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MOF-derived graphitized porous carbon/Fe–Fe3C nanocomposites with broadband and enhanced microwave absorption performance

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Abstract

Design of dual-loss electromagnetic (EM) materials composed of carbon-based materials and magnetic particles have been a rational strategy for application in the EM wave absorption field. Herein, Fe–Fe3C/nanoporous carbon (NPC) nanocomposite has been successfully prepared through a facile thermal decomposition route of zeolitic imidazolate frameworks-8 (ZIF-8) and Fe3O4 nanoparticles. The nanocomposite exhibits excellent microwave absorption property, which is mainly interpreted by the polarization and multiple reflection causing by porous microstructure, suitable impedance matching, additional magnetic loss and synergistic effect between graphitized NPC and magnetic Fe–Fe3C particles. The optimal reflection loss (RL) can reach up to − 48 dB at 8.1 GHz with a layer thickness of 3.0 mm. Besides, the nanocomposites provide the effective bandwidth (RL < − 10 dB) of 3.9 GHz from 8.4 to 12.3 GHz, nearly covering the whole X band when the thickness is 2.5 mm.

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Acknowledgements

This work is supported by the National Natural Science Foundation of China (Grant Nos. 51672201 and 51373129).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, 430070, China

    Tingyu Yan, Jun Wang, Qilei Wu & Huajun Duan

  2. Institute of Advanced Material Manufacturing Equipment and Technology, Wuhan University of Technology, Wuhan, 430070, China

    Jun Wang & Huajun Duan

  3. School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan, 430070, China

    Siqi Huo

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  1. Tingyu Yan
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Yan, T., Wang, J., Wu, Q. et al. MOF-derived graphitized porous carbon/Fe–Fe3C nanocomposites with broadband and enhanced microwave absorption performance. J Mater Sci: Mater Electron 30, 12012–12022 (2019). https://doi.org/10.1007/s10854-019-01558-9

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