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Dielectric and optical spectroscopy of new polycrystalline ceramic for device applications

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Abstract

The polycrystalline double perovskite Li2GdFeTiO6 was synthesized through the solid-state mixed oxide method and its preliminary crystal structure was investigated by the XRD technique. The structure of the material was identified to be tetragonal with space group P4bm using POWD and MATCH software. The morphology of the sample was investigated through a scanning electron microscope (SEM) and the average grain size was found to be 3.82 μm using the intercept technique. The investigation of the perovskite phase and various vibrational modes were carried out through FTIR spectroscopic technique. The bandgap (Eg = 1.73 eV) and visible light sensitivity of the material were identified by UV–Visible spectroscopic operation carried in the range 200–700 nm. The dielectric and related properties were investigated as a function of frequency and temperature using an impedance analyzer (LCR meter). Room-temperature dielectric investigation suggests it may be useful for storage application. The transport activities investigated through conductivity, impedance, and modulus technique illustrate the significant influence of grains on transportation of charges.

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Authors and Affiliations

  1. Department of Physics, Central Institute of Technology, Kokrajhar (Deemed to be University, MHRD, Govt. of India), Assam, Kokrajhar, BTAD, 783370, India

    S. Bhattacharjee & B. N. Parida

  2. Department of Physics, Siksha O Anusandhan University (Deemed to be University), Khandigiri, Bhubaneswar, 751030, India

    R. K. Parida & Bhagyashree Mohanty

  3. Department of Chemistry, Siksha O Anusandhan University, (Deemed to be University), Khandigiri, Bhubaneswar, 751030, India

    N. C. Nayak

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  1. R. K. Parida
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  3. Bhagyashree Mohanty
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Parida, R.K., Bhattacharjee, S., Mohanty, B. et al. Dielectric and optical spectroscopy of new polycrystalline ceramic for device applications. J Mater Sci: Mater Electron 32, 13568–13580 (2021). https://doi.org/10.1007/s10854-021-05932-4

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