Skip to main content
Log in

Facile synthesis of novel I-doped Bi4O5Br2 nanosheets with enhanced visible light photocatalytic activity

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

I-doped Bi4O5Br2 (I-Bi4O5Br2) nanosheets have been synthesized by a facile anion exchange method at room temperature. The formed I-Bi4O5Br2 products have been characterized by means of X-ray diffraction, scanning electron microscopy, transmission electron microscopy, UV–Vis diffuse reflectance and X-ray photoelectron spectroscopy. I-Bi4O5Br2 nanosheets with good crystallinity and a band gap energy of 2.36 eV have stronger absorption in the visible-light region. Compared to pure Bi4O5Br2, I-Bi4O5Br2 photocatalysts showed better performance for methyl orange degradation under visible light irradiation, which could be ascribed to more visible light harvest and more effective separation of photo-generated carriers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. A. Tolosana-Moranchel, J.A. Casas, J. Carbajo, M. Faraldos, A. Bahamonde, Appl. Catal. B 200, 164–173 (2017)

    Article  Google Scholar 

  2. C. Anupama, A. Kaphle, G. Udayabhanu, Nagaraju, J. Mater. Sci.: Mater. Electron. 29, 4238–4249 (2018)

    Google Scholar 

  3. M.C. Long, L.H. Zheng, Chin. J. Catal. 38, 617–624 (2017)

    Article  Google Scholar 

  4. L.H. Zheng, X.J. Yu, M.C. Long, Q.L. Li, Chin. J. Catal. 38, 2076–2084 (2017)

    Article  Google Scholar 

  5. H.J. Chen, Z.F. Zhou, G.N. Greaves, S. Nigar, H.Q. Cao, T.K. Zhao, X.G. Lu, RSC Adv. 8, 914–920 (2018)

    Article  Google Scholar 

  6. A.C. Mera, H. Valdes, F.J. Jamett, M.F. Melendrez, Solid State Sci. 65, 15–21 (2017)

    Article  Google Scholar 

  7. J.C. Sin, C.A. Lim, S.M. Lam, A.R. Mohamed, J. Mater. Sci.: Mater. Electron. 28, 13236–13246 (2017)

    Google Scholar 

  8. X. Xiao, C. Liu, R.P. Hu, X.X. Zuo, J.M. Nan, L.S. Li, L.S. Wang, J. Mater. Chem. 22, 22840–22843 (2012)

    Article  Google Scholar 

  9. S.S. Ding, D.J. Mao, S.G. Yang, F. Wang, L.J. Meng, M.S. Han, H. He, C. Sun, B. Xu, Appl. Catal. B 210, 386–399 (2017)

    Article  Google Scholar 

  10. X.Y. Xiong, T.F. Zhou, X.F. Liu, S.P. Ding, J.C. Hu, J. Mater. Chem. A 5, 15706–15713 (2017)

    Article  Google Scholar 

  11. Q.F. Han, K.K. Zhang, J. Zhang, S. Gong, X. Wang, J.W. Zhu, Chem. Eng. J. 299, 217–226 (2016)

    Article  Google Scholar 

  12. D.J. Mao, S.S. Ding, L.J. Meng, Y.X. Dai, C. Sun, S.G. Yang, H. He, Appl. Catal. B 207, 153–165 (2017)

    Article  Google Scholar 

  13. X.M. Mao, F.X. Xie, M. Li, Mater. Lett. 166, 296–299 (2016)

    Article  Google Scholar 

  14. R. Li, F.X. Xie, J.X. Liu, Y.W. Wang, Y.F. Wang, X.C. Zhang, C.M. Fan, Dalton Trans. 45, 9182–9186 (2016)

    Article  Google Scholar 

  15. M. Li, Y.J. Cui, Y.S. Jin, H. Li, RSC Adv. 6, 47545–47551 (2016)

    Article  Google Scholar 

  16. G.J. Wu, Y. Zhao, Y.W. Li, B. Souvanhthong, H.M. Ma, J.Z. Zhao, Ceram. Int. 44, 5392–5401 (2018)

    Article  Google Scholar 

  17. L.X. Zheng, S.C. Han, H. Liu, P.P. Yu, X.S. Fang, Small 12, 1527–1536 (2016)

    Article  Google Scholar 

  18. X.J. Xu, L.F. Hu, N. Gao, S.X. Liu, S. Wageh, A.A. Al-Ghamdi, A. Alshahrie, X.S. Fang, Adv. Funct. Mater. 25, 445–454 (2015)

    Article  Google Scholar 

  19. M.X. Ji, J. Di, Y.P. Ge, J.X. Xia, H.M. Li, Appl. Surf. Sci. 413, 372–380 (2017)

    Article  Google Scholar 

  20. J. Di, M.X. Ji, J.X. Xia, X.W. Li, W.M. Fan, Q. Zhang, H.M. Li, J. Mol. Catal. A 424, 331–341 (2016)

    Article  Google Scholar 

  21. D. Wu, M. Long, W. Cai, C. Chen, Y. Wu, J. Alloys Compd. 502, 289–294 (2010)

    Article  Google Scholar 

  22. Y. Zhou, L. Yang, L. Jiang, Y.Y. Song, Q. Xu, J. Mater. Sci.: Mater. Electron. 28, 18164–18172 (2017)

    Google Scholar 

  23. C.J. Bi, J. Cao, H.L. Lin, Y.J. Wang, S.F. Chen, RSC Adv. 6, 15525–15534 (2016)

    Article  Google Scholar 

  24. K. Kalantari, M. Kalbasi, M. Sohrabi, S.J. Royaee, Ceram. Int. 42, 14834–14842 (2016)

    Article  Google Scholar 

  25. X. Xiao, M.L. Lu, J.M. Nan, X.X. Zuo, W.D. Zhang, S.M. Liu, S.B. Wang, Appl. Catal. B 218, 398–408 (2017)

    Article  Google Scholar 

  26. J. Di, J.X. Xia, M.X. Ji, S. Yin, H.P. Li, H. Xu, Q. Zhang, H.M. Li, J. Mater. Chem. A 3, 15108–15118 (2015)

    Article  Google Scholar 

  27. D. Wu, M. Long, Surf. Coat. Technol. 206, 3196–3200 (2012)

    Article  Google Scholar 

  28. L.M. Yun, Z.X. Yang, Z.B. Yu, T.F. Cai, Y. Li, C.Y. Guo, C.Y. Qi, T.Q. Ren, RSC Adv. 7, 25455–25460 (2017)

    Article  Google Scholar 

  29. C.X. Zheng, G.P. He, X. Xiao, M.L. Lu, H. Zhong, X.X. Zuo, J.M. Nan, Appl. Catal. B 205, 201–210 (2017)

    Article  Google Scholar 

  30. H. Wan, L. Xu, W.Q. Huang, G.F. Huang, C.N. He, J.H. Zhou, P. Peng, Appl. Phys. A 116, 741–750 (2014)

    Article  Google Scholar 

  31. K. Yang, D.F. Li, W.Q. Huang, L. Xu, G.F. Huang, S. Wen, Appl. Phys. A 123, 96 (2016)

    Article  Google Scholar 

  32. T.T. He, D.Y. Wu, Y.B. Tan, Mater. Lett. 165, 227–230 (2016)

    Article  Google Scholar 

  33. X.X. Wang, Q. Ni, D.W. Zeng, G.L. Liao, Y.W. Wen, B. Shan, C.S. Xie, Appl. Surf. Sci. 396, 590–598 (2017)

    Article  Google Scholar 

  34. Z.C. Shen, Q.F. Han, X. Wang, J.W. Zhu, Mater. Lett. 214, 103–106 (2018)

    Article  Google Scholar 

  35. L. Liang, J. Cao, H.L. Lin, X.M. Guo, M.Y. Zhang, S.F. Chen, Appl. Surf. Sci. 414, 365–372 (2017)

    Article  Google Scholar 

  36. L. Liang, J. Cao, H.L. Lin, X.M. Guo, M.Y. Zhang, S.F. Chen, Mater. Res. Bull. 80, 329–336 (2016)

    Article  Google Scholar 

Download references

Acknowledgements

This project was funded by the National Natural Science Foundation of China (Nos. 21767009, 51408204), and Hubei Key Laboratory of Biological Resources Protection and Utilization (PKLHB1703).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Deyong Wu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wu, D., Wu, C. & Tan, H. Facile synthesis of novel I-doped Bi4O5Br2 nanosheets with enhanced visible light photocatalytic activity. J Mater Sci: Mater Electron 29, 11090–11095 (2018). https://doi.org/10.1007/s10854-018-9191-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-018-9191-0

Navigation