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Magnetism and magnetocaloric effect in iron-rich Pr2Fe14B intermetallics

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Abstract

We report on the structural, magnetic, and magnetoclaoric properties of nanocrystalline iron-rich intermetallic Pr2Fe14B, prepared using ball milling. The annealed sample is single-phase with the tetragonal structure [P42/mnm space group (136)]. The magnetic and magnetocaloric properties were studied using Landau theory around Curie temperature. Reasonable agreement was obtained between the magnetic entropy (− ∆SM) determined using Landau theory and that extracted using classical Maxwell relation. Pr2Fe14B system depicts an interesting value of maximum magnetic entropy change of 3.6 J/kg K at 1 T and a relative cooling power about 36 J/kg. Universal curves based on re-scale entropy change curves as well as Landau theory reveal the first-order magnetic transition of Pr2Fe14B intermetallic.

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Acknowledgements

This work was supported by (PHC MAGHREB project 15MAG07) and was partially supported by National Science Centre in Poland by the Grant 2015/19/B/ST8/02636.

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Nouri, K., Bouzidi, W., Bouhbou, M. et al. Magnetism and magnetocaloric effect in iron-rich Pr2Fe14B intermetallics. J Mater Sci: Mater Electron 32, 5548–5555 (2021). https://doi.org/10.1007/s10854-021-05277-y

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  • DOI: https://doi.org/10.1007/s10854-021-05277-y

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