Skip to main content
Log in

Facile synthesis of α-Fe2O3/diatomite composite for visible light assisted degradation of Rhodamine 6G in aqueous solution

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

α-Fe2O3 particle supported on diatomite (α-Fe2O3/diatomite composite) was prepared at room temperature by the chemical precipitation method using ferrous sulphate as the raw material and diatomite as supporter. α-Fe2O3/diatomite composite was characterized by XRD, FE-SEM, FT-IR and DRS. The result showed that α-Fe2O3 was uniformly loaded on the diatomite. The photocatalytic activity was investigated under visible light toward degradation of Rhodamine 6G aqueous solution and the effects of various experimental factors on Rhodamine 6G degradation were investigated. Compared with the α-Fe2O3, α-Fe2O3/diatomite composite had significantly enhanced activity in the degradation of Rhodamine 6G under visible light irradiation. Besides, the photostability of catalysts was also investigated. The experimental results indicated that the prepared composite is a promising material for the wastewater treatment for its good catalytic performance property and long-term stability.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. A.N. Soon, B.H. Hameed, Heterogeneous catalytic treatment of synthetic dyes in aqueous media using Fenton and photo-assisted Fenton process. Desalination 269, 1 (2011)

    Article  Google Scholar 

  2. B. Wang, G. Zhang, X. Leng, Z. Sun, S. Zheng, Characterization and improved solar light activity of vanadium doped TiO2/diatomite hybrid catalysts. J. Hazard. Mater. 285, 212 (2015)

    Article  Google Scholar 

  3. C.G. Silva, W. Wang, J.L. Faria, Photocatalytic and photochemical degradation of mono-, di- and tri-azo dyes in aqueous solution under UV irradiation. J. Photochem. Photobiol. A 181, 314 (2006)

    Article  Google Scholar 

  4. J. Farias, G.H. Rossetti, E.D. Albizzati, O.M. Alfano, Solar Degradation of Formic Acid: temperature Effects on the Photo-Fenton Reaction. Ind. Eng. Chem. Res. 46, 7580 (2007)

    Article  Google Scholar 

  5. I. Fatimah, S. Wang, D. Wulandari, ZnO/montmorillonite for photocatalytic and photochemical degradation of methylene blue. Appl. Clay Sci. 53, 553 (2011)

    Article  Google Scholar 

  6. H. Kusic, N. Koprivanac, L. Srsan, Azo dye degradation using Fenton type processes assisted by UV irradiation: a kinetic study. J. Photochem. Photobiol. A 181, 195 (2006)

    Article  Google Scholar 

  7. Y. Ling, G. Wang, D.A. Wheeler, J.Z. Zhang, Y. Li, Sn-doped hematite nanostructures for photoelectrochemical water splitting. Nano Lett. 11, 2119 (2011)

    Article  Google Scholar 

  8. F. Meng, J. Li, S.K. Cushing, J. Bright, M. Zhi, J.D. Rowley, Z. Hong, A. Manivannan, A.D. Bristow, N. Wu, Photocatalytic water oxidation by hematite/reduced graphene oxide composites. ACS Catal. 3, 746 (2013)

    Article  Google Scholar 

  9. W. Zhou, W. He, J. Ma, M. Wang, X. Zhang, S. Yan, X. Tian, X. Sun, X. Han, Biosynthesis of mesoporous organic–inorganic hybrid Fe2O3 with high photocatalytic activity. Mat. Sci. Eng. C 29, 1893 (2009)

    Article  Google Scholar 

  10. G. Zhang, Y. Gao, Y. Zhang, Y. Guo, Fe2O3-pillared rectorite as an efficient and stable Fenton-like heterogeneous catalyst for photodegradation of organic contaminants. Environ. Sci. Technol. 44, 6384 (2010)

    Article  Google Scholar 

  11. S. Guo, G. Zhang, Y. Guo, J.C. Yu, Graphene oxide-Fe2O3 hybrid material as highly efficient heterogeneous catalyst for degradation of organic contaminants. Carbon 60, 437 (2013)

    Article  Google Scholar 

  12. B. Wang, F.C. de Godoi, Z. Sun, Q. Zeng, S. Zheng, R.L. Frost, Synthesis, characterization and activity of an immobilized photocatalyst: natural porous diatomite supported titania nanoparticles. J. Colloid Interface Sci. 438, 204 (2015)

    Article  Google Scholar 

  13. C.J. Yue, S.S. Yao, L.P. Gu, Diatomite-entrapped hydrosulfate catalysts for the efficient nitration of toluene with nitric acid. J. Porous Mater. 22, 455 (2015)

    Article  Google Scholar 

  14. X. Wen, S. Wang, Y. Ding, Z.L. Wang, S. Yang, Controlled growth of large-area, uniform, vertically aligned arrays of α-Fe2O3 nanobelts and nanowires. J. Phys. Chem. B 109, 215 (2005)

    Article  Google Scholar 

  15. W. Wu, R. Hao, F. Liu, X. Su, Y. Hou, Single-crystalline α-Fe2O3 nanostructures: controlled synthesis and high-index plane-enhanced photodegradation by visible light. J. Mater. Chem. A. 1, 6888 (2013)

    Article  Google Scholar 

  16. M.A.M. Khraisheh, M.A. Al-Ghouti, S.J. Allen, M.N. Ahmad, Effect of OH and silanol groups in the removal of dyes from aqueous solution using diatomite. Water Res. 39, 922 (2005)

    Article  Google Scholar 

  17. K. Woo, H.J. Lee, J.P. Ahn, Y.S. Park, Sol-Gel mediated synthesis of Fe2O3 nanorods. Adv. Mater. 15, 1761 (2003)

    Article  Google Scholar 

  18. M.Y. Zhu, Y. Wang, D.H. Meng, X.Z. Qin, G.W. Diao, Hydrothermal synthesis of hematite nanoparticles and their electrochemical properties. J. Phys. Chem. C 116, 16276 (2012)

    Article  Google Scholar 

  19. G. Zhang, B. Wang, Z. Sun, S. Zheng, S. Liu, A comparative study of different diatomite-supported TiO2 composites and their photocatalytic performance for dye degradation. Desalin. Water Treat. 57, 17512 (2016)

    Article  Google Scholar 

  20. M. Ghanbari, M. Sabet, M. Salavati-Niasari, Synthesis and characterization of different morphologies of RbPbI3 nanaostructures via simple hydrothermal method and investigation of their photocatalytic activity. J. Mater. Sci: Mater. Electron. 27, 8826 (2016)

    Google Scholar 

  21. H.S. Wahab, A.A. Hussain, Photocatalytic oxidation of phenol red onto nanocrystalline TiO2 particles. J. Nanostructure. Chem. 6, 261 (2016)

    Article  Google Scholar 

  22. I.K. Konstantinou, T.A. Albanis, TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations: a review. Appl. Catal. B 49, 1 (2004)

    Article  Google Scholar 

  23. B. Neppolian, H.C. Choi, S. Sakthivel, B. Arabindoo, V. Murugesan, Solar light induced and TiO2 assisted degradation of textile dye reactive blue 4. Chemosphere 46, 1173 (2002)

    Article  Google Scholar 

  24. N. Panda, H. Sahoo, S. Mohapatra, Decolourization of methyl orange using Fenton-like mesoporous Fe2O3–SiO2 composite. J. Hazard. Mater. 185, 359 (2011)

    Article  Google Scholar 

  25. A.C.K. Yip, F.L.Y. Lam, X.J. Hu, Chemical-vapor-deposited copper on acid-activated bentonite clay as an applicable heterogeneous catalyst for the photo-Fenton-like oxidation of textile organic pollutants. Ind. Eng. Chem. Res. 44, 7983 (2005)

    Article  Google Scholar 

  26. S. Irmak, E. Kusvuran, O. Erbatur, Degradation of 4-chloro-2-methylphenol in aqueous solution by UV irradiation in the presence of titanium dioxide. Appl. Catal. B 54, 85 (2004)

    Article  Google Scholar 

  27. A.P. Toor, A. Verma, C.K. Jotshi, P.K. Bajpai, V. Singh, Photocatalytic degradation of Direct Yellow 12 dye using UV/TiO2 in a shallow pond slurry reactor. Dyes Pigm. 68, 53 (2006)

    Article  Google Scholar 

  28. B. Li, H. Huang, Y. Guo, Y. Zhang, Diatomite-immobilized BiOI hybrid photocatalyst: facile deposition synthesis and enhanced photocatalytic activity. Appl. Surf. Sci. 353, 1179 (2015)

    Article  Google Scholar 

Download references

Acknowledgements

Financial support from National Natural Science Foundation of China (21277039) is acknowledged.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Shaoming Yu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Xu, L., Sun, W., Zhang, L. et al. Facile synthesis of α-Fe2O3/diatomite composite for visible light assisted degradation of Rhodamine 6G in aqueous solution. J Mater Sci: Mater Electron 28, 4661–4668 (2017). https://doi.org/10.1007/s10854-016-6105-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-016-6105-x

Keywords

Navigation