Abstract
The Li2O–MO–WO3 (M = Co, Ni, Ca, Ba) ceramics for ultra-low temperature co-fired ceramic application were prepared by using the conventional solid-state reaction route. The phase composition, microstructures, and microwave dielectric properties of the compounds were investigated systematically. The X-ray diffraction patterns show that the Li2O–MO–WO3 (M = Co, Ni) consist of CoWO4 (NiWO4), Li2WO4 and Li2W2O7 phases while Li2O–MO–WO3 (M = Ca, Ba) comprises CaWO4 (BaWO4) and Li2WO4 phases. The porosity and phase constitution acted as a controlling factor of dielectric constant in the Li2O–MO–WO3 (M = Co, Ni, Ca, Ba) ceramics. These compounds can be sintered at ultra-low temperature of 600–680 °C and exhibit good microwave dielectric properties with εr = 5.6–13.5, Q × f = 13,000–25,000 GHz, and τf =− 97.3 to − 38.3 ppm/°C, which made the compounds promising for multilayer ultra-low temperature cofiring dielectrics application.
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References
M.T. Sebastian, H. Wang, H. Jantunen, Solid State Mater. Sci. 20, 151 (2016)
S.E. Kalathil, U.A. Neelakantan, R. Ratheesh, J. Am. Ceram. Soc. 97, 1530 (2014)
A.N. Unnimaya, E.K. Suresh, R. Ratheesh, Eur. J. Inorg. Chem. 2, 305 (2015)
H. Yu, J. Liu, W. Zhang, S. Zhang, J. Mater. Sci. Mater. Electron. 26, 9414 (2015)
M.T. Sebastian, R. Ubic, H. Jantunen, Int. Mater. Rev. 60, 392 (2015)
H. Zhou, H. Wang, Y. Chen, K. Li, X. Yao, Mater. Chem. Phys. 113, 1 (2009)
D. Zhou, C.A. Randall, L.X. Pang, H. Wang, J. Guo, G.Q. Zhang, X.G. Wu, L. Shui, X. Yao, J. Am. Ceram. Soc. 94, 348 (2011)
L. Fang, Z.H. Wei, C.X. Su, F. Xiang, H. Zhang, Ceram. Int. 40, 16835 (2014)
D.K. Kwon, M.T. Lanagan, T.R. Shrout, J. Am. Ceram. Soc. 88, 3419 (2005)
D. Zhou, L.X. Pang, H. Wang, X. Yao, J. Eur. Soc. 31, 2749 (2011)
S.H. Yoon, D.-W. Kim, S.-Y. Cho, K.S. Hong, J. Eur. Ceram. Soc. 26, 2051 (2006)
R.C. Pullar, S. Farrah, N.M.N. Alford, J. Eur. Ceram. Soc. 27, 1059 (2007)
L. Wang, J.J. Bian, Mater. Lett. 65, 726 (2011)
Z. Zhang, H. Su, X. Tang, H. Zhang, T. Zhou, Y. Jing, Ceram. Int. 40, 1613 (2014)
B.W. Hakki, P.D. Coleman, IEEE Trans. Microw. Theory Tech. 8, 402 (1960)
W.E. Courtney, IEEE Trans. Microw. Theory Tech. 18, 476 (1970)
J.J. Bian, J.Y. Wu, L. Wang, J. Eur. Ceram. Soc. 32, 1251 (2012)
J. Zhang, R. Zuo, Mater. Lett. 158, 92 (2015)
Y.M. Chiang, D. Birnie, W.D. Kingery, Physical Ceramics—Principles for Ceramics Science and Engineering (Wiley, New York, 1997)
S. George, M.T. Sebastian, J. Eur. Ceram. Soc. 30, 2585 (2010)
A.Y. Borisevich, P.K. Davies, J. Am. Ceram. Soc. 85, 573 (2002)
S. Hillier, Clay Miner. 35, 291 (2000)
J. Chen, C. Li, D. Wang, H. Xiang, L. Fang, J. Adv. Dielectr. 07, 1720001-1 (2017)
Y. Wu, X. Zhao, F. Li, Z. Fan, J. Electroceram. 11, 227 (2003)
C.F. Tseng, P.J. Tseng, C.M. Chang, Y.C. Kao, J. Am. Ceram. Soc. 97, 1918 (2014)
Acknowledgements
This work was sponsored by the Ministry of Science and Technology of the Republic of China under Grant MOST 104-2221-E-239 -008.
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Tseng, CF., Chiang, CH., Chen, PH. et al. Ultra-low temperature fired glass-free Li2O–MO–WO3 (M = Co, Ni, Ca, Ba) microwave dielectric ceramics. J Mater Sci: Mater Electron 29, 14835–14841 (2018). https://doi.org/10.1007/s10854-018-9620-0
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DOI: https://doi.org/10.1007/s10854-018-9620-0