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MOFs-derived MnCo2O4 nanowires with porous structures for lithium-ion battery anodes

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Abstract

Porous binary metal oxides with high theoretical specific capacities and power density are attracting increasing attentions as anode materials for high-performance lithium-ion batteries. Herein, we report a facile strategy for the synthesis of porous MnCo2O4 nanowires through direct calcination of metal–organic frameworks in air. The resulting MnCo2O4 nanowires exhibited enhanced lithium-storage performance (929 mAh g−1 at 100 mA g−1 after 100 cycles). The outstanding lithium-storage performances of the resulting MnCo2O4 nanowires can be ascribed to their unique porous architectures, which offer a proximate pathway for the transfer of electrolyte and electrons over long cycling periods.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (NSFC, 21601003, 21371009), Anhui Provincial Natural Foundation (Grant No. 1608085QB34) and China Postdoctoral Science Foundation (Grant No. 2017M61202).

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Authors and Affiliations

  1. Anyang Institute of Technology, College of Chemistry and Environmental Engineering, Anyang, 455000, People’s Republic of China

    Liguo Yang & Xin Wang

  2. Institute of Physical Science and Information Technology, Anhui University, Hefei, 230601, People’s Republic of China

    Fangcai Zheng

  3. High Magnetic Field Laboratory, Hefei Institute of Physical Science, Chinese Academy of Science, Hefei, 230031, People’s Republic of China

    Fangcai Zheng

Authors
  1. Liguo Yang
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  2. Xin Wang
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  3. Fangcai Zheng
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Correspondence to Fangcai Zheng.

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Yang, L., Wang, X. & Zheng, F. MOFs-derived MnCo2O4 nanowires with porous structures for lithium-ion battery anodes. J Mater Sci: Mater Electron 30, 16687–16693 (2019). https://doi.org/10.1007/s10854-019-02049-7

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  • DOI: https://doi.org/10.1007/s10854-019-02049-7

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