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NaNbO3-(Bi0.5La0.5)(Mg2/3Ta1/3)O3 lead-free ceramics achieve ultrafast discharge rate and excellent energy storage performance

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Abstract

Advanced energy storage ceramics are specially beneficial to pulsed power technologies on account of first-class reliability and ultrafast discharge rate. However, the inferior energy storage performance hinders their further applications in the field of energy storage. In this work, a comprehensive strategy was adopted to synthesize the (1 − x)NaNbO3-x(Bi0.5La0.5)(Mg2/3Ta1/3)O3 ((1 − x)NN-xBLMT) lead-free ceramics by traditional solid-state method. Polar nano-regions are generated and the grain size is reduced to the microscale by introducing complex ions of (Bi0.5La0.5)(Mg2/3Ta1/3)6+ into the NN ceramic. The enhanced recoverable energy storage density (Wr = 3.69 J/cm3) and a high efficiency (η = 78%) can be realized simultaneously in 0.90NN-0.10BLMT ceramic at 440 kV/cm. Moreover, the ceramic presents excellent thermal and frequency stability within the range of 20–100 °C and 1–100 Hz at 200 kV/cm, respectively. More noteworthy, an ultrafast discharge rate (t0.9 = 23.6 ns) can be achieved in 0.90NN-0.10BLMT ceramic at 120 kV/cm, which is better than that of other lead-free energy storage ceramics. These results show that 0.90NN-0.10BLMT ceramic has broad application prospects in lead-free dielectric ceramic capacitors.

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Acknowledgements

This work is supported by the National Natural Science Foundation of China (Grant No. 52172117) and the Key Research and Development Program of Shaanxi Province (Grant No. 2022GY-347).

Funding

Funding was provided by the National Natural Science Foundation of China (Grant No. 52172117) and the Key Research and Development Program of Shaanxi Province (Grant No. 2022GY-347).

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  1. Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi’an, 710021, China

    Chenjiao Liu, Haibo Yang, Renrui Hu & Ying Lin

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  1. Chenjiao Liu
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  2. Haibo Yang
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  3. Renrui Hu
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  4. Ying Lin
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Contributions

CL contributed to investigation, methodology, writing-original draft, writing-review, and editing. HY contributed to project administration, funding acquisition, visualization, and software. Renrui Hu contributed to writing-review and editing. YL contributed to supervision, resources, data curation, writing-review, and editing.

Corresponding author

Correspondence to Ying Lin.

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Liu, C., Yang, H., Hu, R. et al. NaNbO3-(Bi0.5La0.5)(Mg2/3Ta1/3)O3 lead-free ceramics achieve ultrafast discharge rate and excellent energy storage performance. J Mater Sci: Mater Electron 34, 668 (2023). https://doi.org/10.1007/s10854-023-10009-5

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  • DOI: https://doi.org/10.1007/s10854-023-10009-5

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