Skip to main content
SpringerLink
Log in

Ba3Na(OH)3(CO3)2: A Non-centrosymmetric Hydroxycarbonate Crystallized Using the Hydroflux Method

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Single crystals of Ba3Na(OH)3(CO3)2 were grown using the hydroflux method and characterized by single crystal X-ray diffraction. Ba3Na(OH)3(CO3)2 crystallizes in the hexagonal, non-centrosymmetric space group P63cm with a = 9.31360(10) Å and c = 6.2218(2) Å. The material exhibits a three-dimensional crystal structure consisting of chains of face-sharing Na(OH)6 octahedra that are hydrogen bonded to carbonate anions; the charge balance is maintained by barium atoms connected to the trigonal planar carbonate groups and surrounding the Na(OH)6 chains.

Graphical Abstract

The synthesis and crystal structure of the non-centrosymmetric hydroxycarbonate, Ba3Na(OH)3(CO3)2, is reported.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Bugaris DE, zur Loye H-C (2012) Angew Chem Int Ed 51:3780–3811

    Article  CAS  Google Scholar 

  2. Mugavero III SJ, Gemmill WR, Roof IP, zur Loye H-C (2009) J Solid State Chem 182:1950–1963

    Article  CAS  Google Scholar 

  3. Chance WM, Bugaris DE, Sefat AS, zur Loye H-C (2013) Inorg Chem 52:11723–11733

    Article  CAS  PubMed  Google Scholar 

  4. Bugaris DE, Smith MD, zur Loye H-C (2013) Inorg Chem 52:3836–3844

    Article  CAS  PubMed  Google Scholar 

  5. Latshaw AM, Chance WM, Trenor N, Morrison G, Smith MD, Yeon J, zur Loye H-C (2015) CrystEngComm 17:4691–4698

    Article  CAS  Google Scholar 

  6. Stoilova D, Koleva V, Vassileva V (2002) Spectrochim Acta A 58:2015

    Article  Google Scholar 

  7. Alwan AK, Thomas JH, Williams PA (1980) Trans Metal Chem 76:51–53

    Google Scholar 

  8. Del Arco M, Trujillano R, Rives V (1998) J Mater Chem 8:761–767

    Article  Google Scholar 

  9. Stoilova D, Koleva V, Vassileva V (2002) Spectrochim Acta A 58:2051

    Article  CAS  Google Scholar 

  10. Kang J, Lee C, Kremer RK, Whangbo M-H (2009) J Phys Cond Mater 21:392201

    Article  CAS  Google Scholar 

  11. Song J-L, Cui J-Q, Wu C, Yang G, Zhang C (2016) Inorg Chim Acta 444:217–220

    Article  CAS  Google Scholar 

  12. Frost RL, López A, Scholz R, Sampaio NP, De Oliveira FAN (2015) Spectrochim Acta A 136:918–923

    Article  CAS  Google Scholar 

  13. Guo Z, Du F, Li G, Cui Z (2006) Inorg Chem 45:4167–4169

    Article  CAS  PubMed  Google Scholar 

  14. Sorbello C, Jobbágy M (2017) Cryst Growth Des 17:5660–5666

    Article  CAS  Google Scholar 

  15. Belokoneva EL, Al’-Ama AG, Dimitrova OV, Kurazhkovskaya VS, Stefanovich SY (2002) Crystallog Rep 47:217–222

    Article  CAS  Google Scholar 

  16. SMART Version 5.631, SAINT + Version 6.45 and SADABS Version 2.10. Bruker Analytical X-ray Systems, Inc., Madison, Wisconsin (2003)

  17. Sheldrick GM (2008) Acta Cryst A64:112–122

    Article  CAS  Google Scholar 

  18. Hübschle CB, Sheldrick GM, Bittrich B (2011) J Appl Cryst 44:1281–1284

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Research supported by the U.S. National Science Foundation through Grant DMR-1301757.

Author information

Authors and Affiliations

  1. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29208, USA

    Karl D. zur Loye, Allison M. Latshaw, Mark D. Smith & Hans-Conrad zur Loye

Authors
  1. Karl D. zur Loye
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Allison M. Latshaw
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Mark D. Smith
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hans-Conrad zur Loye
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hans-Conrad zur Loye.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

zur Loye, K.D., Latshaw, A.M., Smith, M.D. et al. Ba3Na(OH)3(CO3)2: A Non-centrosymmetric Hydroxycarbonate Crystallized Using the Hydroflux Method. J Chem Crystallogr 48, 103–108 (2018). https://doi.org/10.1007/s10870-018-0716-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-018-0716-4

Keywords

Search

Navigation