Skip to main content
Log in

Effects of pore sizes on the electrical properties for porous 0.36BS–0.64PT ceramics

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Porous BiScO3–0.64PbTiO3 (0.36BS–0.64PT) ceramics were fabricated by using burnable plastic sphere technique. Self-synthesized polystyrene microsphere (PS, φ0.36 μm) and poly methyl methacrylate (PMMA, φ2, 10 and 18 μm) micro-balls were selected as PFA. The porosity, microstructure and electrical properties were investigated for porous 0.36BS–0.64PT ceramics fabricated with different particle sizes of pore forming agents (PFA). With increasing particle sizes of PFA, the pore size and porosity increased. Meanwhile relative permittivity (ε r), piezoelectric coefficient (d 33, −d 31) and electromechanical coupling coefficients (k p, k t) decreased. The mechanical quality factor (Q m), elastic coefficient (s 11), hydrostatic voltage coefficient (g h) and hydrostatic figure of merit increased accordingly. Finally, the effects of particle sizes of PFA on the microstructure and electrical properties were discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. E. Mercadelli, A. Sanson, C. Galassi, in Porous Piezoelectric Ceramics, ed. by E. Suaste-Gomez (INTECH, Rijeka, 2010) pp. 111–128

    Google Scholar 

  2. C. Paolo, Engineering porosity in polymer-derived ceramics. J. Eur. Ceram. Soc. 28, 1389–1395 (2008)

    Article  Google Scholar 

  3. C.R. Bowen, A. Perry, A.C.F. Lewis, H. Kara, Processing and properties of porous piezoelectric materials with high hydrostatic figures of merit. J. Eur. Ceram. Soc. 24, 541–545 (2004)

    Article  Google Scholar 

  4. H.L. Zhang, J.F. Li, B.P. Zhang, Microstructure and electrical properties of porous PZT ceramics derived from different pore-forming agents. Acta Mater. 55, 171–181 (2007)

    Article  Google Scholar 

  5. A.K. Yang, C.A. Wang, R. Guo, Y. Huang, Microstructure and electrical properties of porous PZT ceramics fabricated by different methods. J. Am. Ceram. Soc. 93, 1984–1990 (2010)

    Google Scholar 

  6. T. Zeng, X.L. Dong, S. T. Chen, and H. Yang, Processing and piezoelectric properties of porous PZT ceramics. Ceram. Int. 33, 395–399 (2007)

    Article  Google Scholar 

  7. B.P. Kumar, H.H. Kumar, D.K. Kharat, Effect of porosity on dielectric properties and microstructure of porous PZT ceramics. Mater. Sci. Eng. B 127, 130–133 (2006)

    Article  Google Scholar 

  8. T. Zeng, X.L. Dong, H. Chen, Y.L. Wang, The effects of sintering behavior on piezoelectric properties of porous PZT ceramics for hydrophone application. Mater. Sci. Eng. B 131, 181–185 (2006)

    Article  Google Scholar 

  9. S.H. Lee, S.H. Jun, H.E. Kim, Piezoelectric properties of PZT-based ceramic with highly aligned pores. J. Am. Ceram. Soc. 91, 1912–1915 (2008)

    Article  Google Scholar 

  10. A.K. Yang, C.A. Wang, R. Guo, Y. Huang, C.W. Nan, Effects of porosity on dielectric and piezoelectric properties of porous lead zirconate titanate ceramics. Appl. Phys. Lett. 98, 152904 (2011)

    Article  Google Scholar 

  11. S.B. Lang, E, Ringgaard, Measurements of the thermal, dielectric, piezoelectric, pyroelectric and elastic properties of porous PZT samples. Appl. Phys. A 107, 631–638 (2012)

    Article  Google Scholar 

  12. I. Chilibon, J.N. Marat-Mendes, Ferroelectric ceramics by sol–gel methods and applications: a review. J Sol-Gel. Sci. Technol. 64, 571–611 (2012)

    Article  Google Scholar 

  13. S. Iyer, T.A. Venkatesh, Electromechanical response of porous piezoelectric materials: effects of porosity connectivity. Appl. Phys. Lett. 97, 072904 (2010)

    Article  Google Scholar 

  14. B.P. kumar, H.H. Kumar, D.K. kharat, Study on microstructure, piezoelectric and dielectric properties of 3–3 porous PZT composites. J. Mater. Sci. 17, 515–518 (2006)

    Google Scholar 

  15. T. Zeng, X.L. Dong, C.L. Mao, Z.Y. Zhou, H. Yang, Effects of pore shape and porosity on the properties of porous PZT 95/5 ceramics. J. Euro. Ceram. Soc. 27, 2025–2029 (2007)

    Article  Google Scholar 

  16. R. Guo, C.A. Wang, A.k.. Yang, Piezoelectric properties of the 1–3 type porous lead zirconate titanate ceramics. J. Am. Ceram. Soc. 94, 1794–1799 (2011)

    Article  Google Scholar 

  17. B.P. Kumar, H.H. Kumar, D.K. Kharat, Study on pore-forming agents in processing of porous piezoceramics. J. Mater. Sci. 16, 681–686 (2005)

    Google Scholar 

  18. R.E. Eitel, S.J. Zhang, T.R. Shrout, C.A. Randall, Phase diagram of the perovskite system (1−x) BiScO3−xPbTiO3. J. Appl. Phys. 96, 2828–2831 (2004)

    Article  Google Scholar 

  19. J.T. Tan, Z.R. Li, Microstructures, dielectric and piezoelectric properties of unannealed and annealed porous 0.36BiScO3–0.64PbTiO3 ceramics. J. Mater. Sci. 51, 5092–5103 (2016)

    Article  Google Scholar 

  20. J.T. Tan, Z.R. Li, Fabrication and electrical properties of porous BS–0.64PT high temperature piezoceramics using polystyrene microsphere. Ceram. Int. 41, S414–S420 (2015)

    Article  Google Scholar 

  21. A.K. Yang, C.A. Wang, R. Guo, Y. Huang, C.W. Nan, Effects of sintering behavior on microstructure and piezoelectric. Ceram. Int. 36, 549–554 (2010)

    Article  Google Scholar 

  22. A.N. Rybyanets, Porous piezoceramics: theory, technology, and properties. IEEE Trans. Ultrason. Ferroelectr. Freq. Control 58, 1492–1507 (2011)

    Article  Google Scholar 

  23. Y. Huan, X.H. Wang, J. Fang, L.T. Li, Grain size effect on piezoelectric and ferroelectric properties of BaTiO3 ceramics. J. Eur. Ceram. Soc. 34, 1445–1448 (2014)

    Article  Google Scholar 

Download references

Acknowledgements

The SEM work was done at International Center for Dielectric Research (ICDR), Xi’an Jiaotong University, Xi’an, China. This work was financially supported by the 111 project (B14040), International Science & Technology Cooperation Program of China (Grant Nos. 2014DFR51240 and 2013DFR50470) and Science and technology research and development program of Shaanxi province (Grant No. 2014KW08-01).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zhenrong Li.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tan, J., Li, Z. Effects of pore sizes on the electrical properties for porous 0.36BS–0.64PT ceramics. J Mater Sci: Mater Electron 28, 9309–9315 (2017). https://doi.org/10.1007/s10854-017-6668-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-017-6668-1

Keywords

Navigation