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Electrical properties of 0.94Bi0.5Na0.5TiO3–0.06Ba(Zr0.055Ti0.945)O3 lead-free ceramics with high thermal stability

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Abstract

Here we report the 0.94(Bi0.5Na0.5)TiO3–0.06Ba(Zr0.055Ti0.945)O3 (0.94BNT–0.06BZT) lead-free ceramics was synthesized by two-step solid state reaction route. The structural, dielectric, ferroelectric, piezoelectric and electromechanical properties of the ceramics were studied, and showed excellent electric properties (P s  = 39.9 μC/cm2, P r  = 33.7 μC/cm2, E c  = 2.79 kV/mm, S = 0.20%, d 33  = 174 pC/N, k p = 0.33). The depolarization temperature (T d ) of the ceramics is about 65 °C, which is determined from the first hump of relative dielectric constant. The electromechanical factor k p disappears at 65 °C, is consistent with the depolarization temperature (T d ) and the ferroelectric-antiferroelectric phase transition temperature (T fe−afe ) determined from the temperature-dependent P–E and bipolar S–E curves. These results indicate the 0.94BNT–0.06BZT ceramics has a good thermal stability in range of − 60–60 °C, and meets the actual demand.

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References

  1. G.H. Haertling, J. Am. Ceram. Soc. 82(4), 797–818 (1999)

    Article  Google Scholar 

  2. J. Rödel, W. Jo, K.T.P. Seifert, E.N. Anton, T. Granzow, J. Am. Ceram. Soc. 92(6), 1153–1177 (2009)

    Article  Google Scholar 

  3. T. Takenak, ,K. Maruyama, K. Sakata, Jpn. J. Appl. Phys. 30(9S), 2236 (1991)

    Article  Google Scholar 

  4. K. Sakata, T. Takenaka, Y. Naitou, Ferroelectrics 131(1), 219–226 (1992)

    Article  Google Scholar 

  5. A.B. Kounga, S.T. Zhang, W. Jo, T. Granzow, J. Rödel, Appl. Phys. Lett. 92(22), 222902 (2008)

    Article  Google Scholar 

  6. A. Sasaki, T. Chiba, Y. Mamiya, E. Otsuki, Jpn. J. Appl. Phys. 38(9S), 5564 (1999)

    Article  Google Scholar 

  7. S.T. Zhang, F. Yan, B. Yang, J. Appl. Phys. 107(11), 114110 (2010)

    Article  Google Scholar 

  8. H. Nagata, M. Yoshida, Y. Makiuchi, T. Takenaka, Jpn. J. Appl. Phys. 42(12R), 7401 (2003)

    Article  Google Scholar 

  9. X.X. Wang, X.G. Tang, H.L.W. Chan, Appl. Phys. Lett. 85(1), 91–93 (2004)

    Article  Google Scholar 

  10. G.F. Fan, W.Z. Lu, X.H. Wang, F. Liang, Appl. Phys. Lett. 91(20), 202908 (2007)

    Article  Google Scholar 

  11. S.T. Zhang, F. Yan, B. Yang, W.W. Cao, Appl. Phys. Lett. 97(12), 122901 (2010)

    Article  Google Scholar 

  12. C. Peng, J.F. Li, W. Gong, Mater. Lett. 59(12), 1576–1580 (2005)

    Article  Google Scholar 

  13. W.C. Lee, Y.F. Lee, M.H. Tseng, C.Y. Huang, Y.C. Wu, J. Am. Ceram. Soc. 92(5), 1069–1073 (2009)

    Article  Google Scholar 

  14. H.Y. Tian, K.W. Kwok, H.L.W. Chan, C.E. Buckley, J. Mater. Sci. 42(23), 9750–9755 (2007)

    Article  Google Scholar 

  15. P. Kantha, K. Pengpat, P. Jarupoom, U. Intatha, G. Rujijanagul, T. Tunkasiri, Curr. Appl. Phys. 9(2), 460–466 (2009)

    Article  Google Scholar 

  16. I. Franke, K. Roleder, L. Mitoseriu, R. Piticescu, Z. Ujma, Phys. Rev. B 73(14), 144114 (2006)

    Article  Google Scholar 

  17. T. Leist, J. Chen, W. Jo, E. Aulbach, J. Suffner, J. Rödel, J. Am. Ceram. Soc. 95(2), 711–715 (2012)

    Article  Google Scholar 

  18. L. Luo, W.W. Ge, J.F. Li, D. Viehland, C. Farley, R. Bodnar, Q.H. Zhang, H.S. Luo, J. Appl. Phys. 109(11), 113507 (2011)

    Article  Google Scholar 

  19. J. Suchanicz, I. Jankowska-Sumara, T.V. Kruzina, J. Electroceram. 27(2), 45 (2011)

    Article  Google Scholar 

  20. D. Rout, K.S. Moon, V.S. Rao, S.J.L. Kang, J.Ceram.Soc. Jpn. 117(1367), 797–800 (2009)

    Article  Google Scholar 

  21. J. Petzelt, S. Kamba, J. Fabry, D. Noujni, V. Porokhonskyy, A. Pashkin, I. Franke, K. Roleder, J. Suchanicz, R. Klein, G.E. Kugel, J. Phys. 16(15), 2719 (2004)

    Google Scholar 

  22. Y. Hiruma, H. Nagata, T. Takenaka, Jpn. J. Appl. Phys. 45(9S), 7409 (2006)

    Article  Google Scholar 

  23. S.T. Zhang, A.B. Kounga, E. Aulbach, T. Granzow, W. Jo, H.J. Kleebe, J. Rödel, J. Appl. Phys. 103(3), 034108 (2008)

    Article  Google Scholar 

  24. S.T. Zhang, A.B. Kounga, E. Aulbach, Y. Deng, J. Am. Ceram. Soc. 91(12), 3950–3954 (2008)

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Key Basic Research Program of China (No. 2013CB632900), the National Science Foundation of China (Nos. 51572055, 51572056, 51402075).

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Authors and Affiliations

  1. School of Science, Harbin University of Science and Technology, Harbin, 150080, China

    Jun-Jun Wang & Feng-Min Wu

  2. Condensed Matter Science and Technology Institute & Department of Physics, Harbin Institute of Technology, Harbin, 150080, China

    Jun-Jun Wang, Bin Yang, Li-Mei Zheng & Wen-Wu Cao

  3. National Engineering Research Center of Light Alloy Net Forming, Shanghai Jiao Tong University, Shanghai, 200240, China

    Fei-Fei Guo

  4. Department of Materials Science and Engineering & National Laboratory of Solid State Microstructures, Nanjing University, Nanjing, 210093, China

    Shan-Tao Zhang

  5. Materials Research Institute, The Pennsylvania State University, University Park, PA, 16802, USA

    Wen-Wu Cao

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  1. Jun-Jun Wang
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  3. Bin Yang
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Correspondence to Jun-Jun Wang or Fei-Fei Guo.

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Wang, JJ., Guo, FF., Yang, B. et al. Electrical properties of 0.94Bi0.5Na0.5TiO3–0.06Ba(Zr0.055Ti0.945)O3 lead-free ceramics with high thermal stability. J Mater Sci: Mater Electron 29, 2357–2362 (2018). https://doi.org/10.1007/s10854-017-8154-1

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