Skip to main content
Log in

Influence of Co++ ion concentration on magnetic and microwave properties of Ba(4−X)Co(2+X)Fe36O60 (Ba-M-Y) hexaferrite

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

The present paper reports the influence of cobalt content on the structural, electrical, magnetic and microwave properties of barium hexaferrite synthesized via chemical co-precipitation method. The samples were characterized for their structural, electrical, magnetic and microwave characterizations using XRD, SEM, TEM, VSM etc. The transmission electron microscopy results showed that stacking of nanoparticles of size ~ 50 nm. In addition, the highest saturation magnetization of 29.82 emu/g was observed for composition x = 0.2. The microwave permittivity and permeability decreases with frequency and it varies with the cobalt concentration. Cobalt concentration strongly affects the microwave and magnetic properties of hexaferrite.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. K.S. Martirosyan, E. Galstyan, S.M. Hossain, Y.-J. Wang, D. Litvinov, Barium hexaferrite nanoparticles: synthesis and magnetic properties. Mater. Sci. Eng. B 176, 8–13 (2011). doi:10.1016/j.mseb.2010.08.005

    Article  Google Scholar 

  2. R.C. Pullar, Hexagonal ferrites: a review of the synthesis, properties and applications of hexaferrite ceramics. Prog. Mater. Sci. 57, 1191–1334 (2012). doi:10.1016/j.pmatsci.2012.04.001

    Article  Google Scholar 

  3. M.M. Rashad, I.A. Ibarhim, Synthesis and magnetic properties of barium hexaferrite powders using organic acid precursor method. J. Supercond. Nov. Magn. 26, 1639–1644 (2013). doi:10.1007/s10948-012-1871-z

    Article  Google Scholar 

  4. S.Z. Zhaohui, PhD. Thesis, National University, Formation and properties of ferrite-based nanoparticles and nanocomposites, National University, Singapore (2004)

  5. M. Radwan, M.M. Rashad, M.M. Hessien, Synthesis and characterization of barium hexaferrite nanoparticles. J. Mater. Process. Technol. 181, 106–109 (2007). doi:10.1016/j.jmatprotec.2006.03.015

    Article  Google Scholar 

  6. P. Chauhan, Preparation and Characterization of Barium Hexaferrite by Barium Monoferrite. (Thapar University, Patiala, 2010)

    Google Scholar 

  7. N.B. Velhal, N.D. Patil, A.R. Shelke, N.G. Deshpande, V.R. Puri, Structural, dielectric and magnetic properties of nickel substituted cobalt ferrite nanoparticles: effect of nickel concentration. AIP Adv. 5, 97166 (2015). doi:10.1063/1.4931908

    Article  Google Scholar 

  8. S.B. Ogale, R.J. Choudhary, J.P. Buban, S.E. Lofland, S.R. Shinde, S.N. Kale, V.N. Kulkarni, J. Higgins, C. Lanci, J.R. Simpson, N.D. Browning, S. Das Sarma, H.D. Drew, R.L. Greene, T. Venkatesan, High temperature ferromagnetism with a giant magnetic moment in transparent Co-doped SnO2–δ. Phys. Rev. Lett. 91, 77205 (2003). doi:10.1103/PhysRevLett.91.077205

    Article  Google Scholar 

  9. C.M. Liu, X.T. Zu, W.L. Zhou, Magnetic interaction in Co-doped SnO2 nano-crystal powders. J. Phys. Condens. Matter. 18, 6001–6007 (2006). doi:10.1088/0953-8984/18/26/018

    Article  Google Scholar 

  10. M. Ahmad, I. Ali, F. Aen, M.U. Islam, M.N. Ashiq, S. Atiq, W. Ahmad, M.U. Rana, Effect of sintering temperature on magnetic and electrical properties of nano-sized Co2W hexaferrites, Ceram. Int. 38, 1267–1273 (2012). doi:10.1016/j.ceramint.2011.08.059

    Article  Google Scholar 

  11. M.J. Iqbal, S. Farooq, Enhancement of electrical resistivity of Sr0.5Ba0.5Fe12O19 nanomaterials by doping with lanthanum and nickel. Mater. Chem. Phys. 118, 308–313 (2009). doi:10.1016/j.matchemphys.2009.07.056

    Article  Google Scholar 

  12. H.-F. Yu, H.-Y. Lin, Preparation and thermal behavior of aerosol-derived BaFe12O19 nanoparticles. J. Magn. Magn. Mater. 283, 190–198 (2004). doi:10.1016/j.jmmm.2004.05.020

    Article  Google Scholar 

  13. S. Ruan, B. Xu, H. Suo, F. Wu, S. Xiang, M. Zhao, Microwave absorptive behavior of ZnCo-substituted W-type Ba hexaferrite nanocrystalline composite material. J. Magn. Magn. Mater. 212, 175–177 (2000). doi:10.1016/S0304-8853(99)00755-6

    Article  Google Scholar 

  14. P.A. Chernavskii, G.V. Pankina, A.S. Lermontov, V.V. Lunin, Size distribution of cobalt particles in catalysts for the Fischer–Tropsch synthesis. Kinet. Catal. 44, 657–661 (2003). doi:10.1023/A:1026146123264

    Article  Google Scholar 

  15. K. Park, D.Y. Bang, Electrical properties of Ni ± Mn ± Co ± (Fe) oxide thick-film NTC thermistors prepared by screen printing. Most 4, 81–87 (2003). doi:10.1023/A:1021900618988

    Google Scholar 

  16. A.M. Bhavikatti, Characterization and electromagnetic studies of nano-sized barium ferrite. Int. J. Eng. Sci. Technol. 2, 6532–6539 (2010)

    Google Scholar 

  17. T. Sakon, Y. Adachi, T. Kanomata, Magneto-structural properties of Ni2MnGa ferromagnetic shape memory alloy in magnetic fields. Metals (Basel) 3, 202–224 (2013) doi:10.3390/met3020202

    Article  Google Scholar 

  18. J. Ye, W. He, Q. Wu, H.-L. Liu, X.-Q. Zhang, Z.-Y. Chen, Z.-H. Cheng, Determination of magnetic anisotropy constants in Fe ultrathin film on vicinal Si(111) by anisotropic magnetoresistance. Sci. Rep. 3, 2148 (2013). doi:10.1038/srep02148

    Article  Google Scholar 

  19. M. Han, Y. Ou, W. Chen, L. Deng, Magnetic properties of Ba-M-type hexagonal ferrites prepared by the sol–gel method with and without polyethylene glycol added. J. Alloys Compd. 474, 185–189 (2009). doi:10.1016/j.jallcom.2008.06.047

    Article  Google Scholar 

  20. P.M. Shepherd, R.J. Kajal, K. Green, Magnetic and structural properties of M-type barium hexaferrite prepared by co-precipitation. J. Magn. Magn. Mater. 311, 683–692 (2007). doi:10.1016/j.jmmm.2006.08.046

    Article  Google Scholar 

  21. K.K. Mallick, P. Shepherd, R.J. Green, Magnetic properties of cobalt substituted M-type barium hexaferrite prepared by co-precipitation. J. Magn. Magn. Mater. 312, 418–429 (2007). doi:10.1016/j.jmmm.2006.11.130

    Article  Google Scholar 

  22. Y. Bai, F. Xu, L. Qiao, J. Zhou, Effect of Mn doping on physical properties of Y-type hexagonal ferrite. J. Alloys Compd. 473, 505–508 (2009). doi:10.1016/j.jallcom.2008.06.011

    Article  Google Scholar 

  23. N. Velhal, G. Kulkarni, D. Mahadik, P. Chowdhury, H. Barshilia, V. Puri, Effect of Ba2+ ion on structural, magnetic and microwave properties of screen printed BaxSr1–XFe12O19 thick films. J. Alloys Compd. 682, 730–737 (2016). doi:10.1016/j.jallcom.2016.04.310

    Article  Google Scholar 

  24. D.C. Kulkarni, V. Puri, Broad band absorbance of barium hexaferrite thick films in the 8–12 GHz frequency spectrum. Electron. Mater. Lett. 7, 51–57 (2011). doi:10.1007/s13391-011-0308-3

    Article  Google Scholar 

  25. N. Patil, Electric, magnetic and high frequency properties of screen printed ferrite–ferroelectric composite thick films on alumina substrate. Microelectron. Int. 1, 25–31 (2015) doi:10.1108/MI-12-2013-0080.

    Article  Google Scholar 

  26. N.D. Patil, N.B. Velhal, N.L. Tarwar, V.R. Puri, Dielectric and magnetic properties of Co substituted Ni-CD-ferrite prepared by solution combustion Method 3, 73–77 (2014)

    Google Scholar 

  27. D.C. Kulkarni, V. Puri, Ku band microwave studies of fritless strontium hexaferrite thick films. Microelectron. Int. 27, 143–147 (2010). doi:10.1108/13565361011061948

    Article  Google Scholar 

Download references

Acknowledgements

The study was supported by Science and Engineering Research Board (Grant No. SERB/F/2139/2016-17). Dr. Vijaya Puri is grateful to UGC for the award of UGC Research scientist ‘C’. P. B. Kashid acknowledges to UGC for Meritorious fellowship. Ninad Velhal acknowledges to DAE-BRNS for providing the JRF under the project 2012/BRNS/34/36/1034. Also authors thank to DST-FIST, Physics instrumentation facility center (PIFC) Department of Physics, SUK.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Vijaya Puri.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kashid, P.B., Velhal, N., Kulkarni, G. et al. Influence of Co++ ion concentration on magnetic and microwave properties of Ba(4−X)Co(2+X)Fe36O60 (Ba-M-Y) hexaferrite. J Mater Sci: Mater Electron 29, 1748–1758 (2018). https://doi.org/10.1007/s10854-017-8083-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-017-8083-z

Navigation