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Low temperature sintering and energy storage properties of 0.8Ba0.2Sr0.8TiO3–0.2Bi(Mg0.5Zr0.5)O3 ceramic with additive of SrO–B2O3–ZnO glass

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Abstract

Glass additive SrO–B2O3–ZnO (SBZ) is used to decrease the sintering temperature of 0.8Ba0.2Sr0.8TiO3–0.2Bi(Mg0.5Zr0.5)O3 (BST-BMZ) ceramic and improve ceramic energy storage performance. The effects of glass content on the sintering temperature, crystal structure, microstructure, dielectric property, and energy storage performance of BST-BMZ ceramics are investigated. Benefiting from the good wetting behavior of SBZ glass melt and BST-BMZ ceramic, the addition of SBZ glass on the BST-BMZ matrix facilitates achievement of low temperature sintering process, and the sintering temperature reduces from 1300 ºC to 1100 ºC for BST-BMZ + 2 wt% SBZ ceramic. While, the decrease of average grain size and superior densification resulting from the low sintering temperature, are also beneficial to the high breakdown strength. The BST-BMZ + 2 wt% SBZ ceramic achieves the optimum comprehensive properties with the maximum energy storage density of 2.13 J/cm3 and the remarkable efficiency of 94.1%. The addition of SBZ glass reduces the sintering temperature of BST-BMZ ceramic and improves the energy storage performance. The results indicate that the BST-BMZ + 2 wt% SBZ ceramic is a potential dielectric material for multilayer ceramic capacitors.

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The datasets generated during and analysed during the current study are not publicly available but are available from the corresponding author on reasonable request.

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Authors and Affiliations

  1. State Key Laboratory Environment-Friendly Energy Materials, School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang, 621010, People’s Republic of China

    Hang Xu, Jingsong Liu, Pingping Luo & Mengshi Zeng

  2. State Key Lab of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu, 610054, People’s Republic of China

    Jingsong Liu

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All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by HX and PL. Revised it critically for important intellectual content by JL and MZ. The first draft of the manuscript was written by HX and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Xu, H., Liu, J., Luo, P. et al. Low temperature sintering and energy storage properties of 0.8Ba0.2Sr0.8TiO3–0.2Bi(Mg0.5Zr0.5)O3 ceramic with additive of SrO–B2O3–ZnO glass. J Mater Sci: Mater Electron 34, 1048 (2023). https://doi.org/10.1007/s10854-023-10352-7

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