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Room Temperature Syntheses, Crystal Structures and Magnetic Properties of One Novel Decanuclear Copper Cluster Based on 3-amino-1,2,4 triazole Schiff Base

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Abstract

One novel decanuclear copper cluster, {[Cu10(L)8(CH3COO)2(μ3- OH)2]·(DMF)2·(H2O)5} (1, H2L = (E)- 2-(((4H-1,2,4-triazol-3-yl)imino)methyl)-6-methoxyphenol, DMF = N,N’-dimethyl-formamide), were obtained by room temperature micro-bottle reaction. The complex 1 was characterized using elemental analysis, infrared spectroscopy and single-crystal X-ray diffractometry. 1 is decanuclear copper cluster. The {Cu10O4(N2triazol)8} core displays dominant antiferromagnetic interactions owing to the μ3-OH, and μ2-Ophenoxo bridged binding modes with g = 2.126, J = − 6.81 \(\times {10}^{-4}\) cm−1, and zJ’ = − 0.577 cm−1.

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Acknowledgements

Funding for this research was provided by the Nature Science Foundation of china (No. 21861014); the Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi (No. GXYSXTZX2017-II-3) and talent introduction program of Guangdong Institute of Petrochemical Technology (No.520167).

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Authors and Affiliations

  1. College of Chemistry and Bioengineering (Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials), Guilin University of Technology, Guilin, 541004, People’s Republic of China

    Yujie Zhang, Qin Chen, Haiyang Zhang & Shuhua Zhang

  2. College of Chemistry, Guangdong University of Petrochemical Technology, Maoming, 525000, Guangdong, People’s Republic of China

    Yujie Zhang, Qin Chen, Guangzhao Li & Shuhua Zhang

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10876_2021_2064_MOESM2_ESM.pdf

Supplementary Information Crystallographic data (excluding structure factors) for the structures in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication CCDC 2017049 for 1. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: 44 1223 336033, e-mail: deposit@ccdc.cam.ac.uk). Electronic supplementary information (ESI) available: FTIR curves, XRD, χ vs T curve. Continuous Shape Measure (CShM) calculations, bond valence sum (BVS). (PDF 260 kb)

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Zhang, Y., Chen, Q., Zhang, H. et al. Room Temperature Syntheses, Crystal Structures and Magnetic Properties of One Novel Decanuclear Copper Cluster Based on 3-amino-1,2,4 triazole Schiff Base. J Clust Sci 33, 1399–1405 (2022). https://doi.org/10.1007/s10876-021-02064-x

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