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Hydrogen-Bond Reorganization of a Solid-State Dehydration Process in a Salt of Tris(hydroxymethyl)aminomethane and Sulfosalicylic Acid, Investigated by Powder X-ray Diffraction

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Abstract

Hydrated solid salt of tris(hydroxymethyl)aminomethane (THAM) and sulfosalicylic acid (SA) undergoes a facile solid-state dehydration process upon heating, in which single crystals of the hydrated phase transform to a microcrystalline powder of an anhydrous product phase. The structural properties of the anhydrous phase have been determined directly from powder X-ray diffraction data, allowing rationalization of the structural changes associated with the dehydration process. The dehydration process is associated with substantial reorganization of the hydrogen bonding arrangement, while most hydrogen bonds related to SA ion are actually preserved in the transformation.

Graphical Abstract

The process relating to the formation and decomposition of a salt formed by SA and THAM—hydrated and anhydrous states was investigated and discussed in the paper.

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Acknowledgments

This research was supported by NSFC (Nos. 20903052, 21571090), the Program for Liaoning Excellent Talents in University (LJQ 2011003).

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Authors and Affiliations

  1. College of Chemistry, Liaoning University, Shenyang, 110036, China

    Xi-Kun Xu, Peng Zhang, Hong-Liang Liu & Fang Guo

  2. College of Materials Science and Engineering, Nanjing Tech University, Nanjing, 211816, China

    Wei-Cai Ju & Zhi-Gang Pan

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  1. Xi-Kun Xu
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  2. Wei-Cai Ju
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  3. Zhi-Gang Pan
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  4. Peng Zhang
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  5. Hong-Liang Liu
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Correspondence to Zhi-Gang Pan or Fang Guo.

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Xu, XK., Ju, WC., Pan, ZG. et al. Hydrogen-Bond Reorganization of a Solid-State Dehydration Process in a Salt of Tris(hydroxymethyl)aminomethane and Sulfosalicylic Acid, Investigated by Powder X-ray Diffraction. J Chem Crystallogr 46, 1–8 (2016). https://doi.org/10.1007/s10870-015-0620-0

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  • DOI: https://doi.org/10.1007/s10870-015-0620-0

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