Skip to main content
Log in

Effects of silver nanowire concentration and annealing temperature on the optoelectronic properties of hybrid transparent electrodes

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

In this study, Ag nanowire (AgNW) was used to fabricate ITO/AgNW/ITO (IAI) and ZnO/AgNW/ZnO (ZAZ) hybrid transparent electrodes. The covered area ratio of AgNW showed that when AgNW concentration n AgNW ≥ 2.0 mg/mL, AgNW easily agglomerated during the spin-coating. Meanwhile, Haacke index and haziness measurements also indicated that for application with high optical demands, the AgNW concentration should be ≤2.0 mg/mL for both ZnO or ITO systems. In this study, when n AgNW = 2.0 mg/mL, the sheet resistant of ZAZ electrodes was 10.5 Ω/sq while the transmittance (including glass) was 72.7% in the visible region. For IAI electrodes, the sheet resistant was 18.8 Ω/sq and transmittance (including glass) was 78.2% in the visible region. Further analysis implied that the sheet resistance of hybrid electrodes could be as low as 10 Ω/sq by optimizing AgNW distribution as well as using suitable annealing techniques.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. J.D. Perkins, T. Gennett, M. Galante, D. Gillaspie, D. Ginley, in Amorphous indium-zinc-oxide transparent conductors for thin film PV. Proceedings of the 37th IEEE Photovoltaic Specialists Conference, June 19–24, Seattle, USA (2011), pp. 3646–3648

  2. J. Hautcoeur, X. Castel, F. Colombel, R. Benzerga, M. Himdi, G. Legeay, E. Motta-Cruz, Transparency and electrical properties of meshed metal films. Thin Solid Films 519, 3851–3858 (2011)

    Article  Google Scholar 

  3. J.Y. Lee, S.T. Connor, Y. Cui, P. Peumans, Solution-processed metal nanowire mesh transparent electrodes. Nano Lett. 8–2, 689–692 (2008)

    Article  Google Scholar 

  4. X. Wang, L. Zhi, K. Müllen, Transparent, Conductive graphene electrodes for dye-sensitized solar cells. Nano Lett. 8–1, 323–327 (2008)

    Article  Google Scholar 

  5. A. Kasry, M. El Ashry, R.A. Nistor, G.S. Bol, G.J. Tulevski, D.M. Martyna, Newns, High performance metal microstructure for carbon-based transparent conducting electrodes. Thin Solid Films 520, 4827–4830 (2012)

    Article  Google Scholar 

  6. S. Kirchmeyer, K. Reuter, Scientific importance, properties and growing applications of poly(3,4-ethylenedioxythiophene). J. Mater. Chem. 15, 2077–2088 (2005)

    Article  Google Scholar 

  7. C.H. Song, K.H. Ok, C.J. Lee, Y. Kim, M.G. Kwak, C.J. Han, N. Kim, B.K. Ju, J.W. Kim, Intense-pulsed-light irradiation of Ag nanowire-based transparent electrodes for use in flexible organic light emitting diodes. Org. Electron. 17, 208–215 (2015)

    Article  Google Scholar 

  8. J. Jiu, M. Nogi, T. Sugahara, T. Tokuno, T. Araki, N. Komoda, K. Suganuma, H. Uchida, K. Shinozaki, Strongly adhesive and flexible transparent silver nanowire conductive films fabricated with a high-intensity pulsed light technique. J. Mater. Chem. 22, 23561–23567 (2012)

    Article  Google Scholar 

  9. Y.H. Duan, Y. Duan, X. Wang, D. Yang, Y.Q. Yang, P. Chen, F.B. Sun, K.W. Xue, Y. Zhao, Highly flexible peeled-off silver nanowire transparent anode using in organic light-emitting devices. Appl. Surf. Sci. 351, 445–450 (2015)

    Article  Google Scholar 

  10. X.Y. Zeng, Q.K. Zhang, C.Z. Lu, R.M. Yu, A new transparent conductor: silver nanowire film buried at the surface of a transparent polymer. Adv. Mater. 22, 4484–4488 (2010)

    Article  Google Scholar 

  11. K.H. Choi, J. Kim, Y.J. Noh, S.I. Na, H.K. Kim, Ag nanowire-embedded ITO films as a near-infrared transparent and flexible anode for flexible organic solar cells. Sol. Energ. Mat. Sol. C 110, 147–153 (2013)

    Article  Google Scholar 

  12. Y. Kim, K. Won, C.-H. Woo, J. Moon Kim, Highly transparent low resistance ZnO/Ag nanowire/ZnO composite electrode for thin film solar cells. ACS Nano 7, 1081–1091 (2013)

    Article  Google Scholar 

  13. A.R. Madaria, A. Kumar, F.N. Ishikawa, C. Zhou, Uniform, highly conductive, and patterned transparent films of a percolating silver nanowire network on rigid and flexible substrates using a dry transfer technique. Nano Res. 3, 564–573 (2010)

    Article  Google Scholar 

  14. A.T. Bellew, H.G. Manning, C. Gomes da Rocha, M.S. Ferreira, J.J. Boland, Resistance of single Ag nanowire junctions and their role in the conductivity of nanowire networks. ACS Nano 9, 11422–11429 (2015)

    Article  Google Scholar 

  15. T.-B. Song, Y. Chen, C.-H. Chung, Y. Yang, B. Bob, H.-S. Duan, G. Li, K.-N. Tu, Y. Huang, Y. Yang, Nanoscale joule heating and electromigration enhanced ripening of silver nanowire contacts. ACS Nano 8, 2804–2811 (2014)

    Article  Google Scholar 

  16. E.C. Garnett, W. Cai, J.J. Cha, F. Mahmood, S.T. Connor, M.G. Christoforo, Y. Cui, M.D. McGehee, M.L. Brongersma, Self-limited plasmonic welding of silver nanowire junctions. Nat. Mater. 11, 241–249 (2012)

    Article  Google Scholar 

  17. L. Benguigui, Experimental study of the elastic properties of a percolating system. Phys. Rev. Lett. 53, 2028–2030 (1984)

    Article  Google Scholar 

  18. T.W.H. Oates, D.R. McKenzie, M.M.M. Bilek, Percolation threshold in ultrathin titanium films determined by in situ spectroscopic ellipsometry. Phys. Rev. B 70, 195406 (2004)

    Article  Google Scholar 

  19. G.E. Pike, C.H. Seager, Percolation and conductivity: a computer study. I. Phys. Rev. B 10, 1421 (1974)

    Article  Google Scholar 

  20. S. Sorel, P.E. Lyons, S. De, J.C. Dickerson, J.N. Coleman, The dependence of the optoelectrical properties of silver nanowire networks on nanowire length and diameter. Nanotechnology 23, 185201 (2012)

    Article  Google Scholar 

  21. G. Haacke, Transparent conducting coatings. Ann. Rev. Mater. Sci. 7, 73–93 (1977)

    Article  Google Scholar 

  22. W. Gaynor, G.F. Burkhard, M.D. Mcgehee, P. Peumans, Smooth nanowire/polymer composite transparent electrodes. Adv. Mater. 23, 2905 (2011)

    Article  Google Scholar 

  23. Y. Hu, X. Diao, C. Wang, W. Hao, T. Wang, Effects of heat treatment on properties of ITO films prepared by rf magnetron sputtering. Vacuum 75, 183–188 (2004)

    Article  Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge the financial support provided by the Ministry of Science and Technology of Republic of China under contact number MOST 105-2221-E-218-033.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Keh-Moh Lin.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lin, KM., Lin, RL., Hsiao, WT. et al. Effects of silver nanowire concentration and annealing temperature on the optoelectronic properties of hybrid transparent electrodes. J Mater Sci: Mater Electron 28, 5144–5153 (2017). https://doi.org/10.1007/s10854-016-6170-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-016-6170-1

Keywords

Navigation