Abstract
The novel temperature-stable microwave dielectric ceramics of Ce0.5Sm0.5O1.75 were fabricated via the mixed oxide reaction method, with the detail information including crystal phase, microstructure, sintering behavior and microwave dielectric properties being systematically investigated. For crystal phase, all the diffraction patterns were indexed as cubic fluorite-type structure with Fm-3m (225) space group and exhibited a single phase with no obvious peak position shift. The grain growth was analyzed by density and average grain size. For microwave dielectric properties of Ce0.5Sm0.5O1.75 ceramics, the dielectric constant value (εr) was dependent on density. The quality factors (Q × f values) were investigated considered with average grain size. And the temperature coefficient of resonant frequency (τf value) had no significant change during the sintering temperature range, which was found consistent with the trend of the dielectric constant value. The Ce0.5Sm0.5O1.75 ceramics sintered at 1475 °C for 4 h exhibited good microwave dielectric performances with εr = 18.21, Q × f = 70,500 GHz, and τf = − 16.4 ppm/°C.
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References
D.H. Kim, S.K. Lim, H. An, The microwave dielectric properties of xTiO2(1 – x)CeO2 ceramics. Mater. Lett. 52, 240–243 (2002)
Z.X. Wang, C.L. Yuan, B.H. Zhu, Q. Feng, F. Liu, J.W. Xu, C.R. Zhou, G.H. Chen, Sintering behavior, phase evolutions and microwave dielectric properties of LaGaO3-SrTiO3 ceramics modified by CeO2 additives. Ceram. Int. 44, 6601–6606 (2018)
Z.X. Fang, B. Tang, F. Si, S.R. Zhang, Influence of CeO2 on microstructure and microwave dielectric properties of Na1/2Sm1/2TiO3 ceramics. J. Mater. Sci.: Mater. Electron. 27, 1913–1919 (2015)
C. Peng, Y. Wang, K. Jiang, B.Q. Bin, H.W. Liang, J. Feng, J. Meng, Study on the structure change and oxygen vacation shift for Ce1 –xSmxO2–y solid solution. J. Alloy Compd. 349, 273–278 (2003)
H.L. Pan, Z.B. Feng, J.X. Bi, H.T. Wu, Preparation, characterization, and dielectric properties of wolframite-structure MnZrNb2O8 ceramics at microwave frequency. J. Alloy Compd. 651, 440–444 (2015)
W. Li, J.J. Qu, X. Wei, F. Liu, C.L. Yuan, G.H. Chen, Structural characteristics and microwave dielectric properties of a new Sm2O3-Nd2O3-MgO-CeO2 ceramic system. Mater. Chem. Phys. 207, 44–49 (2018)
S.B. Zhang, L.W. Shi, L.Y. Zhang, H.Y. Zhu, W.S. Xia, Synthesis and microwave dielectric properties of new high quality Mg2NdNbO6 ceramics. J. Am. Ceram. Soc. 3, 1014–1019 (2018)
P. Zhang, Z.K. Song, Y. Wang, L.X. Li, Effect of ion substitution for Nd3+ based on structural characteristic on the microwave dielectric properties of NdNbO4 ceramic system. J. Am. Ceram. Soc. 97, 976–981 (2014)
M. Parastoo, T.N. Ehsan, T.A. Hamid, Effect of zinc ions non-stoichiometry on the microstructure and microwave dielectric properties of Li2ZnTi3O8 ceramics. J. Alloy Compd. 695, 3772–3778 (2017)
Y.C. Chen, K.C. Chang, S.L. Yao, Improved microwave dielectric properties of Nd(Mg0.5Sn0.5)O3 ceramics by substituting Mg2+ with Zn2+. Ceram. Int. 38, 5377–5383 (2012)
W.S. Xia, L.Y. Zhang, Y. Wang, S.E. Jin, Y.P. Xu, Z.W. Zuo, L.W. Shi, Extrinsic effects on microwave dielectric properties of high-Q MgZrTa2O8 ceramics. J. Mater. Sci.: Mater. Electron. 27, 11325–11330 (2016)
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This work is supported by the projects from the Fundamental Research Funds for the Central Universities under Grant No. 2020ZDPYMS12.
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Wang, Y., Tang, TL., Deng, JY. et al. Sintering characteristics and microwave dielectric properties of a new temperature-stable ceramic of Ce0.5Sm0.5O1.75. J Mater Sci: Mater Electron 31, 19130–19135 (2020). https://doi.org/10.1007/s10854-020-04449-6
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DOI: https://doi.org/10.1007/s10854-020-04449-6