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Zinc Strontium Sulfide@Carbon nanotube composite electrode materials for high-performance supercapattery devices

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Abstract

High-performance energy storage devices (ESD) are essential to address the rising demand for electric energy. Hybrid energy storage systems provide moderate energy and power density as it merges batteries and supercapacitors. This study used the zinc strontium sulfide (ZnSrS) incorporated with carbon nanotube (CNT) for supercapattery devices. The surface area of CNT@ZnSrS was determined using Brunauer Emmett Teller (BET) calculations to be 17.73 m2g−1. A three-electrode configuration was used to compute the specific capacity of CNT, ZnSrS, and CNT@ZnSrS. The anticipated capacity for CNT@ZnSrS was 788 Cg−1, higher than individual ZnSrS and CNT. In the design of the supercapattery, CNT@ZnSrS served as a positive, while activated carbon was the negative electrode. The specific capacity of the supercapattery device (CNT@ZnSrS//AC) was 192 Cg−1. The supercapattery (CNT@ZnSrS//AC) delivers a superior energy density of 45.23 Wh-kg−1. Additionally, the stability test on the supercapattery device (CNT@ZnSrS//AC) was performed by submitting it to 10,000 consecutive charging/discharging cycles. After completing these cycles, this device shows excellent capacity retention of 91%. This research indicates that incorporating CNT significantly improves the electrochemical performance of ZnSrS as advanced material for energy in hybrid energy storage devices in the future.

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Acknowledgements

The authors thank the Deanship of Scientific Research at King Khalid University for funding this work through the Small Groups Project under Grant Number (R.G.P.1/153/43). Princess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2023R184), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia. The authors would like to thank Riphah International University for supporting this research under project number Riphah- ORIC-22/FEAS-12

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Authors and Affiliations

  1. Department of Physics, Riphah International University, Campus Lahore, Lahore, Pakistan

    Haseebul Hassan, Muhammad Waqas Iqbal & Amir Muhammad Afzal

  2. Department of Physics, College of Science, Princess Nourah Bint Abdulrahman University, P.O. Box 84428, Riyadh, 11671, Saudi Arabia

    Soumaya Gouadria

  3. Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha, Saudi Arabia

    H. H. Hegazy

  4. Research Center for Advanced Materials Science (RCAMS), King Khalid University, P. O. Box 9004, Abha, 61413, Saudi Arabia

    H. H. Hegazy

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  1. Haseebul Hassan
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  4. Amir Muhammad Afzal
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HuH, MWI and AMA, and SG worked on experiments, data collection, analysis, and interpretation of results. HuH, MWI and AMA, HHH performed the calculation and wrote the manuscript. HuH, MI and AMA helped with the calculation and reviewed the manuscript. All the authors read the approved final manuscript.

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Correspondence to Muhammad Waqas Iqbal.

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Hassan, H., Iqbal, M.W., Gouadria, S. et al. Zinc Strontium Sulfide@Carbon nanotube composite electrode materials for high-performance supercapattery devices. J Mater Sci: Mater Electron 34, 439 (2023). https://doi.org/10.1007/s10854-023-09892-9

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