Skip to main content
SpringerLink
Log in

Study on thermal conductive epoxy adhesive based on adopting hexagonal boron nitride/graphite hybrids

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

The effect of hybrid filler on newly developed thermal conductive epoxy adhesive has been reported in this paper. The hybrid filler containing hexagonal boron nitride (h-BN) and graphite (Gr) with the mass ratio of 1:1 was loaded in to the epoxy resin with different wt% ratio (10:90, 20:80, 30:70, 40:60, 50:50 and 60:40). The corresponding thermal conductivity of adhesives was measured using guarded heat flow meter technique which enhanced up to 2.025 W/mK with the loading of 60 wt% of hybrid filler. Lap shear strength of the adhesive containing 40 wt% of hybrid filler was higher than the pristine epoxy resin thereby confirming reinforcing effect of hybrid filler into the epoxy matrix. Afterward, the shear viscosity of uncured epoxy resin filled with hybrid fillers were analyzed by using parallel plate rheometry. Strong shear thinning behavior was exhibited at higher hybrid filler loading. Further, lower loss factor and higher Tg values were observed with increase in the hybrid filler (h-BN/Gr) loading thereby confirming the higher cross linking density and lower mobility of epoxy chain. Thermal stability of hybrid Gr/BN–epoxy composite adhesives was studied using thermo gravimetric analyzer. Scanning electron microscopy confirmed the uniform deposition of hybrid filler on to the surface of epoxy resin.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. T. Zhou, X. Tianle, X. Wang, D. Liu, Xiong, Carbon 48, 1171 (2010)

    Article  CAS  Google Scholar 

  2. J. Gu, Q. Zhang, J. Dang, C. Xie, Polym. Adv. Technol. 23, 1025 (2012)

    Article  CAS  Google Scholar 

  3. A.K. Singh, B.P. Panda, S. Mohanty, S.K. Nayak, M.K. Gupta, J. Mater. Sci.: Mater. Electron. 28, 8908 (2017)

    CAS  Google Scholar 

  4. Z. Wang, R. Qi, J. Wang, S. Qi, Ceram. Int. 41, 13541 (2015)

    Article  CAS  Google Scholar 

  5. G. Wu, Y. Cheng, Z. Wang, K. Wang, K. Wang, A. Feng, J. Mater. Sci.: Mater. Electron. 28, 576 (2017)

    CAS  Google Scholar 

  6. Z. Jia, K. Lin, G. Wu, H. Xing, H. Wu, Nano 13, 1 (2018)

    Article  CAS  Google Scholar 

  7. K. Srinivas, M.S. Bhagyashekar, JMMCE 3, 76 (2015)

    Article  CAS  Google Scholar 

  8. G. Wu, Y. Cheng, K. Wang, Y. Wang, A. Feng, J. Mater. Sci.: Mater. Electron. 27, 5592 (2017)

    Google Scholar 

  9. A. Yu, P. Ramesh, X. Sun, E. Bekyarova, M.E. Itkis, R.C. Haddon, Adv. Mater. 20, 4740 (2008)

    Article  CAS  Google Scholar 

  10. E. Baruch, L. Bielenki, O. Regev, Rev. Chem. Eng. 28, 61 (2012)

    Article  CAS  Google Scholar 

  11. S. Kemaloglu, G. Ozkoc, A. Aytac, Thermochim. Acta 499, 40 (2010)

    Article  CAS  Google Scholar 

  12. N.K. Mahanta, M.R. Loos, I.M. Zlocozower, A.R. Abramson, J. Mater. Res. 30, 959 (2015)

    Article  CAS  Google Scholar 

  13. P.G. Ren, X.H. Si, Z.F. Sun, F. Ren, L. Pei, S.Y. Hou, J. Polym. Res. 23, 21 (2016)

    Article  Google Scholar 

  14. J.G. Kovács, A. Suplicz, in The 19th International Conference on Composite Materials, p. 4011 (2013)

  15. G. Wu, Y. Cheng, Z. Wang, K. Wang, A. Feng, RSC Adv. 6, 102542 (2016)

    Article  CAS  Google Scholar 

  16. Z. Han, A. Fina, Prog. Polym. Sci. 36, 914 (2011)

    Article  CAS  Google Scholar 

  17. I. Novák, I. Krupa, Eur. Polym. J. 40(7), 1417 (2004)

    Article  Google Scholar 

  18. H. Luo, Q. Wei, Z.M. Yu, Y. Wang, H. Long, Y. Xie, Ceram. Int. 41, 12052 (2015)

    Article  CAS  Google Scholar 

  19. S. Lingamneni, A.M. Marconnet, K.E. Goodson, ASME (2013)

  20. M. Brown, K. Jagannadham, J. Electron. Mater. 44, 2624 (2015)

    Article  CAS  Google Scholar 

  21. W. Park, Y. Guo, X. Li, J. Hu, L. Liu, X. Ruan, Y.P. Chen, J. Phys. Chem. C 119, 26753 (2015)

    Article  CAS  Google Scholar 

  22. M.F. Shahil, A.A. Balandin, Solid State Commun. 152, 1331 (2012)

    Article  CAS  Google Scholar 

  23. B. Lee, J.Z. Liu, B. Sun, C.Y. Shen, G.C. Dai, Express Polym. Lett. 2, 357 (2008)

    Article  CAS  Google Scholar 

  24. G. Wu, Y. Cheng, Z. Wang, K. Wang, A. Feng, J. Mater. Sci.: Mater. Electron. 28, 576 (2017)

    CAS  Google Scholar 

  25. R. Moosaei, M. Sharif, A. Ramezannezhad, Polym. Test. 60, 173 (2017)

    Article  CAS  Google Scholar 

  26. T.V. Kosmidou, A.S. Vatalis, C.G. Delides, E. Logakis, P. Pissis, G.C. Papanicolaou, Express Polym. Lett. 2, 364 (2008)

    Article  CAS  Google Scholar 

  27. H. Im, J. Kim, Carbon 50, 5429 (2012)

    Article  CAS  Google Scholar 

  28. K. Kumar, P.K. Ghosh, A. Kumar, Compos. B 97, 353 (2016)

    Article  CAS  Google Scholar 

  29. S. Chandrasekaran, C. Seidel, K. Schulte, Eur. Polym. J. 49, 3878 (2013)

    Article  CAS  Google Scholar 

  30. G. Wu, J. Li, K. Wang, K. Wang, Y. Feng, C. Pan, A. Feng, J. Mater. Sci.: Mater. Electron. 28, 6544 (2017)

    CAS  Google Scholar 

  31. H. Fang, X. Zhang, Y. Zhao, S.L. Bai, Compos. Sci. Technol. 152, 243 (2017)

    Article  CAS  Google Scholar 

  32. R. Meier, I. Kahraman, A.T. Seyhan, S. Zaremba, K. Drechsler, Compos. Sci. Technol. 128, 94 (2016)

    Article  CAS  Google Scholar 

  33. Y. Liu, H.V. Babu, J. Zhao, A.G. Urtiaga, R. Sainz, R. Ferritto, M. Pita, D.Y. Wang, Compos. B 89, 108 (2016)

    Article  Google Scholar 

  34. J. Gu, X. Yang, Z. Lv, N. Li, C. Liang, Q. Zhang, Int. J. Heat Mass Transf. 92, 15 (2016)

    Article  CAS  Google Scholar 

  35. S. Zhou, Y. Chen, H. Zou, M. Liang, Thermochim. Acta 566, 84 (2013)

    Article  CAS  Google Scholar 

  36. S. Gantayat, G. Prusty, D.R. Rout, S.K. Swain, New Carbon Mater. 30, 432 (2015)

    Article  Google Scholar 

  37. L. Diaz-Chacon, R. Metz, P. Dieudonne, J.L. Bantignies, S. Tahir, M. Hassanzadeh, R. Atencio, J. Mater. Sci. Chem. Eng. 3, 75 (2015)

    CAS  Google Scholar 

Download references

Acknowledgements

This work is supported by Board of Research in Nuclear Science-BRNS (Grant No. 39/14/01/2018-BRNS/39001), Department of Atomic Energy (DAE), Govt. of India.

Author information

Authors and Affiliations

  1. SARP-Laboratory for Advanced Research in Polymeric Materials (LARPM), Central Institute of Plastics Engineering & Technology (CIPET), B-25, Infocity Road, Patia, Bhubaneswar, Odisha, 751024, India

    Rajesh Kumar, Sagar Kumar Nayak, Swarnalata Sahoo, Bishnu P. Panda, Smita Mohanty & Sanjay K. Nayak

Authors
  1. Rajesh Kumar
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Sagar Kumar Nayak
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Swarnalata Sahoo
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Bishnu P. Panda
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Smita Mohanty
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Sanjay K. Nayak
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Rajesh Kumar.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kumar, R., Nayak, S.K., Sahoo, S. et al. Study on thermal conductive epoxy adhesive based on adopting hexagonal boron nitride/graphite hybrids. J Mater Sci: Mater Electron 29, 16932–16938 (2018). https://doi.org/10.1007/s10854-018-9788-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-018-9788-3

Search

Navigation