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High temperature dielectric anomaly and impedance analysis of (Pb1−3x/2La x )(Zr0.95Ti0.05)O3 ceramics

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Abstract

(Pb1−3x/2La x )(Zr0.95Ti0.05)O3 (x = 0.02, 0.04, 0.06, 0.08, 0.10) ceramics were successfully synthesized by a solid state mixed oxide technique. Structural information was investigated by X-ray diffraction method. Dielectric permittivity versus temperature demonstrated the phase transition temperature (AFE-FE and FE-PE) reduced with substituting of Pb2+ by La3+. The impedance analysis of (Pb1−3x/2La x )(Zr0.95Ti0.05)O3 ceramics were found to obey an Arrhenius law with activation energy of 0.43–1.61 eV, and the conduction was a thermally activated process with activation energy 0.38–1.66 eV, respectively. Based on these results, the activation energy for anomaly and conduction was calculated, which suggested the oxygen vacancy play a critical role in the dielectric anomaly process of (Pb1−3x/2La x )(Zr0.95Ti0.05)O3 ceramics at high temperatures.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant Nos. 11574057 and 51604087), the Guangdong Provincial Natural Science Foundation of China (Grant No. 2016A030313718), the Science and Technology Program of Guangdong Province of China (Grant No. 2016A010104018) and the Youth Foundation of Guangdong University of Technology (Grant No. 14QNZA004).

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Authors and Affiliations

  1. School of Physics & Optoelectric Engineering, Guangzhou Higher Education Mega Centre, Guangdong University of Technology, Guangzhou, 510006, People’s Republic of China

    Bi Li, Qiu-Xiang Liu, Xin-Gui Tang, Tian-Fu Zhang, Yan-Ping Jiang, Wen-Hua Li & Jie Luo

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  1. Bi Li
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  2. Qiu-Xiang Liu
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  3. Xin-Gui Tang
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Correspondence to Xin-Gui Tang.

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Li, B., Liu, QX., Tang, XG. et al. High temperature dielectric anomaly and impedance analysis of (Pb1−3x/2La x )(Zr0.95Ti0.05)O3 ceramics. J Mater Sci: Mater Electron 28, 14864–14873 (2017). https://doi.org/10.1007/s10854-017-7358-8

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  • DOI: https://doi.org/10.1007/s10854-017-7358-8

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