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Synthesis and electrochemical properties of Ge4+ ions-modified VO2(paramontroseite)

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Abstract

Herein, we report, for the first time, the facile synthesis of VO2(paramontroseite) by doping of Ge4+ ions into VO2 via simple hydrothermal route. The synthesized materials were characterized by different techniques in terms of their structural, morphological, and thermal properties using X-ray diffraction, transmission electron microscopy, and thermogravimetric analysis and differential scanning calorimetry, respectively. It was observed that the formation of a tunnel by the octahedral arrangement of VO6 in VO2(P) allows intercalations of ions from ionic electrolytes, making it useful for electrochemical applications. The detailed cyclic voltammetric studies, at different scan rates, and electrochemical impedance spectroscopic results showed that the VO2(P) is a potential material for electrochemical applications.

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Authors and Affiliations

  1. Nanostructured Materials Laboratory, Department of Materials Science and Nanotechnology, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, Sonepat, Haryana, 131039, India

    Meenu Saini, Bharti Saini, Pawan Kumar & Brijnandan S. Dehiya

  2. Surface Lab, Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, Sonepat, Haryana, 131039, India

    Rinki Malik & Suman Lata

  3. School of Chemical Engineering, Jeonbuk National University, Jeonju, 54896, Republic of Korea

    Hyung-Kee Seo

  4. Department of Chemistry, Faculty of Science and Arts and Promising Centre for Sensors and Electronic Devices (PCSED), Najran University, Najran, 11001, Saudi Arabia

    Ahmad Umar

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  1. Meenu Saini
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  2. Rinki Malik
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  4. Bharti Saini
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Correspondence to Brijnandan S. Dehiya or Ahmad Umar.

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Saini, M., Malik, R., Lata, S. et al. Synthesis and electrochemical properties of Ge4+ ions-modified VO2(paramontroseite). J Mater Sci: Mater Electron 31, 3795–3802 (2020). https://doi.org/10.1007/s10854-020-02910-0

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  • DOI: https://doi.org/10.1007/s10854-020-02910-0

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