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A Series of Lanthanide Chalcogenidogermanates Displaying Two Types of 1-D Polymeric Chains

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Abstract

A series of lanthanide chalcogenidogermanates [Ln2(tepa)2(μ-OH)2(μ-Ge2Q6)]n·nH2O {Q = S, Ln = Er (1a), Tm (1b), tepa = tetraethylenepentamine; Q = Se, Ln = Y (1c)} and [Tb2(tepa)2(μ-OH)2(μ-Ge2Se8)]n (2) were prepared under mild solvothermal conditions and structurally characterized. Compounds 1a–c contain 1-D neutral chains [Ln2(tepa)2(μ-OH)2(μ-Ge2Q6)]n based on the linkages of [Ln2(tepa)2(μ-OH)2]4+ cations and [μ-Ge2Q6]4- anions, while compound 2 exhibits another 1-D neutral chain [Tb2(tepa)2(μ-OH)2(μ-Ge2Se8)]n constructed by the combination of [Ln2(tepa)2(μ-OH)2]4+ cations and [μ-Ge2Se8]4- anions with two Se–Se bonds. The 1-D neutral chains of 1a–c are arranged in a crossing manner, but the 1-D neutral chains of 2 are aligned in a parallel manner. Their band gaps in the range of 2.09–3.35 eV are derived from optical absorption spectra.

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Acknowledgements

This work was supported by the NNSF of china (No. 21671029), the NSF of Chongqing municipality (No. cstc2015jcyjBX0117), Program for leading talents of scientific and technological innovation in Chongqing municipality (No. CSTCCXLJRC201707) and Program for Excellent Talents in Chongqing Higher Education Institutions. The authors are also grateful to Chongqing Normal University for financial support (No.14CSLJ02).

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Authors and Affiliations

  1. Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing, 401331, People’s Republic of China

    Shimei Tang, Shumei Cao & Jian Zhou

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  1. Shimei Tang
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  2. Shumei Cao
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  3. Jian Zhou
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Correspondence to Jian Zhou.

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Tang, S., Cao, S. & Zhou, J. A Series of Lanthanide Chalcogenidogermanates Displaying Two Types of 1-D Polymeric Chains. J Clust Sci 29, 777–783 (2018). https://doi.org/10.1007/s10876-018-1402-6

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