Abstract
In the present work, a novel hybrid nanocomposite of bimetallic Co–Ni hydroxide and polyaniline-modified partially reduced graphene oxide (PRGO) was assembled via in situ growth route for supercapacitor application. A series of characterizations demonstrated that large quantities of bimetallic Co–Ni hydroxide nanosheets could longitudinally grow on the surface of PRGO substrate and intercross together, forming a hierarchical honeycomb-like micro/nanostructure array. As-assembled CoNi(OH)2/PRGO nanocomposite showed a much higher specific capacitance of 2760 ± 160 F g−1 at 1.0 A g−1 in three-electrode measurements, in comparison with pristine bimetallic Co–Ni hydroxide, Co(OH)2/PRGO, and Ni(OH)2/PRGO reference electrodes, which originated from the synergy effect between component units and unique three-dimensional conductive porous framework of nanocomposite, thereby greatly promoting the redox processes of metal ions and facilitating the ion diffusion between the electrolyte and the electrode, as well as the electron transfer. Furthermore, after 1000 charge–discharge cycles, as-assembled nanocomposite electrode possessed good cycling stability, along with a high 93.2% retention level of capacitance at 10 A g−1. An asymmetric flexible all-solid-state supercapacitor device was equipped with poly (vinyl alcohol) film as the solid electrolyte, and as-assembled CoNi(OH)2/PRGO as the positive electrode delivered a 74.84 ± 1.46 wh kg−1 energy density and a 374.34 ± 0.15 w kg−1 power density at 0.5 A g−1, indicating good supercapacitor performance for energy storage and applications in flexible and wearable electronics.
Similar content being viewed by others
References
H. Omanda, T. Brousse, C. Marhic, D. Schleich, Improvement of the thermal stability of LiNi0.8Co0.2O2 cathode by a SiOx protective coating. J. Electrochem. Soc. 151, A922–A929 (2004)
J.M. Tarascon, M. Armand, Issues and challenges facing rechargeable lithium batteries. Nature 414, 359–367 (2001)
M. Sawangphruk, P. Srimuk, P. Chiochan, A. Krittayavathananona, S. Luanwuthia, J. Limtrakulb, High-performance supercapacitor of manganese oxide/reduced graphene oxide nanocomposite coated on flexible carbon fiber paper. Carbon 60, 109–116 (2013)
L.L. Zhang, X.S. Zhao, Carbon-based materials as supercapacitor electrodes. Chem. Soc. Rev. 38, 2520–2531 (2009)
W. Chen, C. Xia, H.N. Alshareef, One-step electrodeposited nickel cobalt sulfide nanosheet arrays for high-performance asymmetric supercapacitors. ACS Nano 8, 9531–9541 (2014)
Z. Tang, C. Tang, H. Gong, A high energy density asymmetric supercapacitor from nano-architectured Ni(OH)2/Carbon nanotube electrodes. Adv. Funct. Mater. 22, 1272–1278 (2012)
G. Wang, L. Zhang, J. Zhang, A review of electrode materials for electrochemical supercapacitors. Chem. Soc. Rev. 41, 797–828 (2012)
P. Simon, Y. Gogotsi, Materials for electrochemical capacitors. Nat. Mater. 7, 845–854 (2008)
B. Kirubasankar, V. Murugadoss, J. Lin, T. Ding, M. Dong, H. Liu et al., In situ grown nickel selenide on graphene nanohybrid electrodes for high energy density asymmetric supercapacitors. Nanoscale 10, 20414–20425 (2018)
K. Le, M. Gao, W. Liu, J. Liu, Z. Wang, F. Wang et al., MOF-derived hierarchical core-shell hollow iron-cobalt sulfides nanoarrays on Ni foam with enhanced electrochemical properties for high energy density asymmetric supercapacitors. Electrochim. Acta 323, 134826 (2019)
J. Qi, D. Chen, W. Wang, Y. Sui, Y. He, Q. Meng et al., Facile synthesis of N-doped activated carbon derived from cotton and CuCo2O4 nanoneedle arrays electrodes for all-solid-state asymmetric supercapacitor. J. Mater. Sci.: Mater Electron. 30, 9877–9887 (2019)
J. Ge, J. Wu, B. Ye, L. Fan, J. Jia, Hollow rod-like hybrid Co2CrO4/Co1−xS for high-performance asymmetric supercapacitor. J. Mater. Sci.: Mater Electron. 30, 1045–1055 (2019)
K. Jia, X. Zhuang, B. Cheng, S. Shi, Z. Shi, B. Zhang, Solution blown aligned carbon nanofiber yarn as supercapacitor electrode. J. Mater. Sci.: Mater Electron. 24, 4769–4773 (2013)
R. Hu, J. Zhao, R. Jiang, J. Zheng, Preparation of high strain polyaniline/polyvinyl alcohol composite and its applications in stretchable supercapacitor. J. Mater. Sci.: Mater Electron. 28, 14568–14574 (2017)
A.H. Siddique, S.W. Bokhari, R. Butt, S. Jiang, W. Chen, X. Zhou, Flexible asymmetric microsupercapacitor with high energy density based on all-graphene electrode system. J. Mater. Sci. 55, 309–318 (2020)
J. Chmiola, G. Yushin, Y. Gogotsi, C. Portet, P. Simon, P.L. Taberna, Anomalous increase in carbon capacitance at pore sizes less than 1 nanometer. Science 313, 1760–1763 (2006)
J. Lee, J. Kim, T. Hyeon, Recent progress in the synthesis of porous carbon materials. Adv. Mater. 18, 2073–2094 (2006)
P.J. Hall, M. Mirzaeian, S.I. Fletcher, F.B. Sillars, A.J.R. Rennie, G.O.S. Bey, G. Wilson, A. Cruden, R. Carter, Energy storage in electrochemical capacitors: designing functional materials to improve performance. Energy Environ. Sci. 3, 1238–1251 (2010)
G.A. Snook, P. Kaoand, A.S. Best, Conducting-polymer-based supercapacitor devices and electrodes. J. Power Sources 196, 1–12 (2011)
J. Yan, T. Wei, Z. Fan, W. Qian, M. Zhang, X. Shen, F. Wei, Preparation of graphene nanosheet/carbon nanotube/polyaniline composite as electrode material for supercapacitors. J. Power Sources 195, 3041–3045 (2010)
J. Zhang, L. Dong, C. Xu, J. Hao, F. Kang, J. Li, Comprehensive approaches to three-dimensional flexible supercapacitor electrodes based on MnO2/carbon nanotube/activated carbon fiber felt. J. Mater. Sci. 52, 5788–5798 (2017)
J. Yu, F. Xie, Z. Wu, T. Huang, J. Wu, D. Yan et al., Flexible metallic fabric supercapacitor based on graphene/polyaniline composites. Electrochim. Acta 259, 968–974 (2018)
W.H. Chen, Y.F. Yang, H.X. Shao, J. Fan, Tunable electrochemical properties brought about by partial cation exchange in hydrotalcite-like Ni-Co/Co-Ni hydroxide nanosheets. J. Phys. Chem. C 112, 17471–17477 (2008)
V. Gupta, S. Gupta, N. Miura, Potentiostatically deposited nanostructured CoxNi1−x layered double hydroxides as electrode materials for redox-supercapacitors. J. Power Sources 175, 680–685 (2008)
X. Wang, A. Sumboja, M. Lin, J. Yan, P.S. Lee, Enhancing electrochemical reaction sites in nickel–cobalt layered double hydroxides on zinc tin oxide nanowires: a hybrid material for an asymmetric supercapacitor device. Nanoscale 4, 7266–7272 (2012)
X. Sun, G. Wang, H. Sun, F. Lu, M. Yu, J. Lian, Morphology controlled high performance supercapacitor behaviour of the Ni-Co binary hydroxide system. J. Power Sources 238, 150–156 (2013)
Y. Tang, Y. Liu, W. Guo, S. Yu, F. Gao, Floss-like Ni-Co binary hydroxides assembled by whisker-like nanowires for high-performance supercapacitor. Ionics 21, 1655–1663 (2015)
G. Chen, S.S. Liaw, B.S. Li, Y. Xua, M. Dunwell, S.G. Deng, H.Y. Fan, H.M. Luo, Microwave-assisted synthesis of hybrid CoxNi1-x(OH)2 nanosheets: Tuning the composition for high performance supercapacitor. J. Power Sources 251, 338–343 (2014)
Q. Wang, S. Liu, H. Sun, Q. Lu, Synthesis of a flower-like Co-doped Ni(OH)2 composite for high-performance supercapacitors. RSC Adv. 5, 48181–48186 (2015)
D.D. Xia, H.C. Chen, J.J. Jiang, L. Zhang, Y.D. Zhao, D.Q. Guo, J.G. Yu, Facilely synthesized a phase nickel-cobalt bimetallic hydroxides: Tuning the composition for high pseudocapacitance. Electrochim. Acta 156, 108–114 (2015)
L. Huang, D.C. Chen, Y. Ding, S. Feng, Z.L. Wang, M.L. Liu, Nickel-cobalt hydroxide nanosheets coated on NiCo2O4 nanowires grown on carbon fiber paper for high-performance pseudocapacitors. Nano Lett. 13, 3135–3139 (2013)
M.P. Umakant, S.S. Ji, B.K. Sachin, C.L. Su, G.P. Hyung, V.G. Kishor, J.H. Kim, C.J. Seong, Enhanced supercapacitive performance of chemically grown cobalt-nickel hydroxides on three-dimensional graphene foam electrodes. ACS Appl. Mater. Int. 6, 2450–2458 (2014)
Y. Bai, W.Q. Wang, R.R. Wang, J. Sun, L. Gao, Controllable synthesis of 3D binary nickel-cobalt hydroxide/graphene/nickel foam as a binder-free electrode for high-performance supercapacitors. J. Mater. Chem. A 3, 12530–12538 (2015)
L.L. Zhang, S.S. Song, H.Y. Shi, One-pot methanol-mediated solvothermal synthesis of 3D porous Co-doped α-Ni(OH)2/RGO nanosheets as a high-performance pseudo-capacitance electrode. J. Alloys Compd. 751, 69–79 (2018)
H.N. Ma, J. He, D.B. Xiong, J.S. Wu, Q.Q. Li, V. Dravid, Y.F. Zhao, Nickel cobalt hydroxide @reduced graphene oxide hybrid nanolayers for high performance asymmetric supercapacitors with remarkable cycling stability. ACS Appl Mater. Int. 8, 1992–2000 (2016)
D. Ghosh, S. Giri, M. Mandal, C.K. Das, High performance supercapacitor electrode material based on vertically aligned PANI grown on reduced graphene oxide/Ni(OH)2 hybrid composite. RSC Adv. 4, 26094–26101 (2014)
M. Mitra, C. Kulsi, K. Chatterjee, K. Kargupta, S. Ganguly, D. Banerjee, S. Goswamid, Reduced graphene oxide-polyaniline composites-synthesis, characterization and optimization for thermoelectric applications. RSC Adv. 5, 31039–31048 (2015)
A.V. Talyzin, G. Mercier, A. Klechikov, M. Hedenström, D. Johnels, D. Wei, D. Cotton, A. Opitz, E. Moons, Brodie vs Hummers graphite oxides for preparation of multi-layered Materials. Carbon 115, 430–440 (2017)
P. Xiong, Y. Fan, Design and synthesis of ternary Ferrite/Graphene/polyaniline hierarchical nanocomposites for high-performance supercapacitors. J. Power Sources 245, 937–946 (2014)
X. Yan, J. Chen, J. Yang, P. Miele, Fabrication of free-standing, electrochemically active, and biocompatible graphene oxide-polyaniline and graphene-polyaniline hybrid papers. ACS Appl. Mater. Int. 2, 2521–2529 (2010)
S. Park, K.S. Lee, G. Bozoklu, W. Cai, S.T. Nguyen, R.S. Ruoff, Graphene oxide papers modified by divalent ions-enhancing mechanical properties via chemical cross-linking. ACS Nano 2, 572–578 (2008)
Y. Si, E.T. Samulski, Synthesis of water soluble graphene. Nano Lett. 8, 1679–1682 (2008)
J. Xu, K. Wang, S.Z. Zu, B.H. Han, Z. Wei, Hierarchical nanocomposites of polyaniline nanowire arrays on graphene oxide sheets with synergistic effect for energy storage. ACS Nano 4, 5019–5026 (2010)
Ü. Ceylan, G.Ö. Tarı, H. Gökce, E.A. Gokce, Spectroscopic (FT–IR and UV–Vis) and theoretical (HF and DFT) investigation of 2-Ethyl-N-[(5-nitrothiophene-2-yl) methylidene] aniline. J. Mol. Struct. 1110, 1–10 (2016)
M. Aghazadeh, H.M. Shiri, A.-A.M. Barmi, Uniform β-Co (OH)2 disc-like nanostructures prepared by low-temperature electrochemical rout as an electrode material for supercapacitors. Appl. Surf. Sci. 273, 237–242 (2013)
L. Zhang, F. Li, D.G. Evans, X. Duan, Structure and surface characteristics of Cu-based composite metal oxides derived from layered double hydroxides. Mater. Chem. Phys. 87(2–3), 402–410 (2004)
G. Irmer, Zum Einfluss der Apparatefunktion auf die Bestimmung von streuquerschnitten und Lebensdauern aus optischen Phononenspektren. Exp. Tech. Phys. 33, 501–506 (1985)
J.W. Qin, M.H. Cao, N. Li, C.W. Hu, Graphene-wrapped WO3 nanoparticles with improved performances in electrical conductivity and gas sensing properties. J. Mater. Chem. 21, 17167–17174 (2011)
Y.W. Zhu, S. Murali, W.W. Cai, X.S. Li, J.W. Suk, J.R. Potts, R.S. Ruoff, Graphene and graphene oxide: synthesis, properties, and applications. Adv. Mater. 22, 3906–3924 (2010)
M. Jana, P. Khanra, N.C. Murmu, P. Samanta, J.H. Lee, T. Kuila, Covalent surface modification of chemically derived graphene and its application as supercapacitor electrode material. Phys. Chem. Chem. Phys. 16, 7618–7626 (2014)
Z. Li, X. Li, L. Xiang, X. Xie, X. Li, D.-R. Xiao et al., Three-dimensional hierarchical nickel-cobalt-sulfide nanostructures for high performance electrochemical energy storage electrodes. J. Mater. Chem. A. 4, 18335–18341 (2016)
E. Martono, J.M. Vohs, Support effects in cobalt-based ethanol steam reforming catalysts: reaction of ethanol on Co/CeO2/YSZ (100) model catalysts. J. Catal. 291, 79–86 (2012)
M.M. Natile, A. Glisenti, Surface reactivity of NiO/Co3O4 and Fe2O3/Co3O4 nanocomposite catalysts: interaction with methanol. J. Mol. Catal. A 217, 175–184 (2004)
C.W. Huang, H.C. Wu, W.H. Lin, Y.Y. Li, Temperature effect on the formation of catalysts for growth of carbon nanofibers. Carbon 47, 795–803 (2009)
H. Ago, T. Kugler, F. Cacialli, W.R. Salaneck, M.S.P. Shaffer, A.H. Windl, Work functions and surface functional groups of multiwall carbon nanotubes. J. Phys. Chem. B 103, 8116–8121 (1999)
D. Xu, Q. Xu, K. Wang, J. Chen, Z. Chen, Fabrication of free-standing hierarchical carbon nanofiber/graphene oxide/polyaniline films for supercapacitors. ACS Appl. Mater. Inter. 6, 200–209 (2013)
Y. Geng, S.J. Wang, J.K. Kim, Preparation of graphite nanoplatelets and graphene sheets. J. Colloid Interface Sci. 336, 592–598 (2009)
D.W. Wang, B. Guan, Y. Li, D.D. Li, Z.Y. Xu, Y.F. Hu, Morphology-controlled synthesis of hierarchical mesoporous α-Ni(OH)2 microspheres for high-performance asymmetric supercapacitors. J. Alloys Compd. 737, 238–247 (2018)
Z. Chen, Y. Chen, C. Zuo, S. Zhou, A.G. Xiao, A.X. Pan, Hydrothermal synthesis of porous Co(OH)2 nanoflake array film and its supercapacitor application. Bull. Mater. Sci. 36, 239–244 (2013)
J. Xu, S. Gai, F. He, N. Niu, P. Gao, Y. Chen, P. Yang, A sandwich-type three-dimensional layered double hydroxide nanosheet array/graphene composite: fabrication and high supercapacitor performance. J. Mater. Chem. A 2, 1022–1031 (2014)
G.Y. Zhou, T.R. Xiong, S.J. He, Y.H. Li, Y.M. Zhu, H.Q. Hou, Asymmetric supercapacitor based on flexible TiC/CNF felt supported interwoven nickel-cobalt binary hydroxide nanosheets. J. Power Sources 317, 57–64 (2016)
M. Jana, S. Saha, P. Samanta, N.C. Murmu, N.H. Kim, T. Kuila, J.H. Lee, Growth of Ni-Co binary hydroxide on a reduced graphene oxide surface by a successive ionic layer adsorption and reaction (SILAR) method for high performance asymmetric supercapacitor electrodes. J. Mater. Chem. A 4, 2188–2197 (2016)
Acknowledgements
This study was funded through the National Natural Science Foundation of China (Grant Nos. 21991102, 21521005; 21776017) and the National Key Research Development Program of China (Grant Nos. 2016YFB0601303 and 2016YFB0301602).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Wang, D., Zhang, Y., Yang, L. et al. Direct in situ assembly of bimetallic Co–Ni hydroxide/polyaniline-modified reduced graphene oxide nanocomposite for asymmetric flexible supercapacitor electrode. J Mater Sci: Mater Electron 31, 6467–6478 (2020). https://doi.org/10.1007/s10854-020-03202-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-020-03202-3