Abstract
The rewritable bistable memory characteristics have been studied in polymethyl methacrylate (PMMA) and carboxylated multi-walled carbon nanotubes (CNT) composite films. The sandwich structure FTO/PMMA + CNTs/Ag devices were prepared by spin coating and vacuum evaporation process. The device exhibited rewritable bistable resistive switching with switch-on voltage of ~ − 1.5 V, switch-off voltage of ~ 3.4 V, and a high ON/OFF ratio almost of 105. The rewritable behavior of the FTO/PMMA + CNTs/Ag device has been investigated by the endurance test, retention test, and the write-read-erase-reread multiple-cycle tests. The FTO/PMMA + CNTs/Ag device exhibited good retention performance for 2 × 105 s and underwent 104 read pulses. The conduction mechanism in ON state obeys Ohmic conduction; simultaneously, for OFF state, trap-limited space-charge limited conduction was discovered to be the dominant conduction mechanism.
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References
P. Russo, M. Xiao, N.Y. Zhou, Carbon nanowalls: a new material for resistive switching memory devices. Carbon 120, 54–62 (2017)
G. Zhou, Z. Ren, L. Wang, J. Wu, B. Sun, A. Zhou, G. Zhang, S. Zheng, S. Duan, Q. Song, Resistive switching memory integrated with amorphous carbon-based nanogenerators for self- powered device. Nano Energy 63, 103793 (2019)
Y. Sun, D. Wen, F. Sun, Eliminating negative-set behavior by adding a graphene blocking layer in resistive switching memory devices based on epoxy resin. Appl. Phys. Express 12, 074006 (2019)
Y. Sun, D. Wen, X. Bai, Nonvolatile ternary resistive switching memory devices based on the polymer composites containing zinc oxide nanoparticles. Phys. Chem. Chem. Phys. 20, 5771–5779 (2018)
J.R. Rani, S.-I. Oh, J.M. Woo, J.-H. Jang, Low voltage resistive memory devices based on graphene oxideiron oxide hybrid. Carbon 94, 362–368 (2015)
Y. Sun, D. Wen, Conductance quantization in nonvolatile resistive switching memory based on the polymer composite of zinc oxide nanoparticles. J. Phys. Chem. C 122, 10582–10591 (2018)
F. Lv, C. Gao, H.-A. Zhou, P. Zhang, K. Mi, X. Liu, Nonvolatile bipolar resistive switching behavior in the perovskite-like (CH3NH3)2FeCl4. ACS Appl. Mater. Interfaces 8, 18985–18990 (2016)
J. Lee, W. Schell, X. Zhu, E. Kioupakis, W.D. Lu, Charge transition of oxygen vacancies during resistive switching in oxide-based RRAM. ACS Appl. Mater. Interfaces 11, 11579–11586 (2019)
B. Sun, X. Zhang, G. Zhou, P. Li, Y. Zhang, H. Wang, Y. Xia, Y. Zhao, An organic nonvolatile resistive switching memory device fabricated with natural pectin from fruit peel. Org. Electron. 42, 181–186 (2017)
A. Pradel, N. Frolet, M. Ramonda, A. Piarristeguy, M. Ribes, Bipolar resistance switching in chalcogenide materials. Phys. Stat. Solidi 208, 2303–2308 (2011)
Y. Sun, J. Lu, C. Ai, D. Wen, X. Bai, Enhancement of memory margins in the polymer composite of [6,6]-phenyl-C61-butyric acid methyl ester and polystyrene. Phys. Chem. Chem. Phys. 18, 30808–30814 (2016)
K. Pramod, R.B. Gangineni, Low voltage bipolar resistive switching in selfassembled PVDF nanodot network in capacitor like structures on Au/Cr/Si with Hg as a top electrode. Org. Electron. 42, 47–51 (2017)
Y. Sun, J. Lu, C. Ai, D. Wen, Nonvolatile memory devices based on poly(vinyl alcohol)+ graphene oxide hybrid composites. Phys. Chem. Chem. Phys. 18, 11341–11347 (2016)
B. Hafsi, A. Boubaker, D. Guerin, S. Lenfant, A. Kalboussi, K. Lmimouni, N-type polymeric organic flash memory device: effect of reduced graphene oxide floating gate. Org. Electron. 45, 81–88 (2017)
Y. Sun, D. Wen, Nonvolatile WORM and rewritable multifunctional resistive switching memory devices from poly(4-vinyl phenol) and 2-amino-5-methyl-1,3,4- thiadiazole composite. J. Alloy. Compound. 806, 215–226 (2019)
Y.M. Sun, D.Z. Wen, F.Y. Sun, Influence of blending ratio on resistive switching effect in donor–acceptor type composite of PCBM and PVK-based memory devices. Org. Electron. 65, 141–149 (2019)
A. Cifarelli, A. Parisini, S. Iannotta, T. Berzina, Organic memristive devices based on pectin as a solid polyelectrolyte. Microelectron. Eng. 185, 55–60 (2018)
B. Sun, Y. Chen, M. Xiao, G. Zhou, S. Ranjan, W. Hou, X. Zhu, Y. Zhao, S.A.T. Redfern, Y.N. Zhou, A unified capacitive-coupled memristive model for the nonpinched current-voltage hysteresis loop. Nano Lett. 19, 6461–6465 (2019)
S. Munjal, N. Khare, Valence change bipolar resistive switching accompanied with magnetization switching in CoFe2O4 thin film. Sci. Rep. 7, 12427 (2017)
B. Antonio Di, R. Mohamed, K.B. Anthony, Y. Yanfei, G. Liberata, G. Filippo, Electrical properties and memory effects of field-effect transistors from networks of single- and double-walled carbon nanotubes. Nanotechnology 21, 115204 (2010)
D. Chaudhary, V.D. Vankar, N. Khare, Noble metal-free-C3N4/TiO2/CNT ternary nanocomposite with enhanced photocatalytic performance under visible-light irradiation via multi-step charge transfer process. Sol. Energy 158, 132–139 (2017)
D.Y. Yun, T.W. Kim, Nonvolatile memory devices based on Au/graphene oxide nano- composites with bilateral multilevel characteristics. Carbon 88, 26–32 (2015)
I. Rosales-Gallegos, J. A. Avila-Nino, D. Hernandez-Arriaga, M. Reyes-Reyes, R. Lopez-Sandoval, Flexible rewritable organic memory devices using nitrogen-doped CNTs/PEDOT: PSS composites. Org. Electron. 45, 159–168 (2017)
K.S. Vasu, S. Sampath, A.K. Sood, Nonvolatile unipolar resistive switching in ultrathin films of graphene and carbon nanotubes. Solid State Comm. 151, 1084–1087 (2011)
Y. Sun, L. Li, D. Wen, X. Bai, G. Li, Bistable electrical switching and nonvolatile memory effect in carbon nanotube-poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) composite films. Phys. Chem. Chem. Phys. 17, 17150–17158 (2015)
J. Molina, R. Torres, A. Ranjan, K.-L. Pey, Resistive switching characteristics of MIM structures based on oxygen variable ultra-thin HfO2 and fabricated at low temperature. Mat. Sci. Semicond. Process. 66, 191–199 (2017)
Y. M. Sun, L. Li D. Wen, X. Bai, Bistable electrical switching characteristics and memory effect by mixing of oxadiazole in polyurethane layer. J. Phys. Chem. C 119, 19520–19525 (2015)
K. Sumaru, S. Inui, T. Yamanaka, Optically-addressed spatial light modulator composed of organic photochromic thin film: its high durability and stable data retention. Proc. SPIE 4642, 130–137 (2002)
S. Kobatake, M. Yamada, T. Yamada, M. Irie, Photochromism of 1,2-bis(2-methyl-6-nitro-1- benzothiophen-3-yl) perfluorocyclopentene in a single crystalline phase: dichroism of the closed-ring form isomer. J. Am. Chem. Soc. 121, 8450–8456 (1999)
L. Wang, Q. Li, Photochromism into nanosystems: towards lighting up the future nanoworld. Chem. Soc. Rev. 47, 1044–1097 (2018)
Y. Sun, F. Miao, R. Li, Bistable electrical switching and nonvolatile memory effect based on the thin films of polyurethane-carbon nanotubes blends. Sensor Actuator Phys. 234, 282–289 (2015)
Y.M. Sun, J. Lu, C. Ai, D. Wen, X. Bai, Multilevel resistive switching and nonvolatile memory effects in epoxy methacrylate resin and carbon nanotube composite films. Org. Electron. 32, 7–14 (2016)
D. Chaudhary, S. Munjal, N. Khare, V.D. Vankar, Bipolar resistive switching and nonvolatile memory effect in poly (3-hexylthiophene) ecarbon nanotube composite films. Carbon 130, 553–558 (2018)
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This work is supported by National Natural Science Foundation of China (NO.61761048).
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Zhao, E., Liu, X., Liu, G. et al. Rewritable bistable memory device in polymethyl methacrylate carbon nanotube composite films. J Mater Sci: Mater Electron 31, 3642–3647 (2020). https://doi.org/10.1007/s10854-020-02921-x
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DOI: https://doi.org/10.1007/s10854-020-02921-x