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Exploring structural, magnetic and dielectric properties of Ba1−xCoxFe12O19 hexaferrites

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Abstract

This article presents a comprehensive investigation into the structural, magnetic, and dielectric properties of Ba1−xCoxFe12O19 (x = 0.00, 0.10, 0.20, 0.30, 0.40 and 0.50) prepared at 1100 °C using the heat treatment method. The FTIR analysis revealed the formation of the ferrite phase. XRD analysis provided valuable crystallographic parameters and confirmed the formation of M-type hexaferrites along with a BaFe2O4 phase. TGA investigations elucidated the thermal stability after 600 °C. VSM measurements unveiled the variation in magnetic saturation with cobalt substitutions from 24.390 to 41.629 Am2 kg−1; coercivity from 1508 to 3577 Oe. Formed samples are magnetically hard in nature. The dielectric measurements indicate that the conduction observed at low frequencies can be attributed to the presence of grain boundaries, while the conduction observed at higher frequencies is mostly influenced by the grains themselves. All samples have a frequency-dependent increase in AC conductivity. These findings contribute to the understanding of its potential applications in the automotive industry, sensors, biomedical applications and related fields.

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Data availability

Data sets generated during the current study are available from the corresponding author upon reasonable request.

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Funding

The authors Tanuj Gupta and Chetna Chauhan are grateful to Nirma University, Ahmedabad, India for financial support in the form of a project (letter no.: NU/DRI/MinResPrj/lT/2023–24/78). Rajshree B. Jotania is grateful to University Grant Commission, New Delhi, India for DRS-SAP-Phase-II (F.530/10/DRS/2018 (SAP-I) dated April 17, 2018), and DST, India for DST-FIST (level- I, No. SR/FST/PSI-198/ 2014) grants.

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Authors and Affiliations

  1. Institute of Technology, Nirma University, Ahmedabad, Gujarat, 382481, India

    Aryan Kalariya, Tanuj Gupta & Chetna C. Chauhan

  2. Department of Physics, University School of Sciences, Gujarat University, Ahmedabad, Gujarat, 380009, India

    Rajshree B. Jotania

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  1. Aryan Kalariya
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Contributions

AK: Samples preparation, characterization. TG: Characterization, Data curation and analysis, Software, graphics, original draft preparation, final manuscript checking and submission. CCC: Samples characterizations, Supervisions, graph modifications, Data curation and analysis, draft modifications, Conceptualization. RBJ: Data curation, sample characterization, draft reading, writing and modification.

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Correspondence to Tanuj Gupta, Chetna C. Chauhan or Rajshree B. Jotania.

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Kalariya, A., Gupta, T., Chauhan, C.C. et al. Exploring structural, magnetic and dielectric properties of Ba1−xCoxFe12O19 hexaferrites. J Mater Sci: Mater Electron 35, 696 (2024). https://doi.org/10.1007/s10854-024-12441-7

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