Abstract
It has been a major challenge to develop a gas sensor capable of detecting ppb-level ammonia (NH3) with high response at low temperature. Herein, Cu2O nanoblocks uniformly dispersed on wrinkle structure of reduced graphene oxide (rGO)-based nanocomposites synthesized via a water bath heating method. Characterizations results illustrate that Cu2O nanoblocks are evenly dispersed on the surface of rGO. Additionally, The gas sensing experiments displayed that the as-obtained rGO/Cu2O nanocomposites exhibited the extremely fast response (1s) and recovery time (1s), high-performance gas sensing property for ultra-low concentration (5 ppb) NH3 detections at low temperature (80 °C), which owe to the mesoporous structure, excellent charge carriers transport properties and large specific surface area. Meanwhile, the probable enhancing mechanism of rGO/Cu2O nanocomposites was discussed as well. Therefore, it is expected that rGO/Cu2O nanocomposites with remarkable sensing performance for the future development in monitoring and detecting NH3 at low temperature.
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References
X. Gao, T. Zhang, An overview: facet-dependent metal oxide semiconductor gas sensors. Sens. Actuators B 277, 604–633 (2018)
H.Y. Gao, J. Guo, Y.W. Li, C.L. Xie, X. Li, L. Liu, Y. Chen, P. Sun, F.M. Liu, X. Yan, F.M. Liu, G.Y. Lu, Highly selective and sensitive xylene gas sensor fabricated from NiO/NiCr2O4 p-p nanoparticles. Sens. Actuators B 284, 305–315 (2019)
Y.S. Xu, L.L. Zheng, C. Yang, X.H. Liu, J. Zhang, Highly sensitive and selective electronic sensor based on Co catalyzed SnO2 nanospheres for acetone detection. Sens. Actuators B Chem. 304, 127237 (2020)
D.Z. Zhang, Z.L. Wu, X.Q. Zong, Flexible and highly sensitive H2S gas sensor based on in-situ polymerized SnO2/rGO/PANI ternary nanocomposite with application in halitosis diagnosis. Sens. Actuators B 289, 32–41 (2019)
M.D. Das, SarkarOne-pot synthesis of zinc oxide-polyaniline nanocomposite for fabrication of efficient room temperature ammonia gas sensor. Ceram. Int. 43, 11123–11131 (2017)
A.M. Soleimanpour, A.H. Jayatissa, G. Sumanasekera, Surface and gas sensing properties of nanocrystalline nickel oxide thin films. Appl. Surf. Sci. 276, 291–297 (2013)
P. Dhivya, A.K. Prasad, M. Sridharan, Nanostructured TiO2 films: enhanced NH3 detection at room temperature. Ceram. Int. 40, 409–415 (2014)
H.H. Yan, P. Song, S. Zhang, Z.X. Yang, Q. Wang, Facile synthesis, characterization and gas sensing performance of ZnO nanoparticles-coated MoS2 nanosheets. J. Alloys Compd. 662, 118–125 (2016)
D. Kwak, Y. Lei, R. Maric, Ammonia gas sensors: a comprehensive review. Talanta 204, 713–730 (2019)
S.R. Ryu, S.D.G. Ram, H.D. Cho, D.J. Lee, T.W. Kang, Y. Woo, Single ZnO nanocactus gas sensor formed by etching of ZnO nanorod. Nanoscale 7, 11115–11122 (2015)
N. Yu, H. Zhang, S.D. Davidson, J.M. Sun, Y. Wang, Effect of ZnO facet on ethanol steam reforming over Co/ZnO. Catal. Commun. 73, 93–97 (2016)
A. Sharma, P. Bhojane, A.K. Rana, Y. Kumar, P.M. Shirage, Mesoporous nickel cobalt hydroxide/oxide as an excellent room temperature ammonia sensor. Scr. Mater. 128, 65–68 (2017)
S. Zhang, P. Zhang, A. Xie, S. Li, F. Huang, Y. Shen, A Novel 2D porousprintfabric-like α-Fe2O3 sheet with high performance as the anode material forlithium-ion battery. Electrochim. Acta. 212, 912–920 (2016)
H. Manisha, P.D. Priya Swetha, Y.B. Shim, K.S. Prasad, Microwave assisted synthesis of hybrid Cu2O microcubes for photocatalysis and electrocatalysis. Mater. Today 5, 16390–16393 (2018)
Y.S. Xu, W. Zheng, X.H. Liu, L.Q. Zhang, L.L. Zheng, C. Yang, N. Pinna, J. Zhang, Platinum single atoms on tin oxide ultrathin films for extremely sensitive gas detection. Mater. Horiz. 7, 1519 (2020)
G.L. Lei, C.M. Lou, X.H. Liu, J.Y. Xie, Z.S. Li, W. Zheng, J. Zhang, Thin films of tungsten oxide materials for advanced gas sensors. Sens. Actuators B: Chem. 341, 129996 (2021)
G.Q. Liu, Y. Zhou, C. Zou, X.Y. Zhu, Y.C. Guo, Heat-pulse assisted NH3 gas sensing based on cuprous oxide nanocomposites anchored on reduced graphene oxide nanosheets. Mater. Electron. 29, 3317–3325 (2018)
L.Y. Hong, H.W. Ke, C.E. Tsai, H.N. Lin, Low concentration NO gas sensing under ambient environment using Cu2O nanoparticle modified ZnO nanowires. Mater. Lett. 185, 243–246 (2016)
S.X. Cao, T. Han, L.L. Peng, C. Zhao, J. Wang, Hydrothermal synthesis, characterization and gas sensing properties of novel Cu2O open hollow nanospheres. Ceram. Int. 43, 4721–4724 (2017)
S.Q. Zhou, M.P. Chen, Q.J. Lu, J. Hu, H.P. Wang, K. Li, K.J. Li, J. Zhang, Z.Q. Zhu, Q.J. Liu, Design of hollow dodecahedral Cu2O nanocages for ethanol gas sensing. Mater. Lett. 247, 15–18 (2019)
M.A. Worsley, S.O. Kucheyev, H.E. Mason, M.D. Merrill, B.P. Mayer, J. Lewicki, C.A. Valdez, M.E. Suss, M. Stadermann, P.J. Pauzauskie, J.H. Satcher Jr., J. Biener, T.F. Baumann, Mechanically robust 3D graphene macroassembly with high surface area. Chem. Commun. 48, 8428–8430 (2012)
H.D. Pham, V.H. Pham, T.V. Cuong, T.D.N. Phan, J.S. Chung, E.W. Shin, S. Kim, Synthesis of the chemically converted graphene xerogel with superior electrical conductivity. Chem. Commun. 47, 9672–9674 (2011)
S. Yi, Q. Fang, B.L. Chen, Environmental applications of three-dimensional graphene-based macrostructures: adsorption, transformation, and detection. Environ. Sci. Technol. 49, 67–84 (2015)
Q.J. Xiang, B. Cheng, J.G. Yu, Graphene-based photocatalysts for solar-fuel generation. Angew. Chem. Int. Ed. 54, 2–19 (2015)
J. Zhang, L.F. Qi, J.R. Ran, J.G. Yu, S.Z. Qiao, Ternary NiS/ZnxCd1−xS/reduced graphene oxide nanocomposites for enhanced solar photocatalytic H2-production activity. Adv. Energy Mater. 4, 1301925 (2014)
J. Zhang, D.W. Zeng, H. Wang, Z.Y. Qin, A.M. Pang, C.S. Xie, Highly responsive chemical sensing on NO2 at room temperature based on reduced porous graphene. Mater. Lett. 204, 27–30 (2017)
C. Zhao, X. Wu, P. Li, C. Zhao, X. Qian, Hydrothermal deposition of CuO/rGO/Cu2O nanocomposite on copper foil for sensitive nonenzymatic voltammetric determination of glucose and hydrogen peroxide. Microchim. Acta. 184, 2341–2348 (2017)
Y. Zhou, X. Lin, Y. Wang, G. Liu, X. Zhu, Y. Huang, Y. Guo, C. Gao, M. Zhou, Study on gas sensing of reduced graphene oxide/ZnO thin film at room temperature. Sens. Actuators B. 240, 870–880 (2017)
J. Lee, A. Katoch, S. Choi, J. Kim, H.W. Kim, S.S. Kim, Extraordinary improvement of gas-sensing performances in SnO2 nanofibers due to creation of local p-n heterojunctions by loading reduced graphene oxide nanosheets. ACS Appl. Mater. Interfaces 7, 3101–3109 (2015)
R. Ghosh, A.K. Nayak, S. Santra, D. Pradhan, P.K. Guha, Enhanced ammonia sensing at room temperature with reduced graphene oxide/tin oxide hybrid film. RSC Adv. 5(62), 50165–50173 (2015)
H. Tai, Z. Yuan, W. Zheng, Z. Ye, C. Liu, X. Du, ZnO nanoparticles/reduced graphene oxide bilayer thin films for improved NH3-sensing performances at room temperature. Nanoscale Res. Lett 11, 1–8 (2016)
X. Liu, J.S. Cui, J.B. Sun, X.T. Zhang, 3D graphene aerogel-supported SnO2 nano particles for efficient detection of NO2. RSC Adv. 4, 22601–22605 (2014)
P. Song, D. Han, H.H. Zhang, J. Li, Z.X. Yang, Q. Wang, Hydrothermal synthesis of porous In2O3 nanospheres with superior ethanol sensing properties. Sens. Actuators B 196, 434–439 (2014)
M. Liu, Z.Y. Wang, P. Song, Z.X. Yang, Q. Wang, Flexible MXene/rGO/CuO hybrid aerogels for high performance acetone sensing at room temperature. Sens. Actuators B Chem. 340, 129946 (2021)
S.H. Liu, Y.S. Wei, J.S. Lu, Visible-light-driven photodegradation of sulfamethoxazole and methylene blue by Cu2O/rGO photocatalysts. Chemosphere 154, 118–123 (2016)
T.K. Aparna, R. Sivasubramanian, M.A. Dar, One-pot synthesis of Au-Cu2O/rGO nanocomposite based electrochemical sensor for selective and simultaneous detection of dopamine and uric acid. J. Alloys Compd. 741, 1130–1141 (2018)
Y.C. Pu, H.Y. Chou, W.S. Kuo, K.H. Wei, Y.J. Hsu, Interfacial charge carrier dynamics of cuprous oxide-reduced graphene oxide (Cu2O-rGO) nanoheterostructures and their related visible-light-driven photocatalysis. Appl. Catal. B 204, 21–32 (2017)
A. Abulizi, G.H. Yang, J.J. Zhu, One-step simple sonochemical fabrication and photocatalytic properties of Cu2O-rGO composites. Ultrason. Sonochem. 21, 129–135 (2014)
J.Y. Cai, W.J. Liu, Z.H. Li, One-pot self-assembly of Cu2O/RGO composite aerogel for aqueous photocatalysis. Appl. Surf. Sci. 358, 146–151 (2015)
K. Wang, X.M. Dong, C.J. Zhao, X.Z. Qian, Y.L. Xu, Facile synthesis of Cu2O/CuO/RGO nanocomposite and its superior cyclability in supercapacitor. Electrochim. Acta 152, 433–442 (2015)
V.D. Botcha, D.S. Sutar, S.S. Major, Study of GO-Cu2O and RGO-Cu nanocomposite monolayer sheets prepared by modified Langmuir Blodgett route. J. Phys. Chem. Solids 118, 158–165 (2018)
T.K. Aparna, R. Sivasubramanian, Mushtaq Ahmad Dar, One-pot synthesis of Au-Cu2O/rGO nanocomposite based electrochemical sensor for selective and simultaneous detection of dopamine and uric acid. J. Alloys Compd. 741, 1130–1141 (2018)
H.J. Huang, J.Z. Zhang, L. Jiang, Z.G. Zang, Preparation of cubic Cu2O nanoparticles wrapped by reduced graphene oxide for the efficient removal of rhodamine B. J. Alloys Compd. 718, 112–115 (2017)
J.S. Kumar, M. Jana, P. Khanra, P. Samanta, T. Kuila, One pot synthesis of Cu2O/RGO composite using mango bark extract and exploration of its electrochemical properties. Electrochim. Acta 193, 104–115 (2016)
Z.Q. Yang, X.P. Hao, S.G. Chen, Z.Q. Ma, Z.H. Guo, Long-term antibacterial stable reduced graphene oxide nanocomposites loaded with cuprous oxide nanoparticles. J. Colloid Interface Sci. 533, 13–23 (2019)
K. Sharma, K. Maiti, N.H. Kim, D. Hui, J.H. Lee, Green synthesis of glucose-reduced graphene oxide supported Ag-Cu2O nanocomposites for the enhanced visible-light photocatalytic activity. Composites B 138, 35–44 (2018)
S. Shahrokhian, S. Rezaee, Vertically standing Cu2O nanosheets promoted flower-like PtPd nanostructures supported on reduced graphene oxide for methanol electro-oxidation. Electrochim. Acta 259, 36–47 (2018)
X. Jie, D. Zeng, J. Zhang, K. Xu, J. Wu, B. Zhu, C. Xie, Graphene-wrapped WO3 nanospheres with room-temperature NO2 sensing induced by interface charge transfer. Sens. Actuators B 220, 201–209 (2015)
F. Yan, G. Shen, X. Yang, T. Qi, J. Sun, X. Li, M. Zhang, Low operating temperature and highly selective NH3 chemiresistive gas sensors based on Ag3PO4 semiconductor. Appl. Surf. Sci. 479, 1141–1147 (2019)
Q. Feng, X. Li, J. Wang, A.M. Gaskov, Reduced graphene oxide (rGO) encapsulated Co3O4 composite nanofibers for highly selective ammonia sensors. Sens. Actuators B 222, 864–870 (2016)
Y.L. Wang, J. Liu, X.B. Cui, Y. Gao, J. Ma, Y.F. Sun, P. Sun, F.M. Liu, X.S. Liang, T. Zhang, G.Y. Lu, NH3 gas sensing performance enhanced by Pt-loaded on mesoporous WO3. Sens. Actuators B 238, 473–481 (2017)
F. Shao, F. Hernández-Ramíreza, J.D. Prades, C. Fàbrega, T. Andreu, J.R. Morante, Copper (II) oxide nanowires for p-type conductometric NH3 sensing. Appl. Surf. Sci. 311, 177–181 (2014)
S. Kumar, A. Singh, R. Singh, S. Singh, P. Kumar, R. Kumar, Facile h-MoO3 synthesis for NH3 gas sensing application at moderate operating temperature. Sensor Actuators B-Chem 325, 128974 (2020)
V. Haridas, A. Sukhananazerin, J. Mary Sneha, B. Pullithadathil, B. Narayanan, Appl. Surf. Sci. 517, 146158 (2020)
T. Siciliano, M.D. Giulio, M. Tepore, E. Filippo, G. Micocci, A. Tepore, Ammonia sensitivity of rf sputtered tellurium oxide thin films. Sens. Actuators B Chem. 138, 550–555 (2009)
J.N. Deng, R. Zhang, L.L. Wang, Z. Lou, T. Zhang, Enhanced sensing performance of the Co3O4 hierarchical nanorods to NH3 gas. Sens. Actuators B Chem. 209, 449–455 (2015)
Y.L. Wang, J. Liu, X.B. Cui, Y. Gao, J. Ma, Y.F. Sun, P. Sun, F.M. Liu, X.S. Liang, T. Zhang, G.Y. Lu, NH3 gas sensing performance enhanced by Pt-loaded on mesoporousWO3. Sens. Actuators B 238, 473–481 (2017)
S.Y. Gong, J.Y. Chen, X.F. Wu, N. Han, Y.F. Chen, In-situ synthesis of Cu2O/reduced graphene oxide composite as effective catalyst for ozone decomposition. Catal. Commun. 106, 25–29 (2018)
L.L. Sun, G.H. Wang, R.R. Hao, D.Y. Han, S. Cao, Solvothermal fabrication and enhanced visible light photocatalytic activity of Cu2O-reduced graphene oxide composite microspheres for photodegradation of Rhodamine B. Appl. Surf. Sci. 358, 91–99 (2015)
M.S. Park, K.H. Kim, M.J. Kim, Y.S. Lee, NH3 gas sensing properties of a gas sensor based on fluorinated graphene oxide. Colloids Surf. A 490, 104–109 (2016)
X. Huang, N. Hu, L. Zhang, L. Wei, H. Wei, Y. Zhang, The NH3 sensing properties of gas sensors based on aniline reduced graphene oxide. Synth. Met. 185, 25–30 (2013)
H.W. Kima, Y.J. Kwon, A. Mirzaei, S.Y. Kang, M.S. Choi, J.H. Bang, S.S. Kim, Synthesis of zinc oxide semiconductors-graphene nanocomposites bymicrowave irradiation for application to gas sensors. Sens. Actuators B 249, 590–601 (2017)
Y. Zhang, Q. Wang, D. Liu, Q. Wang, T. Li, Z. Wang, Cu2O-BiOI isotype (p-p) heterojunction: boosted visible-light-driven photoelectrochemical activity for non-enzymatic H2O2 sensing. Appl. Surf. Sci. 521, 146434 (2020)
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This work was financially supported by National Natural Science Foundation of China (No. 61102006), and Natural Science Foundation of Shandong Province, China (No. ZR2018LE006).
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Sima, Z., Ma, Z., Song, P. et al. Ultra-low concentration detection of NH3 using rGO/Cu2O nanocomposites at low temperature. J Mater Sci: Mater Electron 32, 22617–22628 (2021). https://doi.org/10.1007/s10854-021-06746-0
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DOI: https://doi.org/10.1007/s10854-021-06746-0