Abstract
A series of Ca3La6(SiO4)6:Eu2+ and Ca3La6(SiO4)6:Eu2+/Mn2+ phosphors were fabricated by a solid state reaction. The phase composition and luminescent properties of the fabricated phosphors were investigated. The XRD patterns show that Eu2+ and Mn2+ were doped into the Ca3La6(SiO4)6 host in the present experiment. The Ca3La6(SiO4)6:Eu2+ phosphors show the emission band in blue region and the Ca3La6(SiO4)6:Mn2+ phosphors exhibit the emission band in yellow region. The excitation band of Ca3La6(SiO4)6:Mn2+ overlaps with the emission band of Ca3La6(SiO4)6:Eu2+ that means a possibility for the energy transfer process from Eu2+ to Mn2+ in the Ca3La6(SiO4)6:Eu2+/Mn2+ phosphors. Tunable luminescence was obtained due to this energy transfer process and warm white light was emitted by Ca3La6(SiO4)6:0.05Eu2+/0.04Mn2+ and Ca3La6(SiO4)6:0.05Eu2+/0.05Mn2+ phosphors.
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References
S. Nakamura, Science 281, 956 (1998)
J.K. Sheu, S.J. Chang, C.H. Kuo, Y.K. Su, L.W. Wu, Y.C. Lin, W.C. Lai, J.M. Tsai, G.C. Chi, R.K. Wu, IEEE Photonics Tech. Lett. 15, 18 (2003)
V.V. Actuchin, N.F. Beisel, E.N. Galashov, E.M. Mandrik, M.S. Molokeev, A.P. Yelisseyev, A.A. Yusuf, Z. Xia, ACS Appl. Mater. Interfaces 7, 26235 (2015)
H. Ji, L. Wang, M.S. Molokeev, N. Hirosaki, R. Xie, Z. Huang, Z. Xia, O.M. ten Kate, L. Liu, V.V. Atuchin, J. Mater. Chem. C 4, 6855 (2016)
E.N. Galashov, V.V. Atuchin, T.A. Gavrilova, I.V. Mandrik, A.P. Yelisseyev, Z. Xia, J. Mater. Sci. 52, 13033 (2017)
A.B. Muñoz-García, L. Seijo, Phys. Rev. B 82, 184118 (2010)
M.C. Maniquiz, K.Y. Jung, ECS Trans. 28, 175 (2010)
M. Shang, J. Fan, H. Lian, Y. Zhang, D. Geng, J. Lin, Inorg. Chem. 53, 7748 (2014)
Y. Yang, B. Liu, Y. Zhang, X. Lv, L. Wei, J. Xu, H. Zhang, X. Wang, C. Zhang, J. Li, J. Mater. Sci.: Mater. Electron. 29, 17154 (2018)
S.W. Yoon, H.K. Park, J.H. Oh, Y.B. Do, IEEE Photonics J. 6, 8400110 (2014)
Y.H. Song, G.S. Han, E.K. Ji, M.J. Lee, Y.L. Song, D.S. Kong, M.K. Jung, B.W. Jeong, H.S. Jung, D.H. Yoon, J. Mater. Chem. C 3, 6148 (2015)
R. Murota, T. Kobayashi, Y. Mita, Jpn. J. Appl. Phys. 41, L887 (2002)
C. Yang, G. Gu, X. Zhao, X. Liang, W. Xiang, Mater. Lett. 170, 58 (2016)
Y. Yang, X. Wang, B. Liu, Y. Zhang, X. Lv, J. Li, S. Li, L. Wei, H. Zhang, C. Zhang, J. Lumin. 204, 157 (2018)
X. Zhang, J. Yu, J. Wang, B. Lei, Y. Liu, Y. Cho, R.J. Xie, H.W. Zhang, Y. Li, Z. Tian, Y. Li, Q. Su, ACS Photonics 4, 986 (2017)
H. Yoo, Y. Kouhara, H.C. Yoon, S.J. Park, J.H. Oh, Y.R. Do, RSC Adv. 6, 111640 (2016)
C.K. Chang, T.M. Chen, Appl. Phys. Lett. 91, 081902 (2007)
Z.J. Wang, P.L. Li, Z.P. Yang, Q.L. Guo, G.S. Fu, Chin. Phys. Lett. 26, 117802 (2009)
G. Li, D. Geng, M. Shang, Y. Zhang, C. Peng, Z. Cheng, J. Lin, J. Phys. Chem. C 115, 21882 (2011)
C.H. Huang, T.M. Chen, J. Phys. Chem. C 115, 2349 (2011)
J. Sun, Z. Lian, G. Shen, D. Shen, RSC. Adv. 3, 18395 (2013)
G. Zhu, Y. Wang, Z. Ci, B. Liu, Y. Shi, S. Xin, J. Electrochem. Soc. 158, J236 (2011)
Y. Wang, H. Zhang, Q. Wei, C. Su, D. Zhang, Ceram. Int. 42, 12422 (2016)
M. Zhao, Z. Zhao, L. Yu, L. Yang, J. Jiang, X. Li, G. Li, J. Mater. Sci.: Mater. Electron. 29, 1832 (2018)
F. Wei, Q. Jia, Superlattices Microstruct. 82, 11 (2015)
Z. Wei, Y. Wang, X. Zhu, J. Guan, W. Mao, J. Song, Chem. Phys. Lett. 648, 8 (2016)
Y. Wu, T. He, H. Mao, Ceram. Int. 44, 10015 (2018)
Q. Peng, C. Liu, D. Hou, W. Zhou, C.G. Ma, G. Liu, M.G. Brik, Y. Tao, H. Liang, J. Phys. Chem. C 120, 569 (2016)
H.C. Lin, C.Y. Yang, S. Das, C.H. Lu, J. Am. Ceram. Soc. 97, 1866 (2014)
J. Zhang, B. Zhou, X. Wang, Spectrochim. Acta A 165, 85 (2016)
S. Kubota, R.L. Stanger, Y. Suzuyama, H. Yamane, M. Shimada, J. Electrochem. Soc. 149, H134 (2002)
J. Zhong, D. Chen, Y. Yuan, L. Chen, H. Yu, Z. Ji, Chem. Eng. J. 309, 795 (2017)
H. Ji, Z. Huang, Z. Xia, M.S. Molokeev, V.V. Atuchin, M. Fang, S. Huang, Inorg. Chem. 53, 5129 (2014)
H. Ji, Z. Huang, Z. Xia, M.S. Molokeev, M. Chen, V.V. Atuchin, M. Fang, Y.G. Liu, X. Wu, J. Am. Ceram. Soc. 98, 3280 (2015)
Y. Wei, C.C. Lin, Z. Quan, M.S. Molokeev, V.V. Atuchin, T.S. Chan, Y. Liang, J. Lin, G. Li, RSC Adv. 6, 57261 (2016)
Z. Xia, Y. Zhang, M.S. Molokeev, V.V. Atuchin, J. Phys. Chem. C 117, 20847 (2013)
Z. Zhang, C. Ma, R. Gautier, M.S. Molokeev, Q. Liu, Z. Xia, Adv. Func. Mater. 28, 1804150 (2018)
S. Liang, P. Dang, G. Li, M.S. Molokeev, Y. Wei, Y. Wei, H. Lian, M. Shang, A.A. Al Kheraif, J. Lin, J. Mater. Chem. C 6, 6714 (2018)
K. Li, M. Shang, Y. Zhang, J. Fan, H. Lian, J. Lin, J. Mater. Chem. C 3, 7096 (2015)
Y. Li, H. Li, B. Liu, J. Zhang, Z. Zhao, Z. Yang, Y. Wen, Y. Wang, J. Phys. Chem. Solids 74, 175 (2013)
B. Li, H. Zhang, A. Lan, H. Tang, Superlattices Microstruct. 82, 425 (2015)
M. Zhao, Z. Zhao, L. Yang, X. Wang, F. Yan, C. Xing, J. Mater. Sci.: Mater. Electron. 28, 16008 (2017)
Y. Yang, B. Liu, Y. Zhang, X. Lv, L. Wei, X. Wang, Superlattices Microstruct. 90, 227 (2016)
D. Zeng, Y. Chen, Y. Cai, C. Peng, S. Peng, J. Lumin. 206, 376 (2019)
Acknowledgements
This work was supported by the Scientific Research Subject of Jilin Vocational College of Industry and Technology [16ky06].
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Li, C. Photoluminescence investigation of color-tunable Ca3La6(SiO4)6:Eu2+/Mn2+ phosphors. J Mater Sci: Mater Electron 30, 6832–6837 (2019). https://doi.org/10.1007/s10854-019-00995-w
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DOI: https://doi.org/10.1007/s10854-019-00995-w