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Effect of cobalt on the magnetic properties and temperature coefficient of resistance for lanthanum-strontium manganite

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Abstract

An analysis of the sensitivity of the electrical resistance to temperature changes in cobalt-doped lanthanum-strontium manganite was carried out to provide new insight into the effects of the magnetic interactions between cobalt and manganese ions on the electric properties. Cobalt-doped lanthanum-strontium manganites, La0.7Sr0.3CoxMn1−xO3 with x ranging from 0 to 0.1 (Δx = 0.025), were synthesized by high-energy ball milling for 5 h, followed by annealing at 1673 K. X-ray diffraction showed the presence of a rhombohedral phase for all the studied compositions, indicating a decrease in the bandwidth as the cobalt content increased. The Curie temperature, determined by vibrating sample magnetometry, and the insulator-metal transition temperature, determined by electrical measurements, decrease near to room temperature with increases cobalt content up to 0.1 by weakening the double exchange magnetic interaction. The results confirmed that cobalt increased the temperature coefficient of resistance for the doped manganites by up to 15.6% for 0.1 mol of cobalt near room temperature. Therefore, these materials will prove useful for the development of specialized sensing devices such as bolometers.

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Data availability

The datasets generated during and/or analyzed during the current study are available to download from [https://data.mendeley.com/datasets/mfyyfkt7ww/draft?a=9b747f51-5fcc-4f59-917d-7618db494a2a].

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Acknowledgements

The authors are grateful for the financial support of the Humanities, Science and Technology National Council of Mexico (CONAHCyT) under grant CF-2023-I-769. I. González-García thanks CONAHCyT for the scholarship granted to carry out her postgraduate studies.

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Authors and Affiliations

  1. Área Académica de Ciencias de la Tierra y Materiales, Universidad Autónoma del Estado de Hidalgo, Mineral de la Reforma, 42184, Pachuca, Hidalgo, México

    I. González-García, A. M. Bolarín-Miró, O. Rosales-González, J. C. Aguirre-Espinosa & F. Sánchez-De Jesús

  2. Centro de Investigación e Innovación Tecnológica, Instituto Politécnico Nacional, 02250, Ciudad de México, México

    C. A. Cortés-Escobedo

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  1. I. González-García
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Contributions

IGG: Conceptualization, methodology, validation, writing, reviewing and editing. AMBM: Conceptualization, formal analysis, methodology, validation, writing. JCAE: Material preparation, data collection and analysis. ORG: Data collection, materials characterization and data analysis CACE: Validation and editing. FSDJ: Conceptualization, formal analysis, methodology, validation, writing and editing.

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Correspondence to F. Sánchez-De Jesús.

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González-García, I., Bolarín-Miró, A.M., Rosales-González, O. et al. Effect of cobalt on the magnetic properties and temperature coefficient of resistance for lanthanum-strontium manganite. J Mater Sci: Mater Electron 34, 1979 (2023). https://doi.org/10.1007/s10854-023-11428-0

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