Abstract
A new molybdenum containing oxyfluoride, BaMoOF5, space group Cmcm with lattice parameters of a = 7.1445(3), b = 6.7894(3), c = 10.1969(4), was synthesized via a mild hydrothermal crystal growth method. The synthesis resulted in high-quality single crystals of the title material, which were characterized by single-crystal X-ray diffraction. The structure is discussed in detail.
Graphical Abstract
A new Mo(V) oxyfluoride, BaMoOF5, was synthesized via a mild hydrothermal route that included an in-situ reduction step to reduce molybdenum from a starting oxidation state of 6+ to 5+.
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Acknowledgements
We gratefully acknowledge financial support from the United States Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering. Award number DE-SC0018739 funded this work.
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The funding sponsors had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript, and in the decision to publish the results.
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Supplemental Information: The CIF for the reported composition has been deposited in both the ICSD: Number Pending and the CCDC: 1588566. (PDF 82 KB)
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Felder, J.B., Smith, M.D. & zur Loye, HC. Utilizing an In Situ Reduction in the Synthesis of BaMoOF5. J Chem Crystallogr 49, 52–57 (2019). https://doi.org/10.1007/s10870-018-00767-0
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DOI: https://doi.org/10.1007/s10870-018-00767-0