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The Ba(Bi0.5Ta0.5)O3 modified (K0.5Na0.5)NbO3 lead-free transparent ferroelectric ceramics with high transmittance and excellent energy storage performance

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Abstract

For solving the contradiction that good optical properties and electrical properties of (K0.5Na0.5)NbO3 (KNN)-based transparent ferroelectric ceramics cannot be achieved at the same time. The modification by doping and improved sintering techniques can not only increase the optical properties of ceramics but also improve and enhance the electrical properties of ceramics. (1 − x)(K0.5Na0.5)NbO3–xBa(Bi0.5Ta0.5)O3 (x = 0.01, 0.015, 0.02, 0.025, 0.03) lead-free transparent ferroelectric ceramics were synthesized by conventional solid-phase sintering method. The KNN ceramic was modified by Ba(Bi0.5Ta0.5)O3 to obtain a large optical band gap energy, submicron grains, and a highly symmetric phase structure when x = 0.025, thus gaining highly transmittance of 67.2% in near-infrared region. The smaller grain size and dense microstructure give the ceramic with x = 0.025 a higher dielectric breakdown strength. Therefore, the excellent energy storage performance is achieved at high electric field of 200 kV/cm with energy storage density (Wrec) and energy storage efficiency (η) of 1.41 J/cm3 and 42%, respectively. The results show that (K0.5Na0.5)NbO3–Ba(Bi0.5Ta0.5)O3 ceramics are considered to be excellent candidates for the field of new transparent electronic devices.

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Funding

This work was supported by the National Nature Science Foundation of China (Project No. 61965007), Guangxi Nature Science Foundation, People’s Republic of China (Project No. 2018GXNSFDA281042) and Guangxi Key Laboratory of Information Materials (Guilin University of Electronic Technology), People’s Republic of China (Project No. 201007-Z).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin, 541004, People’s Republic of China

    Huangtao Wu, Shaoyang Shi, Xiang Liu, Hua Wang, Jiwen Xu, Ling Yang, Wei Qiu & Shangju Zhou

  2. Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, Guilin, 541004, People’s Republic of China

    Hua Wang & Jiwen Xu

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  1. Huangtao Wu
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Contributions

All authors jointly participated in the data collection and experimental program exploration. Data collection, analysis and initial manuscript were completed by first author: HW. Revision and refinement of the manuscript was performed by the corresponding author: HW and the manuscript is published with the consent of all authors.

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Correspondence to Hua Wang.

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Wu, H., Shi, S., Liu, X. et al. The Ba(Bi0.5Ta0.5)O3 modified (K0.5Na0.5)NbO3 lead-free transparent ferroelectric ceramics with high transmittance and excellent energy storage performance. J Mater Sci: Mater Electron 33, 16045–16055 (2022). https://doi.org/10.1007/s10854-022-08496-z

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