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Barium titanate@polyaniline core–shell semiconducting particles reinforced poly(vinylidene fluoride) flexible films with a percolation threshold and high dielectric constant

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Abstract

Barium titanate@polyaniline (BT@PANI) core–shell semiconducting particles were prepared by the introduction of polyacrylic acid onto the surface of BT via in-stiu polymerization. Polyvinylidene fluoride (PVDF) based composites filling BT@PANI particles with 3.336 × 10−2 S cm−1 presented positive multiple effect in enhancing dielectric constant of the three-phase composites. A percolation threshold appeared at a BT@PANI loading of 30 wt%, where the composite exhibited a high dielectric constant of 247 at 103 Hz, as well as winding and folding performance. The excellent dielectric behavior could be ascribed to the fact that the BT@PANI/PVDF composites realized multiple dielectric mechanisms, including the sufficient interfacial polarization, the effective BT polarization, and the microcapacitor mechanism. As a result, the novelty ceramic particles/polymer composite films presented a good balance of dielectric performance and mechanical property.

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Acknowledgements

Financial support provided by the National Natural Science Foundation of China (51767016) is gratefully acknowledged.

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Authors and Affiliations

  1. State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou, 730050, China

    Hai-Yan Wang, Xiao-Ting Zhang, Yan-bin You & Xiao-bin Yan

  2. Department of Polymer Science and Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing, 100083, China

    Jun-Wei Zha

  3. State Key Laboratory of Power System, Department of Electrical Engineering, Tsinghua University, Beijing, 100084, China

    Zhi-Min Dang

Authors
  1. Hai-Yan Wang
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  2. Xiao-Ting Zhang
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  3. Jun-Wei Zha
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  4. Yan-bin You
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  5. Xiao-bin Yan
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  6. Zhi-Min Dang
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Correspondence to Hai-Yan Wang or Zhi-Min Dang.

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Wang, HY., Zhang, XT., Zha, JW. et al. Barium titanate@polyaniline core–shell semiconducting particles reinforced poly(vinylidene fluoride) flexible films with a percolation threshold and high dielectric constant. J Mater Sci: Mater Electron 30, 3325–3331 (2019). https://doi.org/10.1007/s10854-018-00605-1

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  • DOI: https://doi.org/10.1007/s10854-018-00605-1

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