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Achieving high-temperature resistance and excellent insulation property of epoxy by introducing triazine ring structure

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Abstract

The rapidly growing third-generation wide-band-gap semiconductor electronic device industry urgently requires high-temperature-resistant packaging materials. However, the epoxy molding compound materials cannot suffer the high-temperature working condition due to the intrinsic molecular chain structure of epoxy materials (EP). In this paper, bisphenol A-type cyanate (BADCy) with triazine ring structure was introduced into EP to improve its heat resistance. The curing reaction as well as the curing mechanism has been clearly revealed for BADCy/EP with different contents of BADCy according to the Fourier transform infrared spectroscopy (FTIR) and differential scanning calorimeter (DSC) results. In the whole copolymer system, the copolymer at higher BADCy concentration (50–60 mol%) achieved the highest crosslink density (12.8 × 10–3 mol/cm3), thus, showing excellent glass transition temperature (> 200 °C) and thermal decomposition temperature(T5% > 400 °C). The heat resistance and electrical insulation property of BADCy/EP system have been systematically investigated, and a balance between high heat resistance and good electrical insulation are achieved at 66 mol% BADCy content, where the glass transition temperature reaches 215 °C, which is 73 °C higher than that of the EP system of anhydride copolymer. The volume resistivity of 1.5 × 1015 Ω·m and dielectric constant of 3.3 is obtained, indicating excellent electrical insulation and dielectric properties of BADCy/EP. This work provides a facile and efficient strategy to improve the overall properties of EP by optimizing the molecular chain structure.

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Data availability

The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

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Funding

This work was supported by the National Natural Science Foundation of China (Nos. U20A20308, 51977050, 52277024), Heilongjiang Provincial Natural Science Foundation of China (ZD2020E009), China Postdoctoral Science Foundation (Nos. 2021T140166, 2018M640303), University Nursing Program for Young Scholars with Creative Talents in Heilongjiang (No. UNPYSCT-2020178, UNPYSCT-2020180).

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Authors and Affiliations

  1. China School of Electrical & Electronic Engineering, Harbin University of Science and Technology, 52 Xuefu Road, Harbin, 150080, Heilongjiang, People’s Republic of China

    Xinle Zhang, Qingguo Chi, Chao Tang, Hua Li, Changhai Zhang, Zhonghua Li & Tiandong Zhang

  2. Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, 52 Xuefu Road, Harbin, 150080, Heilongjiang, People’s Republic of China

    Xinle Zhang, Qingguo Chi, Chao Tang, Hua Li, Changhai Zhang, Zhonghua Li & Tiandong Zhang

Authors
  1. Xinle Zhang
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  2. Qingguo Chi
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  3. Chao Tang
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  4. Hua Li
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  5. Changhai Zhang
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  6. Zhonghua Li
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  7. Tiandong Zhang
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by XZ, QC, CT, HL, CZ, and ZL. The first draft of the manuscript was written by XZ, and revised by TZ. QC and TZ supervised this work. All authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Tiandong Zhang.

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Zhang, X., Chi, Q., Tang, C. et al. Achieving high-temperature resistance and excellent insulation property of epoxy by introducing triazine ring structure. J Mater Sci: Mater Electron 34, 638 (2023). https://doi.org/10.1007/s10854-023-10078-6

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