Abstract
Bluish green emitting phosphor, Ca3Al2O6:Ce3+, is prepared by low-temperature combustion method. X-ray diffraction, photoluminescence, scanning electron microscopy techniques are used to characterize the synthesized phosphor. The most efficient bluish green (483 nm) emission is observed under the excitation by near UV light. The emission characteristics are credited to 5d → 4f type transitions in Ce3+. The luminescence properties of Eu2+ are predicted for the first time from those of Ce3+. Also, photoluminescence of Eu3+ is studied in the same host. The emission spectrum of Ca3Al2O6:Eu3+ shows the peak at 592 (orange) and 614 nm (red) wavelengths. Ca3Al2O6:Ce3+phosphor can be a potential blue phosphor for field emission display, solid-state lighting and LED.
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References
P.F. Smet, A.B. Parmentier, D. Poelman, Selecting conversion phosphors for white light-emitting diodes. J. Electrochem. Soc. 158, 37–54 (2011)
L. Chen, C.C. Lin, C.W. Yeh, R.S. Liu, Light converting inorganic phosphors for white light-emitting diodes. Materials 3, 2172–2195 (2010)
C.C. Lin, R.S. Liu, Advances in phosphors for light-emitting diodes. J. Phys. Chem. Lett. 2, 1268–1277 (2011)
S. Ye, F. Xiao, Y.X. Pan, Y.Y. Ma, Q.Y. Zhang, Phosphors in phosphor-converted white light-emitting diodes: recent advances in materials, techniques and properties. Mater. Sci. Eng. R 71, 1–34 (2010)
A. Zukauskas, R. Vaicekauskas, F. Ivanauskas, H. Vaitkevicius, M.S. Shur, Spectral optimization of phosphor-conversion light-emitting diodes for ultimate color rendering. App. Phys. Lett. 93, 051115 (2008)
B. Han, J. Zhang, Y. Lu, Novel emitting-color tunable phosphors Ba3Y2(BO3)4: Ce3+, Tb3+ with efficient energy transfer for near-UV light-emitting diodes. J. Am. Ceram. Soc. 96, 179–183 (2013)
M. Shang, G. Li, D. Geng, D. Yang, X. Kang, Y. Zhang, H. Lian, J. Lin, Blue emitting Ca8La2(PO4)6O2:Ce3+/Eu2+ phosphors with high color purity and brightness for white LED: soft-chemical synthesis, luminescence, and energy transfer properties. J. Phys. Chem. C 116, 10222–10231 (2012)
Y.F. Wu, Y.H. Chan, Y.T. Nien, I.G. Chen, Crystal structure and optical performance of Al3+ and Ce3+ codoped Ca3Sc2Si3O12 green phosphors for white LEDs. J. Am. Ceram. Soc. 96, 234–240 (2013)
Y. Shimomura, T. Honma, M. Shigeiwa, T. Akai, K. Okamoto, N. Kijima, Photoluminescence and crystal structure of green-emitting Ca3Sc2Si3O12:Ce3+ phosphor for white light emitting diodes. J. Electrochem. Soc. 154, 35–38 (2007)
Y.C. Wu, Y.C. Chen, D.Y. Wang, C.S. Lee, C.C. Sun, T.M. Chen, α-(Y,Gd)FS:Ce3+: a novel red-emitting fluorosulfide phosphor for solid-state lighting. J. Mater. Chem. 21, 15163–15166 (2011)
H.S. Jang, H.Y. Kim, Y.S. Kim, H.M. Lee, D.Y. Jeon, Yellow-emitting γ-Ca2SiO4:Ce3+, Li+ phosphor for solid-state lighting: luminescent properties, electronic structure, and white light-emitting diode application. Opt. Exp. 20, 2761–2771 (2012)
W.B. Im, K. Page, S.P. DenBaars, R. Seshadri, Probing local structure in the yellow phosphor LaSr2AlO5:Ce3+, by the maximum entropy method and pair distribution function analysis. J. Mater. Chem. 19, 8761–8766 (2009)
W.B. Im, N.N. Fellows, S.P. DenBaars, R. Seshadri, Y.I. Kim, LaSr2AlO5, a versatile host compound for Ce3+-based yellow phosphors: structural tuning of optical properties and use in solid-state white lighting. Chem. Mater. 21, 2957–2966 (2009)
H. Ju, W. Deng, B. Wang, J. Liu, X. Tao, S. Xu, The structure and luminescence properties of green Ca3Al2O6:Bi3+ phosphors. J. Alloys Compd. 516, 153–156 (2012)
Z. Tianliang, S. Zhen, B. Liu, R. Qingyong, L. Quanlin, Synthesis and luminescence properties of europium activated Ca3Al2O6-Sr3Al2O6 system. J. Rare Earths 30, 632–636 (2012)
X. Yuan, Y.B. Xu, Y.Y. He, Synthesis of Ca3Al2O6 via citric acid precursor. Mater. Sci. Eng. A 447, 142–145 (2007)
S.J. Lee, E.A. Benson, W.M. Kriven, Preparation of portland cement components by poly(vinyl alcohol) solution polymerization. J. Am. Ceram. Soc. 82, 2049–2055 (1999)
P. Dorenbos, Relation between Eu2+ and Ce3+ f ↔ d-transition energies in inorganic compounds. J. Phys. Condens. Matter. 15, 4797–4807 (2003)
L.G. van Uitert, An empirical relation fitting the position in energy of the lower d-band edge for Eu2+ or Ce3+ in various compounds. J. Lumin. 29, 1–9 (1984)
J.J. Kingsley, N. Manickam, K.C. Patil, Combustion synthesis and properties of fine particle fluorescent aluminous oxides. Bull. Mater. Sci. 13, 179–189 (1990)
P. Mondal, J. Jeffery, The crystal structure of tricalcium aluminate, Ca3Al2O6. Acta Crystallogr. B 31, 689–697 (1975)
W. Chen, Y. Wang, X. Xu, W. Zeng, Y. Gong, A new long-lasting phosphor Ce3+ doped Ca3Al2O6. ECS Solid State Lett. 1, 17–19 (2012)
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Gedekar, K.A., Wankhede, S.P., Moharil, S.V. et al. Synthesis, crystal structure and luminescence in Ca3Al2O6. J Mater Sci: Mater Electron 29, 6260–6265 (2018). https://doi.org/10.1007/s10854-018-8603-5
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DOI: https://doi.org/10.1007/s10854-018-8603-5