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Electrochemical performance and optimization of α-NiMoO4 by different facile synthetic approach for supercapacitor application

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Abstract

Nickel molybdate (NiMoO4) nanoparticles (NPs) are prepared by different synthetic techniques via hydrothermal (SHC), gel-combustion (SGC) and microwave-assisted combustion (SMC) methods. All prepared samples are subjected to calcination at 600 °C to get a pure α-NiMoO4 with a monoclinic crystal structure and their physico-chemical properties are compared. The average crystallite size of SMC is smaller than that of other two methods. Depending on the synthetic process, NiMoO4 NPs exhibits different morphology. Optical band gap energies for all samples are calculated. The cyclic voltammograms signify the occurrence of redox couples and besides with the electrochemical impedance spectra (Nyquist plot) confirm the supercapacitive nature. Among all, the modified SMC electrode material deliver highest specific capacitance value related with scan rate and current density. Nevertheless, SMC exhibits lowest faradic resistance and also grants well permanency with a stable profile of 98.6% retentivity after 1000 cycles results in high electric activity.

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References

  1. X. Han, K. Tao, Q. Ma, L. Han, J. Mater. Sci. Mater. Electron. 29(17), 14697 (2018)

    Article  Google Scholar 

  2. K. Karthik, S. Dhanuskodi, C. Gobinath, S. Prabukumar, S. Sivaramakrishnan, J. Mater. Sci. Mater. Electron. 29(7), 5459 (2018)

    Article  Google Scholar 

  3. M. Rashad, A.M. Ali, M.I. Sayyed, I.V. Kityk, J. Mater. Sci. Mater. Electron. 29(12), 10123 (2018)

    Article  Google Scholar 

  4. A.C. Fernandez, P. Sakthivel, J. Jesudurai, J. Mater. Sci. Mater. Electron. 29(1), 357 (2018)

    Article  Google Scholar 

  5. T. Wang, R. Jin, X. Wu, J. Zheng, X. Li, K. Ostrikov, J. Mater. Chem. A 6, 9228 (2018)

    Article  Google Scholar 

  6. P. Sprenger, W. Kleist, J. Grunwaldt, ACS Catal. 7, 5628 (2017)

    Article  Google Scholar 

  7. J. Xia, L.X. Song, W. Liu, Y. Teng, Q.S. Wang, L. Zhao, M.M. Ruan, RSC Adv. 5, 12015 (2015)

    Article  Google Scholar 

  8. K. Seevakan, A. Manikandan, P. Devendran, A. Shameem, T. Alagesan, Ceram. Int. 44, 13879 (2018)

    Article  Google Scholar 

  9. H. Xuan, Y. Xu, Y. Zhang, H. Li, P. Han, Y. Du, J. Alloys Compd. 745, 135 (2018)

    Article  Google Scholar 

  10. P. Liu, Y. Deng, Q. Zhang, Z. Hu, Z. Xu, Y. Liu, M. Yao, Z. Ai, Ionics 21, 2797 (2015)

    Article  Google Scholar 

  11. B. Senthilkumar, K. Vijaya Sankar, R. Kalai Selvan, M. Danielle, M. Manickam, RSC Adv. 3, 352 (2013)

    Article  Google Scholar 

  12. O.A. Knyazheva, O.N. Baklanova, A.V. Lavrenov, E.A. Buluchevskii, V.A. Drozdov, M.V. Trenikhin, N.N. Leont’eva, A.V. Vasilevich, V.A. Likholobov, Kinet. Catal. 55, 130 (2014)

    Article  Google Scholar 

  13. J. Haetge, I. Djerdj, T. Brezesinski, Chem. Commun. 48, 6726 (2012)

    Article  Google Scholar 

  14. K. Sakthikumar, S. Ede, S. Mishra, S. Kundu, Dalton Trans. 45, 8897 (2016)

    Article  Google Scholar 

  15. G. Kianpour, F. Soofivand, M. Badiei, M. Salavati-Niasari, M. Hamadanian, J. Mater. Sci. Mater. Electron. 27, 10244 (2016)

    Article  Google Scholar 

  16. R. Sundaram, K.S. Nagaraja, Sens. Actuators B 101, 353 (2004)

    Article  Google Scholar 

  17. J.A. Rodriguez, S. Chaturvedi, J.C. Hanson, J.L. Brito, J. Phys. Chem. B 103, 770 (1999)

    Article  Google Scholar 

  18. K. Seevakan, A. Manikandan, P. Devendran, A. Baykal, T. Alagesan, Ceram. Int. 44, 17735 (2018)

    Article  Google Scholar 

  19. K. Seevakan, A. Manikandan, P. Devendran, Y. Slimani, A. Baykal, T. Alagesan, Ceram. Int. 44, 20075 (2018)

    Article  Google Scholar 

  20. A. Kaddouri, R. Anouchinsky, C. Mazzocchia, L.M. Madeira, M.F. Portela, Catal. Today 40, 201 (1998)

    Article  Google Scholar 

  21. R.A. Madeley, S.E. Wanke, Appl. Catal. 39, 295 (1988)

    Article  Google Scholar 

  22. J.H. Ryu, S.M. Koo, J.W. Yoon, C.S. Lim, K.B. Shim, Mater. Lett. 60, 1702 (2006)

    Article  Google Scholar 

  23. A.W. Sleight, B.L. Chamberland, Inorg. Chem. 7, 1672 (1968)

    Article  Google Scholar 

  24. A. Shameem, P. Devendran, V. Siva, K.S. Venkatesh, A. Manikandan, S. Asath Bahadur, N. Nallamuthu, J. Inorg. Organomet. Polym. 28, 671 (2018)

    Article  Google Scholar 

  25. K. Saberyan, F. Soofivand, G. Kianpour, M. Salavati-Niasari, S. Bagheri, J. Mater. Sci. Mater. Electron. 27, 3765 (2016)

    Article  Google Scholar 

  26. V. Hangloo, S. Pandita, K.K. Bamzai, P.N. Kotru, N. Sahni, Cryst. Growth Des. 3, 753 (2003)

    Article  Google Scholar 

  27. N. Nallamuthu, I. Prakash, N. Satyanarayana, M. Venkateswarlu, Mater. Res. Bull. 46, 32 (2011)

    Article  Google Scholar 

  28. P. Devendran, T. Alagesan, K. Pandian, Adv. Mater. Res. 938, 215 (2014)

    Article  Google Scholar 

  29. R. Packiaraj, P. Devendran, S. Asath Bahadur, N. Nallamuthu, J. Mater. Sci. Mater. Electron. 29, 13265 (2018)

    Article  Google Scholar 

  30. J.C. Jansen, A. Arafat, A.K. Barakat, H. Van Bekkum, in Synthesis of Microporous Materials, vol. 1, ed. by M.L. Occelli, H. Robson (Van Nostrand Reinhold, New York, 1992), pp. 507–521

    Google Scholar 

  31. M. Masteri-Farahani, S. Mahdavi, M. Rafizadeh, Ceram. Int. 39, 4619 (2013)

    Article  Google Scholar 

  32. J. Lian, Z. Ding, F. Kwong, H.L. Dickon, Ng, CrystEngCom. 13, 4820 (2011)

    Article  Google Scholar 

  33. S.-M. Lee, S.-N. Cho, J. Cheon, Adv. Mater. 15(5), 441 (2003)

    Article  Google Scholar 

  34. P. Sivakumar, P. Sivakumar, K. Anbarasu, K. Pandian, S. Renganathan, Ind. Eng. Chem. Res. 52, 17676 (2013)

    Article  Google Scholar 

  35. L. Yang, J. Wang, Y. Wan, Y. Li, H. Xie, H. Cheng, H. Jin, Seo, J. Alloys Compd. 664, 756 (2016)

    Article  Google Scholar 

  36. P.K. Pandey, N.S. Bhave, R.B. Kharat, Mater. Res. Bull. 41, 1160 (2006)

    Article  Google Scholar 

  37. L.S. Cavalcante, J.S. Sczancoski, L.F. Lima Jr., J.W.M. Espionsa, P.S. Pizani, J.A. Varela, E. Longo, Cryst. Growth Des. 9, 1002 (2009)

    Article  Google Scholar 

  38. S.K. Meher, G. Ranga Rao, J. Phys. Chem. C 115, 15646 (2011)

    Article  Google Scholar 

  39. B. Saravanakumar, S.P. Ramachandran, G. Ravi, V. Ganesh, A. Sakunthala, R. Yuvakkumar, Mater. Lett. 209, 1 (2017)

    Article  Google Scholar 

  40. Y. Huang, F. Cui, Y. Zhao, J. Lian, J. Bao, H. Li, J. Alloys Compd. 753, 176 (2018)

    Article  Google Scholar 

  41. P. Raja Jothi, K. Shanthi, R.R. Salunkhe, M. Pramanik, V. Malgras, S.M. Alshehri, Y. Yamauchi, Eur. J. Inorg. Chem. (2015). https://doi.org/10.1002/ejic.201500410

    Google Scholar 

  42. Q. Wang, X. Wang, B. Liu, G. Yu, X. Hou, D. Chen, G. Shen, J. Mater. Chem. A 1, 2468 (2013)

    Article  Google Scholar 

  43. H. Wan, J. Jiang, X. Ji, L. Miao, L. Zhang, K. Xu, H. Chen, Y. Ruan, Mater. Lett. 108, 164 (2013)

    Article  Google Scholar 

  44. L.Q. Mai, F. Yang, Y.L. Zhao, X. Xu, L. Xu, Y.Z. Luo, Nat. Commun. 2, 381 (2011)

    Article  Google Scholar 

  45. I. Kotutha, E. Swatsitang, W. Meewassana et al., Jpn. J. Appl. Phys. 54, 06FH10–06FH11 (2015)

    Article  Google Scholar 

  46. C. Yuan, J. Li, L. Hou, X. Zhang, L. Shen, X. Wen Lou, Adv. Funct. Mater. 22, 4592 (2012)

    Article  Google Scholar 

  47. Y.Q. Wu, X.Y. Chen, P.T. Ji, Q.Q. Zhou, Electrochim. Acta 56, 7517 (2011)

    Article  Google Scholar 

  48. T.H. Lee, K. Do, Y.W. Lee, S.S. Jeon, C. Kim, J. Ko, S.S. Im, J. Mater. Chem. 22, 21624 (2012)

    Article  Google Scholar 

  49. T. Zhai, L. Wan, S. Sun, Q. Chen, J. Sun, Q. Xia, H. Xia, Adv. Mater. 29(7), 1604167 (2017)

    Article  Google Scholar 

Download references

Acknowledgements

The author A.S and R.P are grateful to Kalasalingam Academy of Research and Education, Krishnankoil-626 126, India for providing financial support as the University Research Fellowship. Also, financial assistance from Council of Scientific and Industrial Research, India through the Minor Research Project (No. 03 (1276)/13/EMR-II) is gratefully acknowledged by V.S and S.A.

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Authors and Affiliations

  1. Department of Physics, International Research Centre (IRC), Kalasalingam Academy of Research and Education, Krishnankoil, Tamil Nadu, 626126, India

    A. Shameem, P. Devendran, V. Siva, R. Packiaraj, N. Nallamuthu & S. Asath Bahadur

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  1. A. Shameem
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  2. P. Devendran
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  3. V. Siva
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  4. R. Packiaraj
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  5. N. Nallamuthu
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  6. S. Asath Bahadur
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Correspondence to S. Asath Bahadur.

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Shameem, A., Devendran, P., Siva, V. et al. Electrochemical performance and optimization of α-NiMoO4 by different facile synthetic approach for supercapacitor application. J Mater Sci: Mater Electron 30, 3305–3315 (2019). https://doi.org/10.1007/s10854-018-00603-3

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