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Thermoluminescence behaviour of Gd2O3:Er3+ phosphor prepared by combustion synthesis method

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Abstract

Er3+ doped Gd2O3 phosphors were prepared by using solution combustion synthesis method. The structural characterization and the luminescence behaviour of the prepared phosphors were determined and compared. Average crystal size for the phosphors yielded was in nanometre range from 6 to 48 nm, which was calculated by using XRD and confirmed by TEM technique. The compositional analysis was done by FTIR. Qualitative information regarding the elemental composition of powder sample was measured using EDX spectroscopy. EDX and FT-IR spectra confirm presence of Er3+ in the Gd2O3:Er3+ phosphors. For thermoluminescence (TL) studies the TL glow curves were recorded under two different excitations i.e. UV and gamma exposures. All the factors like dopant concentration, heating rate, exposure dose etc. were optimized for both the excitations. Various Kinetic parameters were calculated for TL glow curve recorded for all the optimized conditions. Computerized glow curve deconvolution analysis was carried out for optimized TL glow curve. Different kinetic parameters were also calculated for all the deconvoluted peaks.

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References

  1. F. Daniels, C.A. Boyd, D.F. Saunders, Science 117, 343 (1953)

    Article  Google Scholar 

  2. P.D. Townsend, J.C. Kelly, Colour Centres and Imperfections in Insulators and Semiconductors (Sussex University Press, London, 1993), p. 70

    Google Scholar 

  3. R. Chen, S.W.S. Mckeever, Theory of Thermoluminescence and Related Phenomenon (World Scientific Publisher, Beijing, 1997)

    Book  Google Scholar 

  4. P. Aliberti, S.K. Shrestha, R. Li, M.A. Green, G.J. Conibeer, J. Cryst. Growth 327, 84–88 (2011)

    Article  Google Scholar 

  5. R. Chen, Y. Kirsh, Analysis of Thermally Stimulated Process (Pergamon, Oxford, 1981)

    Google Scholar 

  6. S. Erdei, R. Roy, G. Harshe, H. Juwhari, D. Agarwal, F.W. Ainger, W.B. White, Mater. Res. Bull. 30, 745–753 (1995)

    Article  Google Scholar 

  7. Y.L. Song, Q.W. Tian, R.J. Zou, Z.G. Chen, J.M. Yang, J.H. Hua, J. Alloys Compd. 509, 6539–6544 (2011)

    Article  Google Scholar 

  8. K. Bernot, L. Bogani, A. Caneschi, D. Gatteschi, R. Sessoli, J. Am. Chem. Soc. 128, 7947–7956 (2006)

    Article  Google Scholar 

  9. V.P. Menushenkov, J. Magn. Magn. Mater. 290, 1274–1277 (2005)

    Article  Google Scholar 

  10. N. Dhananjaya, H. Nagabhushana, B.M. Nagabhushana, B. Rudraswamy, C. Shivakumara, R.P.S. Chakradhar, J. Alloys Compd. 509, 2368–2374 (2011)

    Article  Google Scholar 

  11. X. Zhang, J. Wang, K. Guo, H. Chen, X. Yang, J. Zhao, J. Alloys Compd. 517, 149–156 (2012)

    Article  Google Scholar 

  12. R.K. Tamrakar, K. Upadhyay, D.P. Bisen, Gamma ray induced thermoluminescence studies of yttrium(III) oxide nanopowders doped with gadolinium. J. Radiat. Res. Appl. Sci. 7(4), 526–531 (2014)

    Article  Google Scholar 

  13. R.K. Tamrakar, D.P. Bisen, K. Upadhyay, S. Tiwari, Synthesis and thermoluminescence behavior of ZrO2:Eu3+ with variable concentration of Eu3+ doped phosphor. J. Radiat. Res. Appl. Sci. 7(4), 486–490 (2014)

    Article  Google Scholar 

  14. R.K. Tamrakar, V. Dubey, Synthesis, structural characterization and thermoluminescence glow curve study of gadolinium-doped Y2O3 nanophosphor. J. Taibah Univ. Sci. 3(10), 317–323 (2014)

    Google Scholar 

  15. R.K. Tamrakar, N. Tiwari, R.K. Kuraria, D.P. Bisen, V. Dubey, K. Upadhyay, Effect of annealing temperature on thermoluminescence glow curve for UV and gamma ray induced ZrO2:Ti phosphor. J. Radiat. Res. Appl. Sci. 8(1), 1–10 (2015)

    Article  Google Scholar 

  16. R. Tamrakar, V. Dubey, N.K. Swamy, R. Tiwari, S.V.N. Pammi, P.V. Ramakrishna, Thermoluminescence studies of UV-irradiated Y2O3:Eu3+ doped phosphor. Res. Chem. Intermed. 39(8), 3919–3923 (2013)

    Article  Google Scholar 

  17. R.K. Tamrakar, D.P. Bisen, I.P. Sahu, N. Brahme, UV and gamma ray induced thermoluminescence properties of cubic Gd2O3:Er3+ phosphor. J. Radiat. Res. Appl. Sci. 7(4), 417–429 (2014)

    Article  Google Scholar 

  18. R.K. Tamrakar, D.P. Bisen, Thermoluminescence studies of ultraviolet and gamma irradiated erbium(III)-and ytterbium(III)-doped gadolinium oxide phosphors. Mater. Sci. Semicond. Process. 33, 169–188 (2015)

    Article  Google Scholar 

  19. S.K. Singh, K. Kumar, S.B. Rai, Multifunctional Er3+–Yb3+ codoped Gd2O3 nanocrystalline phosphor synthesized through optimized combustion route. Appl. Phys. B 94(1), 165–173 (2009)

    Article  Google Scholar 

  20. R.K. Tamrakar, D.P. Bisen, K. Upadhyay, Effect of annealing on down-conversion properties of monoclinic Gd2O3:Er3+ nanophosphors. Luminescence (2014). doi:10.1002/bio.2824

    Google Scholar 

  21. A. Guinier, X-Ray Diffraction (Freeman, San Francisco, 1963)

    Google Scholar 

  22. V.D. Mote, J.S. Dargad, B.N. Dole, Effect of Mn doping concentration on structural, morphological and optical studies of ZNO nano particles. Nanosci. Nanoeng. 1(2), 116–122 (2013)

    Google Scholar 

  23. Y.S. Horowitz, TL Dose Response, in Thermoluminescence and Thermoluminescence Dosimetry (CRC Press, Boston, 1984), p. 89

    Google Scholar 

  24. S. Bahl, A. Pandey, S.P. Lochab, V.E. Aleynikov, A.G. Molokanov, P. Kumar, Synthesis and thermoluminescence characteristics of gamma and proton irradiated nanocrystalline MgB4O7:Dy, Na. J. Lumin. 134, 691–698 (2013)

    Article  Google Scholar 

  25. V. Pagonis, R. Chen, J.L. Lawless, A quantitative kinetic model for Al2O3:C:TL response to ionizing radiation. Radiat. Meas. 42(2), 198–204 (2007)

    Article  Google Scholar 

  26. J.L. Lawless, R. Chen, D. Lo, V. Pagonis, A model for non-monotonic dose dependence of thermoluminescence (TL). J. Phys. Condens. Matter 17(4), 737 (2005)

    Article  Google Scholar 

  27. R. Chen, Y. Kirsh, The Analysis of Thermally Stimulated Processes (Pergamon Press, Oxford, 1981)

    Google Scholar 

Download references

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Correspondence to Raunak Kumar Tamrakar.

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Tamrakar, R.K., Upadhyay, K. Thermoluminescence behaviour of Gd2O3:Er3+ phosphor prepared by combustion synthesis method. J Mater Sci: Mater Electron 28, 4267–4278 (2017). https://doi.org/10.1007/s10854-016-6050-8

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  • DOI: https://doi.org/10.1007/s10854-016-6050-8

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