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Synthesis, Characterization and Crystal Structure of Polymer [La3(MeBA)8(OH)(o-Phen)(H2O)]n Containing the Novel La6 Cluster Unit

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Abstract

The title complex La/3-methylbenzoic acid (HMeBA) with o-phenanthroline has been hydrothermally synthesized directly: [La3(MeBA)8(OH)(o-Phen)(H2O)]n 1 (o-Phen = o-phenanthroline). The crystal structure was determined by single-crystal X-ray diffraction with the following data: triclinic P − 1. The complex is a one-dimensional chain and one water molecule and [OH]− also coordinate with La ion in particular. Interestingly, the one-dimensional chain is composed of the novel repeated La6 cluster units. Additionally, in order to explore the structural characteristic, 2D correlation analysis of FTIR with thermal perturbation, photo-luminescent and solid UV–Vis spectrum are used.

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Acknowledgements

The project was supported by Scientific Research Fund of Hebei Provincial Education Department (z2017017). We thank Prof. Sun Suqin (Tsinghua University, Beijing, China) for providing the 2D IR correlation analysis software.

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Authors and Affiliations

  1. Qian’an College, North China University of Science and Technology, Qian’an, 063000, China

    Ling-Yan Zhao, Ying-Xin Yang, Xiao-Chen Deng & Xiao-Ge Shi

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  1. Ling-Yan Zhao
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  2. Ying-Xin Yang
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Correspondence to Ling-Yan Zhao.

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Zhao, LY., Yang, YX., Deng, XC. et al. Synthesis, Characterization and Crystal Structure of Polymer [La3(MeBA)8(OH)(o-Phen)(H2O)]n Containing the Novel La6 Cluster Unit. J Clust Sci 28, 3115–3126 (2017). https://doi.org/10.1007/s10876-017-1277-y

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