Abstract
Rare earth oxides Er2TiO5 photocatalysts supported on superparamagnetic Fe3O4@SiO2 core–shell nanostructures were prepared through a sol–gel method. The achieved magnetic nanostructures were characterized by a number of procedures such as XRD, FE-SEM, TEM, UV–Vis DRS, VSM and PL spectroscopy and then the activity of the magnetic nanostructures as a photocatalysts for the UV–Vis induced degradation of methyl orange was evaluated. The activity of Fe3O4@SiO2@Er2TiO5 were tested as photodegradation catalysts for removing methyl orange. Moreover, the effect of incorporating different amounts of erbium oxides in the photocatalysts was studied and it was found that the optimal amount of erbium oxide in terms of reaching the highest photocatalytic activity was 25 wt%.
Similar content being viewed by others
References
I. Prabha, S. Lathasree, Photodegradation of phenol by zinc oxide, titania and zinc oxide–titania composites: nanoparticle synthesis, characterization and comparative photocatalytic efficiencies. Mater. Sci. Semicond. Process. 26, 603–613 (2014)
Kommineni, S., et al. 3.0 Advanced oxidation processes. center for groundwater restoration and protection national water research institute, (2000)
M. Rahimi-Nasrabadi et al., Preparation of Co2TiO4/CoTiO3/Polyaniline ternary nano-hybrids for enhanced destruction of agriculture poison and organic dyes under visible-light irradiation. J. Mater. Sci. Mater. Electron. 30, 1–15 (2019)
S.M. Peymani-Motlagh et al., Assessing the magnetic, cytotoxic and photocatalytic influence of incorporating Yb3+ or Pr3+ ions in cobalt–nickel ferrite. J. Mater. Sci. Mater. Electron. 30(7), 6902–6909 (2019)
A. Sobhani-Nasab et al., Preparation, characterization and investigation of sonophotocatalytic activity of thulium titanate/polyaniline nanocomposites in degradation of dyes. Ultrason. Sonochem. 50, 46–58 (2019)
A. Sobhani-Nasab et al., New method for synthesis of BaFe12O19/Sm2Ti2O7 and BaFe12O19/Sm2Ti2O7/Ag nano-hybrid and investigation of optical and photocatalytic properties. J. Mater. Sci. Mater. Electron. 30(6), 5854–5865 (2019)
H. Kooshki et al., Eco-friendly synthesis of PbTiO3 nanoparticles and PbTiO3/carbon quantum dots binary nano-hybrids for enhanced photocatalytic performance under visible light. Sep. Purif. Technol. 211, 873–881 (2019)
F. Sedighi et al., Synthesis and characterization of CuWO4 nanoparticle and CuWO4/NiO nanocomposite using co-precipitation method; application in photodegradation of organic dye in water. J. Mater. Sci. Mater. Electron. 29(16), 13737–13745 (2018)
M. Eghbali-Arani et al., Green synthesis and characterization of SmVO4 nanoparticles in the presence of carbohydrates as capping agents with investigation of visible-light photocatalytic properties. J. Electron. Mater. 47(7), 3757–3769 (2018)
A. Sobhani-Nasab et al., Synthesis and characterization of MnWO4/TmVO4 ternary nano-hybrids by an ultrasonic method for enhanced photocatalytic activity in the degradation of organic dyes. Mater. Lett. 238, 159–162 (2019)
A. Mishra et al., Graphitic carbon nitride (g–C3N4)–based metal-free photocatalysts for water splitting: a review. Carbon 149, 693 (2019)
C.V. Reddy et al., Mn-doped ZrO2 nanoparticles prepared by a template-free method for electrochemical energy storage and abatement of dye degradation. Ceram. Int. 45(12), 15298–15306 (2019)
M.A. Marsooli et al., Preparation of Fe3O4/SiO2/TiO2/PrVO4 nanocomposite in various molar ratios: investigation on photocatalytic performance on organic contaminate and bacterial environments, and anti-cancer properties. Polyhedron 176, 114239 (2020)
S. Behvandi et al., Synthesis and characterization of Sm2(MoO4)3, Sm2(MoO4)3/GO and Sm2 (MoO4)3/C3N4 nanostructures for improved photocatalytic performance and their anti-cancer the MCF-7 cells. Polyhedron 180, 114424 (2020)
M.A. Marsooli et al., Preparation of Fe3O4/SiO2/TiO2/CeVO4 nanocomposites: investigation of photocatalytic effects on organic pollutants, bacterial environments, and new potential therapeutic candidate against cancer cells. Front. Pharmacol. 11, 192 (2020)
M. Eghbali-Arani et al., Optimization and detailed stability study on coupling of CdMoO4 into BaWO4 for enhanced photodegradation and removal of organic contaminant. Arab. J. Chem. 13, 2425 (2018)
F. Gandomi et al., Simple synthesis and characterization of Li0.5Fe2.5O4, LiMg0.5Fe2O4 and LiNi0.5Fe2O4, and investigation of their photocatalytic and anticancer properties on hela cells line. J. Mater. Sci. Mater. Electron. 30(22), 19691–19702 (2019)
S.M. Peymani-Motlagh et al., Effect of Gd3+-, Pr3+-or Sm3+-substituted cobalt–zinc ferrite on photodegradation of methyl orange and cytotoxicity tests. J. Rare Earths 37(12), 1288–1295 (2019)
M. Rahimi-Nasrabadi et al., Preparation of Co2TiO4/CoTiO3/Polyaniline ternary nano-hybrids for enhanced destruction of agriculture poison and organic dyes under visible-light irradiation. J. Mater. Sci. Mater. Electron. 30(17), 15854–15868 (2019)
A. Sobhani-Nasab et al., Synergetic effect of graphene oxide and C3N4 as co-catalyst for enhanced photocatalytic performance of dyes on Yb2 (MoO4) 3/YbMoO4 nanocomposite. Ceram. Int. 45(14), 17847–17858 (2019)
M.A. Marsooli et al., Preparation and characterization of magnetic Fe3O4/CdWO4 and Fe3O4/CdWO4/PrVO4 nanoparticles and investigation of their photocatalytic and anticancer properties on PANC1 cells. Materials 12(19), 3274 (2019)
P.S. Basavarajappa et al., Enhanced photocatalytic activity and biosensing of gadolinium substituted BiFeO3 nanoparticles. ChemistrySelect 3(31), 9025–9033 (2018)
A. Hamza et al., Solar photocatalytic degradation of phenol using nanosized ZnO and-Fe2O3. J. Chem. Eng. Mater. Sci. 4(7), 87–92 (2013)
M. Rahimi-Nasrabadi et al., Optimizing the procedure for the synthesis of nanoscale gadolinium (III) tungstate as efficient photocatalyst. J. Mater. Sci. Mater. Electron. 28(4), 3780–3788 (2017)
M. Rahimi-Nasrabadi et al., Samarium carbonate and samarium oxide; synthesis, characterization and evaluation of the photo-catalytic behavior. J. Mater. Sci. Mater. Electron. 28(7), 5574–5583 (2017)
M. Rahimi-Nasrabadi et al., Synthesis of nano-structured lanthanum tungstates photocatalysts. J. Mater. Sci. Mater. Electron. 28(11), 7600–7608 (2017)
M. Rahimi-Nasrabadi et al., Fabrication, characterization and photochemical activity of ytterbium carbonate and ytterbium oxide nanoparticles. J. Mater. Sci. Mater. Electron. 28(13), 9478–9488 (2017)
S. Jessl et al., Honeycomb-shaped carbon nanotube supports for BiVO4 based solar water splitting. Nanoscale 11(47), 22964–22970 (2019)
V.N. Rao et al., Photocatalytic recovery of H2 from H2S containing wastewater: surface and interface control of photo-excitons in Cu2S@ TiO2 core-shell nanostructures. Appl. Catal. B 254, 174–185 (2019)
C.V. Reddy et al., Template-free synthesis of tetragonal Co-doped ZrO2 nanoparticles for applications in electrochemical energy storage and water treatment. Electrochim. Acta 317, 416–426 (2019)
K.R. Reddy et al., Polymeric graphitic carbon nitride (g-C3N4)-based semiconducting nanostructured materials: synthesis methods, properties and photocatalytic applications. J. Environ. Manage. 238, 25–40 (2019)
M. Panigati et al., Luminescent dinuclear rhenium (I) complexes containing bridging 1, 2-diazine ligands: photophysical properties and application. Coord. Chem. Rev. 256(15–16), 1621–1643 (2012)
M. Rahimi-Nasrabadi, F. Ahmadi, M. Eghbali-Arani, Simple morphology-controlled fabrication of CdTiO3 nanoparticles with the aid of different capping agents. J. Mater. Sci. Mater. Electron. 27(12), 13294–13299 (2016)
M. Rahimi-Nasrabadi, F. Ahmadi, M. Eghbali-Arani, Different morphologies fabrication of NiAl2O4 nanostructures with the aid of new template and its photocatalyst application. J. Mater. Sci. Mater. Electron. 28(3), 2415–2420 (2017)
N. Lakshminarasimhan, A.D. Bokare, W. Choi, Effect of agglomerated state in mesoporous TiO2 on the morphology of photodeposited Pt and photocatalytic activity. J. Phys. Chem. C 116(33), 17531–17539 (2012)
S.P. Dharupaneedi et al., Membrane-based separation of potential emerging pollutants. Sep. Purif. Technol. 210, 850–866 (2019)
K.R. Reddy, V.G. Gomes, M. Hassan, Carbon functionalized TiO2 nanofibers for high efficiency photocatalysis. Mater. Res. Express 1(1), 015012 (2014)
K.R. Reddy, M. Hassan, V.G. Gomes, Hybrid nanostructures based on titanium dioxide for enhanced photocatalysis. Appl. Catal. A 489, 1–16 (2015)
K.R. Reddy et al., Nanofibrous TiO2-core/conjugated polymer-sheath composites: synthesis, structural properties and photocatalytic activity. J. Nanosci. Nanotechnol. 10(12), 7951–7957 (2010)
M. Rahimi-Nasrabadi et al., Statistically optimized synthesis of dyspersium tungstate nanoparticles as photocatalyst. J. Mater. Sci. Mater. Electron. 27(12), 12860–12868 (2016)
M. Rahimi-Nasrabadi et al., Preparation of dysprosium carbonate and dysprosium oxide efficient photocatalyst nanoparticles through direct carbonation and precursor thermal decomposition. J. Mater. Sci. Mater. Electron. 28(4), 3325–3336 (2017)
T. Tavangar et al., Textile waste, dyes/inorganic salts separation of cerium oxide-loaded loose nanofiltration polyethersulfone membranes. Chem. Eng. J. 385, 123787 (2020)
M. Rostami et al., Facile synthesis and characterization of TiO2–graphene–ZnFe2–xTbxO4 ternary nano-hybrids. J. Mater. Sci. 52(12), 7008–7016 (2017)
M. Rahimi-Nasrabadi et al., Assessment of supercapacitive performance of europium tungstate nanoparticles prepared via hydrothermal method. J. Mater. Sci. Mater. Electron. 28(17), 12391–12398 (2017)
M. Rahimi-Nasrabadi, F. Ahmadi, A. Fosooni, Influence of capping agents additives on morphology of CeVO4 nanoparticles and study of their photocatalytic properties. J. Mater. Sci. Mater. Electron. 28(1), 537–542 (2017)
M. Rahimi-Nasrabadi et al., ZnFe2–xLaxO4 nanostructure: synthesis, characterization, and its magnetic properties. J. Mater. Sci. Mater. Electron. 26(12), 9776–9781 (2015)
M. Rahimi-Nasrabadi et al., Synthesis and characterization of ZnFe2−xYbxO4–graphene nanocomposites by sol–gel method. J. Mater. Sci. Mater. Electron. 27(11), 11940–11945 (2016)
D.K. Kim et al., Starch-coated superparamagnetic nanoparticles as MR contrast agents. Chem. Mater. 15(23), 4343–4351 (2003)
Y. Kobayashi et al., Preparation and properties of silica-coated cobalt nanoparticles. J. Phys. Chem. B 107(30), 7420–7425 (2003)
Z. Liu et al., Synthesis and magnetic properties of Fe3O4 nanoparticles. J. Mater. Synth. Process. 10(2), 83–87 (2002)
Z. Liu et al., Synthesis and characterization of ultrafine well-dispersed magnetic nanoparticles. J. Magn. Magn. Mater. 283(2–3), 258–262 (2004)
Z. Liu et al., Synthesis of magnetite nanoparticles in W/O microemulsion. J. Mater. Sci. 39(7), 2633–2636 (2004)
M. Mikhaylova et al., Superparamagnetism of magnetite nanoparticles: dependence on surface modification. Langmuir 20(6), 2472–2477 (2004)
L. Casas et al., Silica aerogel–iron oxide nanocomposites: structural and magnetic properties. J. Non-Cryst. Solids 285(1–3), 37–43 (2001)
A. Corrias et al., X-ray absorption spectroscopy study of FeCo− SiO2 nanocomposites prepared by the sol− gel method. J. Phys. Chem. B 107(13), 3030–3039 (2003)
M. Ohmori, E. Matijević, Preparation and properties of uniform coated inorganic colloidal particles: 8. Silica on iron. J. Colloid Interface Sci. 160(2), 288–292 (1993)
R. Massart, Preparation of aqueous magnetic liquids in alkaline and acidic media. IEEE Trans. Magn. 17(2), 1247–1248 (1981)
S.H. Hosseini, A. Asadnia, Synthesis, characterization, and microwave-absorbing properties of polypyrrole/MnFe2O4 nanocomposite. J. Nanomater. 2012, 3 (2012)
Z. Ding, G. Lu, P. Greenfield, Role of the crystallite phase of TiO2 in heterogeneous photocatalysis for phenol oxidation in water. J. Phys. Chem. B 104(19), 4815–4820 (2000)
Y. Yu et al., Enhancement of photocatalytic activity of mesoporous TiO2 by using carbon nanotubes. Appl. Catal. A 289(2), 186–196 (2005)
C. Dette et al., TiO2 anatase with a bandgap in the visible region. Nano Lett. 14(11), 6533–6538 (2014)
S.K. Movahed, N.F. Lehi, M. Dabiri, Palladium nanoparticles supported on core-shell and yolk-shell Fe3O4@ nitrogen doped carbon cubes as a highly efficient, magnetically separable catalyst for the reduction of nitroarenes and the oxidation of alcohols. J. Catal. 364, 69–79 (2018)
L.G. Devi et al., Photo degradation of methyl orange an azo dye by advanced fenton process using zero valent metallic iron: influence of various reaction parameters and its degradation mechanism. J. Hazard. Mater. 164(2–3), 459–467 (2009)
P. Liang et al., Photocatalysis of C, N-doped ZnO derived from ZIF-8 for dye degradation and water oxidation. RSC Adv. 6(98), 95903–95909 (2016)
Y. Li et al., Efficient decomposition of organic compounds and reaction mechanism with BiOI photocatalyst under visible light irradiation. J. Mol. Catal. A 334(1–2), 116–122 (2011)
Acknowledgements
The authors wish to thank the National Institute for Medical Research Development (NIMAD) for their support (Grant No. 971032).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Gandomi, F., Sobhani-Nasab, A., Pourmasoud, S. et al. Synthesis of novel Fe3O4@SiO2@Er2TiO5 superparamagnetic core–shell and evaluation of their photocatalytic capacity. J Mater Sci: Mater Electron 31, 10553–10563 (2020). https://doi.org/10.1007/s10854-020-03604-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-020-03604-3