Abstract
In this study, tungsten-doped zinc oxide (WZO) thin films were deposited on quartz glass substrates with varied modulation powers using a radio frequency (RF) magnetron sputtering technique. The crystallinity, along with the microstructural, optical and electrical properties of the WZO and zinc oxide thin films were further investigated and compared. When the modulation power was increased from 100 to 250 W, the crystallinity of WZO thin films improved and the surface crystallite size increased. An optimized WZO thin film obtained at a modulation power of 250 W exhibited a highest carrier concentration of 5.39 × 1019 cm−3 and a highest hall mobility of 17.3 cm2 V− 1 s−1. Furthermore, it also displayed a lowest resistivity of 6.69 × 10−3 Ω cm and an average transmittance of 81.25% in the wavelength range of 400–2500 nm. Lastly, an increase in carrier concentration resulted in a decrease in infrared transmittance.
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References
M.D. McCluskey, C.D. Corolewski, J. Lv et al., Acceptors in ZnO. J. Appl. Phys 117, 112802 (2015)
Y. Hu, Y. Chen, X. Zhang et al., effects of substrate temperature on the doping characteristics of Li-W CO-doped ZnO films. Surf. Rev. Lett 21, 1450003 (2014)
M.D. McCluskey, S.J. Jokela, Defects in ZnO. J. Appl. Phys 106, 071101 (2009)
S. Calnan, A.N. Tiwari, High mobility transparent conducting oxides for thin film solar cells. Thin Solid Films 518, 1839 (2010)
P.F. Newhouse, C.H. Park, D.A. Keszler et al., High electron mobility W-doped In2O3 thin films by pulsed laser deposition. Appl. Phys. Lett. 87, 112108 (2005)
Y.C. Lin, B.L. Wang, W.T. Yen et al., Effect of process conditions on the optoelectronic characteristics of ZnO:Mo thin films prepared by pulsed direct current magnetron sputtering. Thin Solid Films 518, 4928 (2010)
B.D. Ngom, T. Mpahane, N. Manyala et al., Structural and optical properties of nano-structured tungsten-doped ZnO thin films grown by pulsed laser deposition. Appl. Surf. Sci 255, 4153 (2009)
B.D. Ngom, O. Sakho, N. Manyala et al., Structural, morphological and photoluminescence properties of W-doped ZnO nanostructures. Appl. Surf. Sci 255, 7314 (2009)
F.H. Wang, H.P. Chang, J.C. Chao, Improved properties of Ti-doped ZnO thin films by hydrogen plasma treatment. Thin Solid Films 519, 5178 (2011)
P. Shpak, A. M. Korduban, M. M. Medvedskij, et al. XPS studies of active elements surface of gas sensors based on WO3–x nanoparticles. J. Electron. Spectrosc. Relat. Phenom., 156–158, 172 (2007).
R. Sivakumar, R. Gopalakrishnan, M. Jayachandran et al., Investigation of X-ray photoelectron spectroscopic (XPS), cyclic voltammetric analyses of WO3 films and their electrochromic response in FTO/WO3/electrolyte/FTO cells. Smart. Mater. Struct 15, 877 (2006)
M.C. Patterson, X. Nie, F. Wang et al., Growth and Structure of Cu and Au on the Nonpolar ZnO(1010) Surface: STM, XPS, and DFT Studies. J. Phys. Chem. C 117, 18386 (2013)
T.G.G. Maffeis, M.W. Penny, A. Castaing et al., XPS investigation of vacuum annealed vertically aligned ultralong ZnO nanowires. Surf. Sci 606, 99 (2012)
J.S.O. Evans, Z. Hu, J.D. Jorgensen et al., Compressibility, Phase Transitions, and Oxygen Migration in Zirconium Tungstate, ZrW2O8. Science 275, 5 (1997)
J. Tao, M.L. Tong, J.X. Shi et al., Blue photoluminescent zinc coordination polymers with supertetranuclear cores. Chem. Commun 20, 2043 (2000)
L. Zhang, Y. Zhou, L. Guo et al., Correlated metals as transparent conductors. Nat Mater 15, 204 (2016)
C. Zhang, X. Chen, X.-H. Geng et al., Temperature-dependent growth and properties of W-doped ZnO thin films deposited by reactive magnetron sputtering. Appl. Surf. Sci 274, 371 (2013)
Acknowledgements
This work was financially supported by the following funds: (1) The Natural Science Foundation of China (No. 61464005 and 51562015); (2) Young scientist of Jiangxi Province (Grant No. 20153BCB23004); (3) The Natural Science Foundation of Jiangxi Province (No. 20143ACB21004, 20151BAB202010 and 20151BAB212008); (4) The Jiangxi Province Foreign Cooperation Projects, China (No. 20151BDH80031); (5) The Leader Training Object Project of Major Disciplines Academic and Technical of Jiangxi Province (No. 20123BCB22002); (6) The Colleges and Universities Landing Plan of Jiangxi Province (No. KJLD12085 and KJLD14075); (7) The Science Foundation of Jingdezhen (No. 2013-1-4, 2014-2-22 and 2014-1-3).
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Chen, Y., Hu, Y., Zhang, X. et al. Investigation of the properties of W-doped ZnO thin films with modulation power deposition by RF magnetron sputtering. J Mater Sci: Mater Electron 28, 5498–5503 (2017). https://doi.org/10.1007/s10854-016-6211-9
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DOI: https://doi.org/10.1007/s10854-016-6211-9