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Study on electrochemical properties of active coating PbO2-CeO2 reinforced Al-based composite coating electrode

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Abstract

In this paper, Al/TiB2 + 10%Ti4O7/PbO2-xCeO2 composite electrode materials were prepared by thermal spraying technology and electrochemical deposition method. The microstructure of the coatings with different contents of Ce3+ was observed by scanning electron microscope, and the phase composition of the coatings was analyzed by X-ray diffractometer. The electrochemical properties of the electrodes were studied by Tafel, EIS, LSV, and CV. The results show that with the increase of Ce3+ concentration, the overall performance of the electrode is improved, but when the content exceeds 1.5 g/L, it will cause agglomeration and reduce the electrode performance. Therefore, when the Ce3+ concentration is 1.5 g/L, the comprehensive performance and effect of the electrode are the best. Moreover, it can be seen from the SEM image that after adding Ce3+, the grains are denser than that of the composite anode without addition.

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The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

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Funding

The authors are grateful for the financial support from the National Natural Science Foundation of People's Republic of China (NSFC52161024), Yunnan Ten Thousand Talents Plan Young & Elite Talents Project (YNWR-QNJ-2018-044).

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Authors and Affiliations

  1. Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, 650093, Yunnan, People’s Republic of China

    Shenggang Zhou, Jihao Duan, Yang Xu, Daxin Zhang, Tao Li, Junfeng Liu, Peng Wang & Yong Cao

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  1. Shenggang Zhou
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  2. Jihao Duan
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  3. Yang Xu
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  4. Daxin Zhang
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  5. Tao Li
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  7. Peng Wang
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  8. Yong Cao
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All authors contributed to the study conception and design. All authors have given approval to the final version of the manuscript.

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Correspondence to Yong Cao.

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Zhou, S., Duan, J., Xu, Y. et al. Study on electrochemical properties of active coating PbO2-CeO2 reinforced Al-based composite coating electrode. J Mater Sci: Mater Electron 33, 17223–17234 (2022). https://doi.org/10.1007/s10854-022-08599-7

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  • DOI: https://doi.org/10.1007/s10854-022-08599-7

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