Eliseeva, E. R. Trivedi, T. N. Nguyen, J. W. Kampf, S. Petoud, and V. L. Pecoraro (2016). J. Am. Chem. Soc. 138, 5100.

    Article  CAS  PubMed  Google Scholar 

  21. E. R. Trivedi, S. V. Eliseeva, J. Jankolovits, M. M. Olmstead, S. Petoud, and V. L. Pecoraro (2014). J. Am. Chem. Soc. 136, 1526.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  22. J. Jankolovits, C. M. Andolina, J. W. Kampf, K. N. Raymond, and V. L. Pecoraro (2011). Angew. Chem. Int. Ed. 50, 9660.

    Article  CAS  Google Scholar 

  23. T. N. Nguyen, C. Y. Chow, S. V. Eliseeva, E. R. Trivedi, J. W. Kampf, I. Martinić, S. Petoud, and V. L. Pecoraro (2018). Chem. Eur. J. 24, 1031.

    Article  CAS  PubMed  Google Scholar 

  24. S. Y. Woo, T. Mallah, V. Pecoraro, M. Kociak, O. Stéphan, and A. Zobelli (2019). Microsc. Microanal. 25, 604.

    Article  Google Scholar 

  25. R. Sessoli, D. Gatteschi, A. Caneschi, and M. A. Novak (1993). Nature. 365, 141.

    Article  CAS  Google Scholar 

  26. C. J. Milios, R. Inglis, A. Vinslava, R. Bagai, W. Wernsdorfer, S. Parsons, S. P. Perlepes, G. Christou, and E. K. Brechin (2007). J. Am. Chem. Soc. 129, 12505.

    Article  CAS  PubMed  Google Scholar 

  27. C. Dendrinou-Samara, C.M. Zaleski, A. Evagorou, J.W. Kampf, V.L. Pecoraro, D.P. Kessissoglou (2003). Chem. Commun. 2668.

  28. A. Tarushi, F. Kastanias, V. Psycharis, C. P. Raptopoulou, G. Psomas, and D. P. Kessissoglou (2012). Inorg. Chem. 51, 7460.

    Article  CAS  PubMed  Google Scholar 

  29. J.M. Frost, S. Sanz, T. Rajeshkumar, M.B. Pitak, S.J. Coles, G. Rajaraman, W. Wernsdorfer, J. Schnack, P.J. Lusby, E.K. Brechin (2014). 43, 1069.

  30. E. Canpolat, A. Aglamis, and M. Kaya (2016). Cumhuriyet University Faculty of Science Science Journal. 37 (1), 65–73.

    Google Scholar 

  31. X. Liu and J. R. Hamon (2019). Coord. Chem. Rev. 398, 94–118.

    Article  CAS  Google Scholar 

  32. W. M. Wang, L. Y. He, X. X. Wang, Y. Shi, Z. L. Wu, and J. Z. Cui (2019). Dalton Trans. 48, 16744–16755.

    Article  CAS  PubMed  Google Scholar 

  33. C. L. Yin, Z. B. Hu, and Q. Q. Long (2019). Dalton. Tran. 48 (2), 512–522.

    Article  CAS  Google Scholar 

  34. E. C. Mazrakioti, J. Regier, and L. Cunha-silva (2017). Inorg. Chem. 56, 3568–3578.

    Article  CAS  Google Scholar 

  35. S. X. Huang, F. Xu, S. J. Qi, K. Wang, Y. Li, S. H. Zhang, X. Q. Zhang, S. Y. Luo, and F. P. Liang (2021). J. Clust. Sci. 32, 765–772.

    Article  CAS  Google Scholar 

  36. E. S. Bazhina, A. A. Bovkunova, A. V. Medved’ko, N. N. Efimov, M. A. Kiskin, and I. L. Eremenko (2019). J. Clust. Sci. 30, 1267–1275.

    Article  CAS  Google Scholar 

  37. H. Mihara, Y. Xu, N. E. Shepherd, S. Matsunaga, and M. Shibasaki (2009). J. Am. Chem. Soc. 131, 8384–8385.

    Article  CAS  PubMed  Google Scholar 

  38. M. T. Nielsen, R. Padilla, and M. Nielsen (2020). J. Clust. Sci. 31, 11–61.

    Article  CAS  Google Scholar 

  39. G. B. Li, H. C. Fang, Y. P. Cai, Z. Y. Zhou, P. K. Thallapally, and J. Tian (2010). Inorg. Chem. 49, 7241–7243.

    Article  CAS  PubMed  Google Scholar 

  40. S. S. Zheng, W. K. Dong, and Y. Zhang (2017). New. J. Chem. 41 (12), 4966–4973.

    Article  CAS  Google Scholar 

  41. S. Gautam, S. Chandra, and H. Rajor (2018). Appl. Organ. Chem. 32 (1), e3915.

    Article  CAS  Google Scholar 

  42. B. S. Far, G. Grivani, and A. D. Khalaji (2017). J. Clust. Sci. 28, 3217–3227.

    Article  CAS  Google Scholar 

  43. W. F. Zheng, H. F. Ma, X. W. Chang, and S. Y. Zhang (2019). J. Clust. Sci. 30, 97–103.

    Article  CAS  Google Scholar 

  44. A. Hamil, A. A. Almutaleb, and M. Q. Nouradean (2020). Sfkjhgikhu. Adv. J. Chem. 3 (4), 524–533.

    Article  CAS  Google Scholar 

  45. Y. Y. Meng, Y. Q. Zhang, and L. W. Pan (2020). Inorg. Chim. Acta. 509, 119707.

    Article  CAS  Google Scholar 

  46. S. Sengupta, S. Khan, S. K. Chattopadhyay, I. Banerjee, T. K. Panda, and S. Naskar (2020). Polyhedron. 182, 114512.

    Article  CAS  Google Scholar 

  47. F. F. Xing, H. Yang, D. C. Li, and J. M. Dou (2019). Inorg. Chem. Commun. 104, 19–22.

    Article  CAS  Google Scholar 

  48. H. G. Zhang, H. Yang, J. Yang, D. C. Li, and J. M. Dou (2019). Inorg. Chim. Acta. 495, 119014.

    Article  CAS  Google Scholar 

  49. S. Giri, D. Maity, J. F. Godsell, S. Roy, M. G. B. Drew, A. Ghosh, G. Mukhopadhyay, and S. K. Saha (2011). Inorg. Chim. Acta 377, 99.

    Article  CAS  Google Scholar 

  50. H. Pagonda, P. P. Yogesh, H. R. Katreddi, and N. Munirathinam (2012). Inorg Chim. Acta 392, 478.

    Article  CAS  Google Scholar 

  51. M. Dolai, U. Saha, S. Biswas, S. Chatterjee, and G. S. Kumar (2020). CrystEngComm 22, 8374.

    Article  CAS  Google Scholar 

  52. P. Seppälä, E. Colacio, A. J. Mota, and R. Sillanpää (2012). Dalton Trans. 41, 2648.

    Article  PubMed  CAS  Google Scholar 

  53. M. Pait, M. Shatruk, J. Lengyel, S. Gómez-Coca, A. Bauzá, A. Frontera, V. Bertolasi, and D. Ray (2015). Dalton Trans. 44, 6107–6117.

    Article  CAS  PubMed  Google Scholar 

  54. B. Kintzel, M. Böhme, J. J. Liu, A. Burkhardt, J. Mrozek, A. Buchholz, A. Ardavan, and W. Plass (2018). Chem. Commun. 54, 12934–12937.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work received support from the National Natural Science Foundation of China (No. 21671093 and 21701078).

Author information

Authors and Affiliations

  1. Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, 252059, Liaocheng, People’s Republic of China

    Wenhui Miao, Na Yang, Hua Yang, Jianmin Dou & Dacheng Li

Authors
  1. Wenhui Miao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Na Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hua Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jianmin Dou
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Dacheng Li
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Hua Yang or Jianmin Dou.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Miao, W., Yang, N., Yang, H. et al. Two Copper Coordination Polymers with Cage-Like 12-MC-4 Metallacrown and Linear Trinuclear Structures. J Clust Sci 33, 1923–1928 (2022). https://doi.org/10.1007/s10876-021-02113-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-021-02113-5

Keywords

Search

Navigation