Abstract
In this study, Heusler alloys with nominal composition of Ni50−xMoxMn37Sb13+B2 (x = 0, 1, 3, 5, and 7) were synthesized by the arc-melting method. In the samples with low Mo-content, 4O and 10 M phases were obtained, indicating the presence of the martensite phase, while in the samples with high Mo-content, the L21 phase was determined, which is attributed to the austenite structure. The samples showed a two-step transition between T1 and T2 temperatures in the temperature dependent magnetization measurements, which is attributed to a premartensitic transformation. It was observed that the interval T1−T2 decreased with the increase of Mo-content in the system. It was found that there was an increase in magnetization value due to Curie transition around 350 K in x = 0 and x = 1 Mo-substituted samples, but there was no such increase between 5 and 360 K for other samples. It was found that the blocking temperature (TB) was affected by the Mo-substitution. The thermal hysteresis between the M–T curves during cooling and heating indicates a first-order phase transition in the samples. It is evident from both the M–T and ρ–T analyses that the MT temperatures shifted to low temperatures as the Mo-content increases. An exchange bias effect was observed in the samples. ∆SM with a positive sign was determined for all samples, reaching a maximum value around MT temperature. The maximum ∆SM was obtained at a magnetic field of 5 T at 255 K in the x = 3 Mo-substituted sample. Similarly, the highest RC, AHL and RCeff values were also found for the x = 3 Mo-substituted sample.
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This work was supported by the Research Fund of Inonu University, Turkey under Grant Contract No. FDK-2022-2892.
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All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by MA, GK and MAA. The first draft of the manuscript was written by GK and MAA, and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Ayyildiz, M., Kirat, G. & Aksan, M.A. Investigation of magnetic and electrical properties in the Mo-substituted Ni-Mn-Sb Heusler alloys. J Mater Sci: Mater Electron 34, 2122 (2023). https://doi.org/10.1007/s10854-023-11537-w
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DOI: https://doi.org/10.1007/s10854-023-11537-w