Abstract
A metal–oxide–semiconductor (MOS) electroluminescence device based on erbium silicate nanocrystals and silicon nanocrystals co-embedded in silicon oxide films fabricated by reactive magnetron co-sputtering on silicon substrate is reported. It was found that annealing temperatures have great influence on the structural composition of the deposited films. Only at 1100 °C annealing temperature, erbium silicate nanocrystals and silicon nanocrystals co-embedded in silicon oxide films formed. The MOS devices based on films with 112.9 % excess Si annealed at 1100 °C exhibited the lowest 20 V threshold voltage, highest near-infrared electroluminescence intensity, and external quantum efficiency (1.64*10−3) at 1540 nm because these films can combine the excellent optical activity of crystalline erbium silicate with better conductivity improved by Si nanocrystals.
Similar content being viewed by others
References
S. Khasminskaya, F. Pyatkov, K. Słowik, S. Ferrari, O. Kahl, V. Kovalyuk, P. Rath, A. Vetter, F. Hennrich, M.M. Kappes, G. Gol’Tsman, A. Korneev, C. Rockstuhl, R. Krupke, H.P. Pernice, Fully integrated quantum photonic circuit with an electrically driven light source. Nat. Photon. 10(11), 727–732 (2016)
A.W. Elshaari, W. Pernice, K. Srinivasan, O. Benson , V. Zwiller, Hybrid integrated quantum photonic circuits. Nat. Photon. 14(5), 285–298 (2020)
The rise of, integrated quantum photonics. Nat. Photon. 14(5), 265 (2020)
A. Polman, F.C.J.M. van Veggel, Broadband sensitizers for erbium-doped planar optical amplifiers: review. J. Opt. Soc. Am. B Opt. Phys. 21(5), 871 (2004)
A. Polman, Erbium implanted thin film photonic materials. J. Appl. Phys. 82(1), 1–39 (1997)
G. Franzò, S. Coffa, F. Priolo, C. Spinella, Mechanism and performance of forward and reverse bias electroluminescence at 1.54 µm from Er-doped Si diodes. J. Appl. Phys. 81(6), 2784–2793 (1997)
S. Coffa, G. Franzò, F. Priolo, High efficiency and fast modulation of Er-doped light emitting Si diodes. Appl. Phys. Lett. 69(14), 2077–2079 (1996)
D.J. Eaglesham, J. Michel, E.A. Fitzgerald, D.C. Jacobson, J.M. Poate, J.L. Benton, A. Polman, Y.H. Xie, L.C. Kimerling, Microstructure of erbium-implanted Si. Appl. Phys. Lett. 58(24), 2797–2799 (1991)
H. Wen, J. He, J. Hong, S. Jin, Z. Xu, H. Zhu, J. Liu, G. Sha, F. Yue, Y. Dan, Efficient Er/O-doped silicon light‐emitting diodes at communication wavelength by deep cooling. Adv Opt Mater 8(18), 2000720 (2020)
P. Pellegrino, B. Garrido, J. Arbiol, C. Garcia, Y. Lebour, J.R. Morante, Site of Er ions in silica layers codoped with Si nanoclusters and Er. Appl. Phys. Lett. 88(12), 121915 (2006)
L. Rebohle, Y. Berencén, R. Wutzler, M. Braun, D. Hiller, J.M. Ramírez, B. Garrido, M. Helm, W. Skorupa, The electroluminescence mechanism of Er3 + in different silicon oxide and silicon nitride environments. J. Appl. Phys. 116(12), 123104 (2014)
S. Cueff, J. Manel Ramírez, J.A. Kurvits, Y. Berencén, R. Zia, B. Garrido, R. Rizk, C. Labbé, Electroluminescence efficiencies of erbium in silicon-based hosts. Appl. Phys. Lett. 103(19), 191109 (2013)
J.M. Ramírez, S. Cueff, Y. Berencén, C. Labbé, B. Garrido, Role of silicon excess in Er-doped silicon-rich nitride light emitting devices at 1.54 µm. J. Appl. Phys. 116(8), 83103 (2014)
S. Cueff, C. Labbé, O. Jambois, B. Garrido, X. Portier, R. Rizk, Thickness-dependent optimization of Er3 + light emission from silicon-rich silicon oxide thin films. Nanoscale Res. Lett. 6(1), 1–6 (2011)
Q. Fu, Y. Gao, D. Li, D. Yang, Sensitizing properties of luminescence centers on the emission of Er3 + in Si-rich SiO2 film. J. Appl. Phys. 119(20), 203106 (2016)
Y. Berencén, S. Illera, L. Rebohle, J.M. Ramírez, R. Wutzler, A. Cirera, D. Hiller, J.A. Rodríguez, W. Skorupa, B. Garrido, Luminescence mechanism for Er3 + ions in a silicon-rich nitride host under electrical pumping. J. Phys. D 49(8), 85106 (2016)
S. Yerci, R. Li, L. Dal Negro. Electroluminescence from Er-doped Si-rich silicon nitride light emitting diodes. Appl. Phys. Lett. 97(8): 81109 (2010)
S. Cueff, C. Labbé, L. Khomenkova, O. Jambois, P. Pellegrino, B. Garrido, C. Frilay, R. Rizk, Silicon-rich oxynitride hosts for 1.5µm Er3 + emission fabricated by reactive and standard RF magnetron sputtering. Mater. Sci. Eng. B 177(10), 725–728 (2012)
L. Xu, L. Jin, D. Li, D. Yang, Effects of excess silicon on the 1540 nm Er3 + luminescence in silicon rich oxynitride films. Appl. Phys. Lett. 103(7), 71101 (2013)
Y. Yang, L. Jin, X. Ma, D. Yang, Low-voltage driven visible and infrared electroluminescence from light-emitting device based on Er-doped TiO2/p+-Si heterostructure. Appl. Phys. Lett. 100(3), 31103 (2012)
Y. Yang, Y. Li, L. Xiang, X. Ma, D. Yang, Low-voltage driven ∼1.54 µm electroluminescence from erbium-doped ZnO/p+-Si heterostructured devices: energy transfer from ZnO host to erbium ions. Appl. Phys. Lett. 102(18), 181111 (2013)
S. Harako, S. Yokoyama, K. Ide, X. Zhao, S. Komoro, Visible and infrared electroluminescence from an Er-doped n-ZnO/p-Si light emitting diode. Phys. Status Solidi (a) 205(1), 19–22 (2008)
M. Miritello, R. Lo Savio, F. Iacona, G. Franzò, A. Irrera, A.M. Piro, C. Bongiorno, F. Priolo, Efficient luminescence and energy transfer in erbium silicate thin films. Adv. Mater. 19(12), 1582–1588 (2007)
K. Masaki, H. Isshiki, T. Kawaguchi, T. Kimura, The effect of annealing conditions on the crystallization of Er–Si–O formed by solid phase reaction. Opt. Mater. 28(6–7), 831–835 (2006)
H. Isshiki, M.J.A. de Dood, A. Polman, T. Kimura, Self-assembled infrared-luminescent Er-Si-O crystallites on silicon. Appl. Phys. Lett. 85(19), 4343 (2004)
H. Isshiki, A. Polman, T. Kimura, Fine structure in the Er-related emission spectrum from Er-Si-O matrices at room temperature under carrier mediated excitation. J. Luminescence 102–103, 819–824 (2003)
Y. Yin, K. Sun, W.J. Xu, G.Z. Ran, G.G. Qin, S.M. Wang, C.Q. Wang, 1.53 microm photo- and electroluminescence from Er(3+) in erbium silicate. J. Phys. Condens. Matter 21(1), 12204 (2009)
Y. Yin, X. Wang, G. Qin, Room temperature Er3 + 1.54 µm electroluminescence from Si-rich erbium silicate deposited by magnetron sputtering. J. Phys. D: Appl. Phys. 43(33), 335102 (2010)
B. Wang, R.M. Guo, X.J. Wang, L. Wang, L.Y. Hong, B. Yin, L.F. Gao, Z. Zhou, Near-infrared electroluminescence in ErYb silicate based light-emitting device. Opt. Mater. 34(8), 1371–1374 (2012)
Z. Ouyang, Y. Yang, J. Sun, Electroluminescent Yb2O3:Er and Yb2Si2O7:Er nanolaminate films fabricated by atomic layer deposition on silicon. Opt. Mater. 80, 209–215 (2018)
Y. Gao, H. Shen, D. Li, D. Yang, Efficient sensitized photoluminescence of Er silicate in silicon oxide films embedded with amorphous silicon clusters, part I: fabrication. Opt. Mater. Express 9(11), 4329 (2019)
Y. Gao, H. Shen, J. Cao, D. Li, D. Yang, Control of the formation and luminescent properties of polymorphic erbium silicates on silicon. Opt. Mater. Express 9(4), 1716 (2019)
F. Chiu, A review on conduction mechanisms in dielectric films. Adv. Mater. Sci. Eng. 2014, 1–18 (2014)
Acknowledgements
The authors appreciate the financial support from National Key R&D Program of China (2018YFB2200102).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
He, M., Yang, D. & Li, D. Electroluminescence from metal–oxide–semiconductor devices based on erbium silicate nanocrystals and silicon nanocrystals co-embedded in silicon oxide thin films. J Mater Sci: Mater Electron 32, 20659–20667 (2021). https://doi.org/10.1007/s10854-021-06579-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-021-06579-x