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Effect of silicone grease on electrical tree degradation of silicon rubber under AC electric field

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Abstract

Silicone grease (SG) is usually applied on the interface between the insulation of cable and cable joint to enhance the sealing of interface. However, in long-term operating process, SG will gradually diffuse into silicone rubber (SiR) matrix and cause the electrical performance degradation of SiR, which can even result in the failure of cable joints. The commercial HTV SiR with functional silica filler was used in this study, and the electrical tree characteristics SiR samples with different SG coating times were investigated. The crosslinking density and trap distribution were analyzed to explain the transformation of electrical tree with different coating times. It was found that the electrical tree initiation voltage dropped from 13.35 to 10.46 kV and the fractal dimension increased from 1.25 to 1.52, while the electrical tree length showed an almost constant trend. The morphology of the electrical trees gradually changed from branch-type to bush-type. The decline of crosslinking density from 1.92 × 10−4 to 1.76 × 10−4 mol/g is attributed to the breaking of crosslinking structure between silica and SiR matrix, which can lead to the expanding free volume and decreased deep trap density. More high-energy electrons can be generated, which aggravates the degradation of molecular chains and further results in the decreased electrical tree initiation voltage. In addition, the denser morphology of electrical tree is considered to be caused by the more growth direction for electrical tree provided by the expanding free volume.

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References

  1. Y. Jiang, H. Min, J. H. Luo, Y. Li, X. J. Jiang, R. Xia, W. J. Li, Asia-pacific power and energy engineering conference (APPEEC), 1–4 (2010)

  2. Y. Kamiya, Y. Muramoto, N. Shimizu, IEEE conference on electrical insulation and dielectric phenomena (CEIDP), 712–715 (2006)

  3. Y. Kamiya, Y. Muramoto, N. Shimizu, IEEE conference on electrical insulation and dielectric phenomena (CEIDP), 53–56 (2007)

  4. K. Tanabe, Y. Muramoto, N. Shimizu. IEEE international conference on solid dielectrics (ICSD), 760–763 (2013)

  5. Y.X. Zhang, Y.X. Zhou, R. Liu, X. Zhang, M.Y. Wang, L. Zhang, J. Electrost. 76, 83–88 (2015)

    Article  CAS  Google Scholar 

  6. Y.X. Zhou, Y.X. Zhang, L. Zhang, D.W. Guo, X. Zhang, M.Y. Wang, I.E.E.E. Trans, Dielectr. Electr. Insul. 23(2), 748–756 (2016)

    Article  CAS  Google Scholar 

  7. Y.X. Zhang, L. Zhang, Y.X. Zhou, M. Chen, Z.L. Zhou, J. Liu, Z.Z. Chen, I.E.E.E. Trans, Dielectr. Electr. Insul. 25(3), 1142–1150 (2018)

    Article  CAS  Google Scholar 

  8. Y.X. Zhang, L. Zhang, Y.X. Zhou, M. Chen, M. Huang, R. Liu, I.E.E.E. Trans, Dielectr. Electr. Insul. 24(5), 2694–2702 (2017)

    Article  CAS  Google Scholar 

  9. B.X. Du, T. Han, J.G. Su, I.E.E.E. Trans, Dielectr. Electr. Insul. 22(2), 720–727 (2017)

    Article  Google Scholar 

  10. B.X. Du, J.G. Su, J. Li, T. Han, I.E.E.E. Trans, Dielectr. Electr. Insul. 24(3), 1547–1556 (2017)

    Article  CAS  Google Scholar 

  11. Normand, F. Daniel, IEEE international conference on solid dielectrics (ICSD), 35–38 (2001)

  12. X. Wang, H. Yao, K. Wu, S. Liu, J.K. Peng, H. Cui, High Volt. Eng. 40(1), 74–79 (2014). (in Chinese)

    Google Scholar 

  13. X. Wang, Y.Y. Zhu, Y.W. Zhang, Y.F. Liao, F.Z. Zhang, G.L. Wang, High Volt. Eng. 42(8), 2382–2387 (2016). (in Chinese)

    Google Scholar 

  14. J.Y. Li, F.S. Zhou, D.M. Min, S.T. Li, R. Xia, I.E.E.E. Trans, Dielectr. Electr. Insul. 22(3), 1723–1732 (2015)

    Article  CAS  Google Scholar 

  15. F.S. Zhou, J.Y. Li, Z.M. Yan, X. Zhang, Y.Q. Yang, M.J. Liu, D.M. Min, S.T. Li, I.E.E.E. Trans, Dielectr. Electr. Insul. 23(6), 3742–3751 (2016)

    Article  Google Scholar 

  16. P.J. Flory, J. Rehner, J. Chem. Phys. 11(11), 512–520 (1943)

    Article  CAS  Google Scholar 

  17. P.J. Flory, J. Rehner, J. Chem. Phys. 11(11), 521–526 (1943)

    Article  CAS  Google Scholar 

  18. S.H. Wang, P.X. Chen, H. Li, J.Y. Li, Z.Z. Chen, I.E.E.E. Trans, Dielectr. Electr. Insul. 24(3), 1809–1817 (2017)

    Article  CAS  Google Scholar 

  19. P. Kannan, M. Sivakumar, K. Mekala, J. Electr. Eng. Technol. 10(1), 355–363 (2015)

    Article  Google Scholar 

  20. L.A. Dissado, J.C. Fothergill, Electrical Degradation and Breakdown in Polymers (Peter Peregrinus Ltd., London, 1992)

    Book  Google Scholar 

  21. M.T. Nazir, B.T. Phung, S.H. Yu, S.T. Li, I.E.E.E. Trans, Dielectr. Electr. Insul. 25(6), 2076–2085 (2018)

    Article  CAS  Google Scholar 

  22. W.W. Wang, S.T. Li, I.E.E.E. Trans, Dielectr. Electr. Insul. 25(1), 2–12 (2018)

    Article  CAS  Google Scholar 

  23. D.M. Min, C.Y. Yan, Y. Huang, S.T. Li, Y. Ohki, Polymers 9(10), 533 (2017)

    Article  Google Scholar 

  24. S.T. Li, G.L. Yin, G. Chen, J.Y. Li, S.N. Bai, L.S. Zhong, Y.X. Zhang, Q.Q. Lei, I.E.E.E. Trans, Dielectr. Electr. Insul. 17(5), 1523–1535 (2010)

    Article  CAS  Google Scholar 

  25. P.X. Chen, S.H. Wang, Z.Z. Chen, J.Y. Li, High Voltage Engineering 44(12), 78–86 (2018). (in Chinese)

    Google Scholar 

  26. Z.M. Yan, K. Yang, Y.Y. Zhang, S.H. Wang, J.Y. Li, J. Mater. Sci.: Mater. Electron. 30(23), 20605–60213 (2019)

    CAS  Google Scholar 

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Liao, Y., Yang, K., Yan, Z. et al. Effect of silicone grease on electrical tree degradation of silicon rubber under AC electric field. J Mater Sci: Mater Electron 31, 6279–6287 (2020). https://doi.org/10.1007/s10854-020-03183-3

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  • DOI: https://doi.org/10.1007/s10854-020-03183-3

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