Abstract
Ti-doped (Cu0.5Tl0.5)Ba2(Ca2−xTix)Cu3O10−δ (x = 0, 0.25, 0.50, 0.75, 1.0) superconductors have been synthesized by solid state reaction method. The prepared samples are characterized by XRD, electrical resistivity, AC susceptibility and FTIR techniques. XRD analysis showed that the lattice parameters are marginally altered but there is no substantial change with the doping of Ti. All the samples are found with orthorhombic crystal structure following PMMM space group. Tc(R = 0) is enhanced with the doping of Ti except for x = 1.0 sample. The magnitude of diamagnetism in the AC-susceptibility measurements is enhanced up to x = 0.5 and decreased beyond. The FTIR measurements show that the apical oxygen phonon modes are softened. The planar oxygen phonon modes are softened but their intensity is raised with the enhanced Ti contents. This softening of the planar oxygen phonon modes may be arising due to the heavier Ti ions (47.9 amu) at the lighter Ca (40.07 amu) sites. Variation in the lattice parameters in the XRD data and shifting of various oxygen phonon modes in the FTIR data show that Ti is incorporated at Ca sites in the unit cell. Increase in the superconducting properties up to certain doping level (x = 0.75) may be arising due to the improved interplane coupling caused by the smaller sized Ti at Ca sites. While the decrease in Tc and magnitude of diamagnetism beyond x = 0.75 and x = 0.5 respectively, is attributed to the suppressed density of a particular type of phonons required for optimum superconductivity. This suppression in the density of the desired phonons is brought about by the substitution of heavier Ti ions at the lighter Ca sites. This study signifies the role of electron–phonon interaction in mechanism of high Tc superconductivity.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10854-018-9357-9/MediaObjects/10854_2018_9357_Fig1_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10854-018-9357-9/MediaObjects/10854_2018_9357_Fig2_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10854-018-9357-9/MediaObjects/10854_2018_9357_Fig3_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10854-018-9357-9/MediaObjects/10854_2018_9357_Fig4_HTML.gif)
Similar content being viewed by others
References
M. Karppinen, H. Yamauchi, Y. Morita, M. Kitabatake, T. Motosahi, R.S. Lu, J.M. Lee, J.M. Chen, J. Phys. Chem. Solids 177, 1037 (2004)
H. Zhang, H. Sato, Phys. Rev. Lett. 70, 1697 (1993)
J. Orenstein, A.J. Millis, Science 288, 468 (2000)
T.H. Geballe, Science 259, 1550 (1993)
C. Park, R.L. Synder, J. Am. Ceram. Soc. 78, 3171 (1995)
M. Mumtaz, N. A. Khan, S. Khan, J. Appl. Phys. 107, 103905 (2010)
N. A. Khan, J. Asim, A. A. Khurram, H. Naghma, Physica C 425, 90 (2005)
N.A. Khan, M. Shamraiz, J. Phys. 439, 012022 (2013)
N.A. Khan, M. Rahim, J. Alloy Compd. 481, 81 (2009)
M. Rahim, N.A. Khan, J. Alloy Compd. 513, 55 (2012)
N.A. Khan, A. Raza, J. Supercond. Novel Magn. 23, 199 (2010)
J. Bardeen, L.N. Cooper, J.R. Schrieffer, Phys. Rev. 108, 1175 (1957)
H. Ihara, A. Iyo, K. Tanaka, K. Tokiwa, K. Ishida, N. Terada, M. Tokumoto, Y. Sekita, T. Tsukamoto, T. Watanabe, M. Umeda, Physica C 282–287, 1973 (1997)
M. Tinkham, Introduction to Superconductivity, 2nd edn. (McGraw-Hill, Inc., New York, 1996)
H. Ihara, A. Iyo, K. Tanaka, K. Tokiwa, N. Terada, M. Tokumoto, K. Ishida, M. Umeda, Adv. Supercond. IX, 277 (1996)
M.A. Halcrow, Chem. Soc. Rev. 42, 1784 (2013)
T. Hashimoto, S. Ishibashi, K. Terakura, Phys. Rev. B 82, 045124 (2010)
N. Hassan, N.A. Khan, Mater. Chem. Phys. 112, 412 (2008)
N.A. Khan, M. Arif, Physica C 488, 35 (2013)
Acknowledgements
Higher Education Commission of Pakistan (HEC) through project No. 20-1482/R&D/09-1472 and International Center for Theoretical Physics (ICTP) through project number PRJ-27 are highly acknowledged for their financial support.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Arif, M., Rahim, M., Hassan, N. et al. Enhanced superconducting properties of Ti doped (Cu0.5Tl0.5)Ba2(Ca2−xTix)Cu3O10−δ samples. J Mater Sci: Mater Electron 29, 12414–12418 (2018). https://doi.org/10.1007/s10854-018-9357-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-018-9357-9