Abstract
InGaN/GaN multiple quantum well-based light-emitting diode LEDs were investigated over a wide range of injection currents (0.04 mA–0.1 A) and temperature (80–370 K)-dependent electroluminescence EL measurements. Two centers were identified for blue luminescence peaking at 2.9 eV and 3.0 eV, denoted as BL2 and BL\(_\text {C}\), respectively. Although the 3.0 eV center was more effective than 2.9 eV under low temperature (below 160 K), both vanished completely above 170 K due to the activation of non-radiative recombination under a low-current injection regime. At the same time, EL signal intensity was significantly reduced at a high-current injection regime. The recombination through a point trap in GaN barrier layer (known as H1 trap) in InGaN/GaN multi-quantum well structure was non-radiative recombination process: this leads to either vanishing or weakening of 3.0 eV center and its energy depth were determined as 0.9 eV through temperature-dependent dc current–voltage (I–V) and ac capacitance–temperature–frequency (C–T–\(\omega \)) measurements. The trap depth, thermal quenching of the peak at 3.0 eV, and the sole presence of a peak at 2.9 eV at high temperature might be ascribed to carbon-related defects and agreed with recent theoretical and experimental works in literature.
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References
F. Zimmermann, J. Beyer, C. Röder, F.C. Beyer, E. Richter, K. Irmscher, J. Heitmann, Current status of carbon-related defect luminescence in GaN. Phys. Stat. Sol. A 218, 2100235 (2021). https://doi.org/10.1002/pssa.202100235
I. Akasaki, H. Amano, Breakthroughs in improving crystal quality of GaN and invention of the p–n junction blue-light-emitting diode. Jpn. J. Appl. Phys. 45(12), 9001–9010 (2006). https://doi.org/10.1143/JJAP.45.9001
C. Li, Z. Ji, J. Li, M. Xu, H. Xiao, X. Xu, Electroluminescence properties of InGaN/GaN multiple quantum well-based LEDs with different indium contents and different well widths. Sci. Rep. 1, 15301 (2017). https://doi.org/10.1038/s41598-017-15561-9
S. Krishna, N. Aggarwal, M. Mishra, K.K. Maurya, M. Kaur, G. Sehgal, S. Singh, N. Dilawar, B. Gupta, G. Gupta, Epitaxial growth of high In-content In0. 41Ga0. 59N/GaN heterostructure on (11–20) Al\(_2\)O\(_3\) substrate. J. Alloys Compd. 658, 470–475 (2016). https://doi.org/10.1016/j.jallcom.2015.10.201
J. Liu, Z. Jia, S. Ma, H. Dong, G. Zhai, B. Xu, Enhancement of carrier localization effect and internal quantum efficiency through In-rich InGaN quantum dots. Superlattices Microstruct. 113, 497–501 (2018). https://doi.org/10.1016/j.spmi.2017.11.026
J. Yang, D.G. Zhaoa, D.S. Jiang, S.T. Liu, P. Chen, J.J. Zhu, F. Liang, W. Liu, M. Li, Improvement of thermal stability of InGaN/GaN multiple-quantum-well by reducing the density of threading dislocations. Opt. Mater. 85, 14–17 (2018). https://doi.org/10.1016/j.optmat.2018.08.030
X. Xu, Q. Wang, C. Li, Z. Ji, M. Xu, H. Yang, X. Xu, Enhanced localisation effect and reduced quantum-confined Stark effect of carriers in InGaN/GaN multiple quantum wells embedded in nanopillar. J. Lumin. 203, 216–221 (2018). https://doi.org/10.1016/j.jlumin.2018.06.024
J. Piprek, Efficiency droop in nitride based light emitting diodes. Phys Stat. Sol. A 207(10), 2217 (2010). https://doi.org/10.1002/pssa.201026149
D.S. Meyaard, G.B. Lin, Q. Shan, J. Cho, S.E. Fred, H. Shim, M.H. Kim, C. Sone, Asymmetry of carrier transport leading to efficiency droop in GaInN based light-emitting diodes. Appl. Phys. Lett. 99(25), 251115 (2011). https://doi.org/10.1063/1.3671395
D. Zhu, A.N. Noemaun, M.F. Schubert, J. Cho, E.F. Schubert, M.H. Crawford, D.D. Koleske, Enhanced electron capture and symmetrized carrier distribution in GaInN light-emitting diodes having tailored barrier doping. Appl. Phys. Lett. 96(12), 121110 (2010). https://doi.org/10.1063/1.3371812
Y.C. Shena, G.O. Mueller, S. Watanabe, N.F. Gardner, A. Munkholm, M.R. Krames, Auger recombination in InGaN measured by photoluminescence. Appl. Phys. Lett. 91(14), 141101 (2007). https://doi.org/10.1063/1.2785135
A.A. Efremov, N.I. Bochkareva, R.I. Gorbunov, D.A. Larinovich, Y.T. Rebane, D.V. Tarkhin, Y.G. Shreter, Effect of the joule heating on the quantum efficiency and choice of thermal conditions for high-power blue InGaN/GaN LEDs. Semiconductors 40, 605 (2006). https://doi.org/10.1134/S1063782606050162
S. Hammersley, D. Watson-Parris, P. Dawson, M.J. Godfrey, T.J. Badcock, M.J. Kappers, C. McAleese, R.A. Oliver, C.J. Humphreys, The consequences of high injected carrier densities on carrier localization and efficiency droop in InGaN/GaN quantum well structures. J. Appl. Phys. 111(8), 083512 (2012). https://doi.org/10.1063/1.3703062
M.A. Reshchikov, J.D. McNamara, M. Toporkov, V. Avrutin, H. Morkoç, A. Usikov, H. Helava, Y. Makarov, Determination of the electron-capture coefficients and the concentration of free electrons in GaN from time-resolved photoluminescence. Sci. Rep. 30(6), 37511 (2016). https://doi.org/10.1038/s41598-020-59033-z
M.A. Reshchikov, A. Usikov, H. Helava, Y. Makarov, V. Prozheeva, I. Makkonen, F. Tuomisto, J.H. Leach, K. Udwary, Evaluation of the concentration of point defects in GaN. Sci. Rep. 7(1), 1–11 (2017). https://doi.org/10.1038/s41598-017-08570-1
Y.S. Yoo, J.H. Na, S.J. Son, Y.H. Cho, Effective suppression of efficiency droop in GaN-based light-emitting diodes: role of significant reduction of carrier density and built-in field. Sci. Rep. 6(1), 1–9 (2016). https://doi.org/10.1038/srep34586
I.H. Lee, A.Y. Polyakov, N.B. Smirnov, I.V. Shchemerov, P.B. Lagov, R.A. Zinov’Ev, E.B. Yakimov, K.D. Shcherbachev, S.J. Pearton, Point defects controlling non-radiative recombination in GaN blue light emitting diodes: Insights from radiation damage experiments. J. Appl. Phys. 122(11), 115704 (2017). https://doi.org/10.1063/1.5000956
J. Wu, W. Walukiewicz, M.K. Yu, J.W. Ager III, E.E. Haller, J. William, Small band gap bowing in In\(_{1- x}\) Ga\(_{ x}\)N alloys. Appl. Phys. Lett. 80(25), 4741–4743 (2002). https://doi.org/10.1063/1.1489481
K. Dogheche, B. Alshehri, G. Patriache, E. Dogheche, Development of micron sized photonic devices based on deep GaN etching. Photonics 8(3), 68 (2021). https://doi.org/10.3390/photonics8030068
A.M. Lampert, P. Mark, Current Injection in Solids (Academic Press, Cambridge, 1970). https://doi.org/10.1016/S0080-8784(08)62630-7
A. Hierro, S.A. Ringel, M. Hansen, J.S. Speck, U.K. Mishra, S.P. DenBaars, Hydrogen passivation of deep levels in n-GaN. Appl. Phys. Lett. 77, 1499–1501 (2000). https://doi.org/10.1063/1.1290042
J.L. Lyons, A. Janotti, C.G. Van De Walle, Carbon impurities and the yellow luminescence in GaN. Appl. Phys. Lett. 97(15), 152108 (2010). https://doi.org/10.1063/1.3492841
J.L. Lyons, A. Janotti, C.G. Van De Walle, Effects of carbon on the electrical and optical properties of InN, GaN, and AlN. Phys. Rev. B 89(3), 035204 (2014). https://doi.org/10.1103/PhysRevB.89.035204
Acknowledgements
This work was supported by a Research Fund of the Yıldız Technical University under contract numbers FBA-2022-4983, FBA-2021-4559 and FDK-2019-3525. We are grateful to Prof. Dr. Ayşe Erol and her team for performing photoluminescence measurements.
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The fabrication of the structure and TEM, EDS, and XRD measurements were performed by BA, KD, and ED. E–L and I–V measurements and writing of the article were performed by NAK, OÖ, KB, and HB. All authors read and approved the final manuscript.
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Ayarcı Kuruoğlu, N., Özdemir, O., Bozkurt, K. et al. Investigation of luminescence centers inside InGaN/GaN multiple quantum well over a wide range of temperature and injection currents. J Mater Sci: Mater Electron 33, 19151–19159 (2022). https://doi.org/10.1007/s10854-022-08752-2
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DOI: https://doi.org/10.1007/s10854-022-08752-2