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Structural, magnetic, and magnetocaloric properties of La0.8−xEuxCa0.1Sr0.1MnO3 (x = 0.05, 0.10, and 0.15): A-site doping

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Abstract

With the development of the current times, the demand for refrigeration is in every aspect. Nevertheless, the necessity for new refrigeration materials is immediate because of the greenhouse effect and the destruction of the atmosphere. Therefore, perovskite materials have been investigated. La0.8−xEuxCa0.1Sr0.1MnO3 (LECSMO) (x = 0.05, 0.10, 0.15) powder samples were prepared using the sol–gel method (S–G). The structure, magnetocaloric effect, and magnetic of LECSMO have been explored. X-ray diffraction (XRD) indicates that all samples belong to the rhombohedral perovskite structure of the Pbnm space group. The magnetic research of LECSMO revealed that the samples doped with Eu3+ exhibited a ferromagnetic (FM) to paramagnetic (PM) transition around the Curie temperature (Tc). As the amount of Eu3+ doping is added, Tc decreased from 264 to 194 K. Normalization and Banerjee’s criterion confirmed the second-order phase transition of the LECSMO near Tc. The maximum magnetic entropy change (\(-\varDelta {S}_{M}^{max}\)) for LECSMO (x = 0.05, 0.10, 0.15) is 5.39, 4.52, and 4.35 J/(kg·K) when the applied magnetic field (H) = 5 T, respectively. Further, the relative cooling power (RCP) of LECSMO is 282.20 J·kg− 1, 305.20 J·kg− 1, and 323.15 J·kg− 1, respectively.

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Data availability

The datasets generated during and analyzed during the current study are available from the corresponding author on reasonable request.

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Funding

The funding was provided by the National Natural Science Foundation of China, Grant No. 52162038.

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Author notes

  1. Zhuojia Xie and Xinyu Jiang have contributed equally to this work.

Authors and Affiliations

  1. College of Materials Science and Engineering, Guilin University of Technology, Guilin, 541004, China

    Zhuojia Xie, Xinyu Jiang, Weijian Zhang & Zhengguang Zou

  2. Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials, Guilin University of Technology, Guilin, 541004, China

    Zhengguang Zou

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  1. Zhuojia Xie
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Contributions

ZX contributed to conceptualization, data curation, writing of the original draft, and writing, reviewing, & editing of the manuscript. XJ contributed to data curation, supporting, and writing, reviewing, & editing of the manuscript. WZ contributed to writing, reviewing, & editing of the manuscript and supporting. ZZ contributed to conceptualization, funding acquisition, and writing, reviewing, & editing of the manuscript.

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Correspondence to Zhengguang Zou.

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Xie, Z., Jiang, X., Zhang, W. et al. Structural, magnetic, and magnetocaloric properties of La0.8−xEuxCa0.1Sr0.1MnO3 (x = 0.05, 0.10, and 0.15): A-site doping. J Mater Sci: Mater Electron 34, 1514 (2023). https://doi.org/10.1007/s10854-023-10943-4

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